• Title/Summary/Keyword: Bonding durability

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Cryogenic Mechanical Characteristics of Laminated Plywood for LNG Carrier Insulation System (LNG운반선 방열시스템에 적용되는 적층형 플라이우드의 극저온 기계적 특성 분석)

  • Kim, Jeong-Hyeon;Park, Doo-Hwan;Choi, Sung-Woong;Lee, Jae-Myung
    • Journal of Ocean Engineering and Technology
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    • v.31 no.3
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    • pp.241-247
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    • 2017
  • Plywood, which is created by bonding an odd number of thin veneers perpendicular to the grain orientation of an adjacent layer, was developed to supplement the weak points such as contraction and expansion of conventional wood materials. With structural merits such as strength, durability, and good absorption against impact loads, plywood has been adopted as a structural material in the insulation system of a membrane type liquefied natural gas (LNG) carrier. In the present study, as an attempt to resolve recent failure problems with plywood in an LNG insulation system, conventional PF (phenolic-formaldehyde) resin plywood and its alternative MUF (melamine-urea-formaldehyde) resin bonded plywood were investigated by performing material bending tests at ambient ($20^{\circ}C$) and cryogenic ($-163^{\circ}C$) temperatures to understand the resin and grain effects on the mechanical behavior of the plywood. In addition, the failure characteristics of the plywood were investigated with regard to the grain orientation and testing temperature.

FULL COVERAGE RESTORATION OF PRIMARY ANTERIOR TEETH : A CASE REPORT (유전치의 전장피개수복 : 증례보고)

  • Hong, Kee-Sang;Jang, Ki-Taeg;Lee, Sang-Hoon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.26 no.2
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    • pp.240-247
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    • 1999
  • Primary anterior teeth requiring extensive restorative therapy due to caries, trauma or developmental defects can present a particularly challenging problem for the pediatric dentist. The ideal restorative technique would combine strength, durability esthetics and efficiency in placement. Couple these concerns with the technical difficulties of operating on children with behavior management problems, and the dentist is left with the difficult task of choosing from a variety of restorative options. Restorative modalities currently in use to treat primary anterior teeth include bonding with composite resin as in celluloid strip crowns, conventional stainless steel crowns, open-faced stainless steel crowns, commercially and chairside veneered stainless steel crowns and epoxy-coated stainless steel crowns. Each of these techniques presents technical, functional or esthetic compromises that complicate their efficient and effective usage. This is a report of the results obtained at the Department of Pediatric Dentistry, College of Dentistry Seoul National University, through the use of these various methods of treating primary anterior teeth.

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Effects of Hardeners and Catalysts on the Reliability of Copper to Copper Adhesive Joint (Cu-Cu 접착부의 고온고습 내구성에 미치는 경화제 및 촉매제의 영향)

  • Min, Kyung-Eun;Kim, Hae-Yeon;Bang, Jung-Hwan;Kim, Jong-Hoon;Kim, Jun-Ki
    • Korean Journal of Materials Research
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    • v.21 no.5
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    • pp.283-287
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    • 2011
  • As the performance of microelectronic devices is improved, the use of copper as a heat dissipation member is increasing due to its good thermal conductivity. The high thermal conductivity of copper, however, leads to difficulties in the joining process. Satisfactory bonding with copper is known to be difficult, especially if high shear and peel strengths are desired. The primary reason is that a copper oxide layer develops rapidly and is weakly attached to the base metal under typical conditions. Thus, when a clean copper substrate is bonded, the initial strength of the joint is high, but upon environmental exposure, an oxide layer may develop, which will reduce the durability of the joint. In this study, an epoxy adhesive formulation was investigated to improve the strength and reliability of a copper to copper joint. Epoxy hardeners such as anhydride, dihydrazide, and dicyandiamide and catalysts such as triphenylphosphine and imidazole were added to an epoxy resin mixture of DGEBA and DGEBF. Differential scanning calorimetry (DSC) analyses revealed that the curing temperatures were dependent on the type of hardener rather than on the catalyst, and higher heat of curing resulted in a higher Tg. The reliability of the copper joint against a high temperature and high humidity environment was found to be the lowest in the case of dihydrazide addition. This is attributed to its high water permeability, which led to the formation of a weak boundary layer of copper oxide. It was also found that dicyandiamide provided the highest initial joint strength and reliability while anhydride yielded intermediate performance between dicyandiamide and dihydrazide.

EFFECT OF METAL PRIMER TREATMENT OF THE Au-Ag-PD ALLOY SURFACE ON THE METAL-RESIN BONDING (치과용 금-은-팔라디움 합금에 대한 프라이머 처리가 금속-레진 접착에 미치는 영향)

  • Lee Kang;Lee Cheong-Hee;Jo Kwang-Hun;Kim Kyo-Han
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.4
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    • pp.417-432
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    • 2001
  • The pcf metal primers on the bond strength and durability of 4-META/MMA-TBB resins adhered to an Au-Ag-Pd alloy. For this study, the specimens were divided into 8 groups as follows: Thermocyle 0 : (1) control group : sandblast, (2) Group I : sandblast + Cesead Opaque Primer; (3) Group II : sandblast + Metal Primer; (4) Group III : sandblast + V-Primer; Thermocyle 10,000 (5) control sandblast: (6) Group I : sandblast + Cesead Opaque Primer: (7) Group II : sandblast + Metal Primer; (8) Group III sandblast + V-Primer. The shear bond strength was determined using an Instron were observed with the use of scanning electron microscope. Finally, the strengths of bonded joints were evaluated with regard to their adherence energy using a wedge test. The results obtained were as follows ; (1) The shear bond strength of 4-META/MMA-TBB resin to the Au-Ag-Pd alloy was significantly improved in all the groups treated with the primers (p<0.05). (2) Regardless of the adhesive primers used, a significant difference was observed in the bond strength of the thermocycle 0 groups and 10,000 groups (p<0.05). (3) Both before and after thermocycling, the strongest bond strength between the resin an the alloy was obtained after treatment with a metal primer containing MEPS (p<0.05). (4) In the wedge test, the adherence energies of the control group and Group III decreased more rapidly than those of Group I and II during the 2nd day of storage in water.

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Repair bond strength of resin composite to bilayer dental ceramics

  • Ataol, Ayse Seda;Ergun, Gulfem
    • The Journal of Advanced Prosthodontics
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    • v.10 no.2
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    • pp.101-112
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    • 2018
  • PURPOSE. The purpose of this study was to investigate the effect of various surface treatments (ST) on the shear bond strength of resin composite to three bilayer dental ceramics made by CAD/CAM and two veneering ceramics. MATERIALS AND METHODS. Three different bilayer dental ceramics and two different veneering ceramics were used (Group A: IPS e.max CAD+IPS e.max Ceram; Group B: IPS e.max ZirCAD+IPS e.max Ceram, Group C: Vita Suprinity+Vita VM11; Group D: IPS e.max Ceram; Group E: Vita VM11). All groups were divided into eight subgroups according to the ST. Then, all test specimens were repaired with a nano hybrid resin composite. Half of the test specimens were subjected to thermocycling procedure and the other half was stored in distilled water at $37^{\circ}C$. Shear bond strength tests for all test specimens were carried out with a universal testing machine. RESULTS. There were statistically significant differences among the tested surface treatments within the all tested fracture types (P<.005). HF etching showed higher bond strength values in Groups A, C, D, and E than the other tested ST. However, bonding durability of all the surface-treated groups were similar after thermocycling (P>.00125). CONCLUSION. This study revealed that HF etching for glass ceramics and sandblasting for zirconia ceramics were adequate for repair of all ceramic restorations. The effect of ceramic type exposed on the fracture area was not significant on the repair bond strength of resin composites to different ceramic types.

Microtensile bond strength and micromorphologic analysis of surface-treated resin nanoceramics

  • Park, Joon-Ho;Choi, Yu-Sung
    • The Journal of Advanced Prosthodontics
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    • v.8 no.4
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    • pp.275-284
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    • 2016
  • PURPOSE. The aim of this study was to evaluate the influence of different surface treatment methods on the microtensile bond strength of resin cement to resin nanoceramic (RNC). MATERIALS AND METHODS. RNC onlays (Lava Ultimate) (n=30) were treated using air abrasion with and without a universal adhesive, or HF etching followed by a universal adhesive with and without a silane coupling agent, or tribological silica coating with and without a universal adhesive, and divided into 6 groups. Onlays were luted with resin cement to dentin surfaces. A microtensile bond strength test was performed and evaluated by one-way ANOVA and Tukey HSD test (${\alpha}$=.05). A nanoscratch test, field emission scanning electron microscopy, and energy dispersive X-ray spectroscopy were used for micromorphologic analysis (${\alpha}$=.05). The roughness and elemental proportion were evaluated by Kruskal-Wallis test and Mann-Whitney U test. RESULTS. Tribological silica coating showed the highest roughness, followed by air abrasion and HF etching. After HF etching, the RNC surface presented a decrease in oxygen, silicon, and zirconium ratio with increasing carbon ratio. Air abrasion with universal adhesive showed the highest bond strength followed by tribological silica coating with universal adhesive. HF etching with universal adhesive showed the lowest bond strength. CONCLUSION. An improved understanding of the effect of surface treatment of RNC could enhance the durability of resin bonding when used for indirect restorations. When using RNC for restoration, effective and systemic surface roughening methods and an appropriate adhesive are required.

A Study on the Development of Fashion Accessary Product made with Korean Traditional Paper Hanji II - Focusing on analysis of the related references - (전통 한지를 활용한 패션 액세서리 상품 개발 II - 관련문헌 분석을 중심으로 -)

  • Shim, Joon-Young;Kim, Yong-Sook
    • Korean Journal of Human Ecology
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    • v.15 no.5
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    • pp.803-809
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    • 2006
  • Korean traditional paper 'Hanji' made from the bark of the paper mulberry tree is a good handicraft material because of its high viscosity, durability, dyeability, toughness, flexibility, plasticity, and manipulability. Hanji has been used as a textile material such as cotton wool for protection and keeping us warm from cold weather. However, Hanji has many limitations, while other textile materials have many advantages of such as washability, being sunproof, and fast coloring. The purpose of this study is to review physical properties, formation ability, and dyeability of Hanji as a material of fashion accessary. The contents of this study are composed of 5 parts: 1. To introduce the necessities of this study, 2. To review a historical background of Hanji and to identify its physical characteristics as a fashion accessary material, 3. To review and to compare techniques such as bonding, quilting, knitting, creasing and holding, twisting, folding & braiding, paper pasting, coloring & cutting, and outwashing(?) in making Hanji fashion accessaries, 4. To review dyeing and finishing techniques to increase commercial value, 5. To identify the best fashion accessary materials made of Hanji. The most important characteristics of Hanji as a fashion accessary material are its toughness in a wet state, fast color fixing, and flexibility. Especially weaving and knitting are considered as the most desirable techniques to make fashion accessary products stronger and more practical.

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Effect of Heat Treatment Temperature and Coating Thickness on Conversion Lens for White LED (백색 LED용 색변환 렌즈의 열처리 온도 및 코팅 두께에 따른 영향)

  • Lee, Hyo-Sung;Hwang, Jong Hee;Lim, Tae-Young;Kim, Jin-Ho;Jung, Hyun-Suk;Lee, Mi Jai
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.533-538
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    • 2014
  • Today, silicon and epoxy resin are used as materials of conversion lenses for white LEDs on the basis of their good bonding and transparency in LED packages. But these materials give rise to long-term performance problems such as reaction with water, yellowing transition, and shrinkage by heat. These problems are major factors underlying performance deterioration of LEDs. In this study, in order to address these problems, we fabricated a conversion lenses using glass, which has good chemical durability and is stable to heat. The fabricated conversion lenses were applied to a remote phosphor type. In this experiment, the conversion lens for white LED was coated on a glass substrate by a screen printing method using paste. The thickness of the coated conversion lens was controlled during 2 or 3 iterations of coating. The conversion lens fabricated under high heat treatment temperature and with a thin coating showed higher luminance efficiency and CCT closer to white light than fabricated lenses under low heat treatment temperature or a thick coating. The conversion lens with $32{\mu}m$ coating thickness showed the best optical properties: the measured values of the CCT, CRI, and luminance efficiency were 4468 K, 68, and 142.22 lm/w in 20 wt% glass frit, 80 wt% phosphor with sintering at $800^{\circ}C$.

Flexural strength and microstructure of two lithium disilicate glass ceramics for CAD/CAM restoration in the dental clinic

  • Kang, Suk-Ho;Chang, Juhea;Son, Ho-Hyun
    • Restorative Dentistry and Endodontics
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    • v.38 no.3
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    • pp.134-140
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    • 2013
  • Objectives: There has been a growing interest in glass ceramic systems with good esthetics, high fracture resistance and bonding durability, and simplified fabrication techniques using CAD/CAM. The aim of this study is to compare flexural strength before and after heat treatment of two lithium disilicate CAD/CAM blocks, IPS e.max CAD (Ivoclar Vivadent) and Rosetta SM (Hass), and to observe their crystalline structures. Materials and Methods: Biaxial flexural strength was tested according to ISO 6872 with 20 disc form specimens sliced from each block before and after heat treatment. Also, the crystalline structures were observed using field-emission scanning microscopy (FE-SEM, Hitachi) and x-ray diffraction (XRD, Rigaku) analysis. The mean values of the biaxial flexural strength were analyzed by the Mann-Whitney U test at a significance level of p = 0.05. Results: There were no statistically significant differences in flexural strength between IPS e.max CAD and Rosetta SM either before heat treatment or after heat treatment. For both ceramics, the initial flexural strength greatly increased after heat treatment, with significant differences (p < 0.05). The FE-SEM images presented similar patterns of crystalline structure in the two ceramics. In the XRD analysis, they also had similar patterns, presenting high peak positions corresponding to the standard lithium metasilicate and lithium disilicate at each stage of heat treatment. Conclusions: IPS e.max CAD and Rosetta SM showed no significant differences in flexural strength. They had a similar crystalline pattern and molecular composition.

Cyclic behaviour and modelling of stainless-clad bimetallic steels with various clad ratios

  • Liu, Xinpei;Ban, Huiyong;Zhu, Juncheng;Uy, Brian
    • Steel and Composite Structures
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    • v.34 no.2
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    • pp.189-213
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    • 2020
  • Stainless-clad (SC) bimetallic steels that are manufactured by metallurgically bonding stainless steels as cladding metal and conventional mild steels as substrate metal, are kind of advanced steel plate products. Such advanced composite steels are gaining increasingly widespread usage in a range of engineering structures and have great potential to be used extensively for large civil and building infrastructures. Unfortunately, research work on the SC bimetallic steels from material level to structural design level for the applications in structural engineering field is very limited. Therefore, the aim of this paper is to investigate the material behaviour of the SC bimetallic steels under the cyclic loading which structural steels usually could encounter in seismic scenario. A number of SC bimetallic steel coupon specimens are tested under monotonic and cyclic loadings. The experimental monotonic and cyclic stress-strain curves of the SC bimetallic steels are obtained and analysed. The effects of the clad ratio that is defined as the ratio of the thickness of cladding layer to the total thickness of SC bimetallic steel plate on the monotonic and cyclic behaviour of the SC bimetallic steels are studied. Based on the experimental observations, a cyclic constitutive model with combined hardening criterion is recommended for numerical simulation of the cyclic behaviour of the SC bimetallic steels. The parameters of the constitutive model for the SC bimetallic steels with various clad ratios are calibrated. The research outcome presented in this paper may provide essential reference for further seismic analysis of structures fabricated from the SC bimetallic steels.