• Title/Summary/Keyword: Bond quality

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3D-QSARs of Herbicidal 2-N-Phenylisoindolin-1-one Analogues as a New Class of Potent Inhibitors of Protox

  • Soung, Min-Gyu;Lee, Yoon-Jung;Sung, Nack-Do
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.613-617
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    • 2009
  • 3D-QSARs for the inhibition activities against protox by herbicidal 2-N-phenylisoindolin-1-one derivatives were studied quantitatively using CoMFA and CoMSIA methods. The result of the statistical quality of optimized CoMSIA model 2 ($FF:\;{r^2}_{cv.};\;0.973\;&\;{r^2}_{ncv.};\;0.612$) was higher than that of CoMFA model 1 ($AF:\;{r^2}_{cv.};\;0.414\;&\;{r^2}_{ncv.};\;0.909$). Also, the relative contribution of the optimized CoMSIA model 2 showed the steric (24.6%), electrostatic (31.0%), hydrophobic (ClogP, 23.4%) and H-bond acceptor field (21.0%), respectively. From the results of the contour maps, the protox inhibition activities are expected to increase when steric favor and H-bond acceptor favor groups are substituted on $R_2$ position and positive favor group are substituted on $C_2,\;C_3,\;and\;C_5$ atom in phenyl ring of $R_2$ position. And the inhibition activities are expected to increase when hydrophobic favor group is substituted on $C_1,\;C_3$ atom in phenyl ring of $R_2$ position and $C_1$ atom of $R_2$ position and hydrophilic favor groups are substituted on $C_4$ atom in phenyl ring of $R_1$ position and the terminal group of $R_1$ position.

A Study on the Trade Structure between Korea and RCEP Participating Countries (한국과 RCEP 참여국가와의 무역구조에 관한 연구)

  • Kim, Min-Soo
    • The Journal of Industrial Distribution & Business
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    • v.9 no.1
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    • pp.89-97
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    • 2018
  • Purpose - The Regional Comprehensive Economic Partnership (RCEP) among 16 countries including South Korea, the largest free trade agreement in the Asia-Pacific region, will be concluded next year. The participating countries decided to pursue a comprehensive and high -quality agreement, while ensuring flexibility considering development level of each country. In this study, trade structures between nations from 2005 through 2016 were examined to see the impact that this agreement will have on Korea and to come up with effective countermeasures. Research design, data, and methodology - The method of analysis includes the analysis of the trade matrix, which is useful for identifying the dependency of the individual countries on the market in the region and the reciprocal dependency of the member countries on the market, and the index of intensity of trade, which is useful for figuring out the share of trade between the parties in total trade. Results - The results showed that first, the international trade coefficients of Vietnam and Philippines are higher than those of China and Japan. Secondly, the international inducement coefficients between China and Japan were high, and that between Indonesia and Burma were low, indicating that Korea's exports did not have much effect on export increase of these countries. Third, as a result of analyzing Korea's trade intensity, it was found that export intensity and import intensity were greater than 1 in Vietnam and Philippines, which shows that there is a high degree of relational bond with these countries. India and Laos countries still have a low level of relational bond, which indicates that there is room for improvement in economic relations when the agreement is concluded. After the signing of the agreement in the future, more diverse industrial structures should be continuously studied. Conclusions - The analysis of trade matrix, trade structure, trade inducement coefficient and trade intensity between Korea and RCEP participating countries shows that the majority of the countries have the high level of economic relationship with Korea. Korea should drive a harder bargain when negotiating the terms of the RCEP, in comparison with the level of the existing FTA agreement excluding Japan.

Effect of Allium hookeri Root on Physicochemical, Lipid, and Protein Oxidation of Longissimus Dorsi Muscle Meatball

  • Yoon, Dong-kyu;Kim, Ji-Han;Cho, Won-Young;Ji, Da-Som;Lee, Ha-Jung;Kim, Jung-Ho;Lee, Chi-Ho
    • Food Science of Animal Resources
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    • v.38 no.6
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    • pp.1203-1215
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    • 2018
  • The antioxidant effects of Allium hookeri root (AHR) were investigated by evaluating lipid and protein oxidation in meatballs during refrigerated storage at $4{\pm}1^{\circ}C$. AHR was mixed at concentrations of 0.5% (w/w, T2) and 1% (w/w, T3) with minced longissimus dorsi muscle. Meatballs containing AHR (T2 and T3) were compared to those containing 0.05% (w/w) ascorbic acid (T1) as a reference and without antioxidant as a control. The 2-thiobarbituric acid reactive substances (TBARS) value, disulfide bond formation, carbonyl contents, and volatile basic nitrogen (VBN) value of T2 were lower than those of the control during storage (p<0.05). The pH values of T2 and T3 were higher than that of the control (p<0.05). Texture profile analysis of T2 revealed a lower value compared to the control (p<0.05). Therefore, the VBN value, TBARS value, disulfide bond formation, and carbonyl content in meatball containing AHR were lower than those of the control meatball. These results indicate that AHR improves the quality of meat products and functions as an antioxidant.

A Stress Transfer Length of Pre-tensioned Members Using Ultra High Performance Concrete (초고성능 콘크리트 프리텐션부재의 응력전달길이)

  • Kim, Jee-Sang;Choi, Dong-Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.336-341
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    • 2018
  • The prestressing force introduced to the tendon in pretensioned concrete members is transferred by direct bond between tendon and concrete, which requires a proper estimation of stress transfer length. The use of pretensiond and/or precast members with UHPC (Ultra High Performance Concrete) may give many advantages in quality control. This paper presents an experiment to estimate the stress transfer length of UHPC for various compressive strength levels of UHPC, cover depths, diameters of tendons and tensioning forces. According to the result of this experiment, the stress transfer length of UHPC member is much reduced comparing that of normal strength concrete. The reduction in stress transfer length of UHPC may come from the high bond strength capacity of UHPC. The transfer lengths obtained from this experiment are compared to those in current design code and a new formula is proposed.

Factors Influencing Depression in Late Middle-aged Men (후기 중년 남성의 우울 영향 요인)

Behavior of Bond-type Shallow Anchors in Rock Masses ( I ) - Metamorphic Rock (gneiss) at Taean Test Site - (암반에 근입된 부착형 앵커의 거동특성 (I) - 태안지역 편마암 -)

  • Kim, Dae-Hong;Lee, Dae-Soo;Chun, Byung-Sik;Kim, Byung-Hong
    • Journal of the Korean Geotechnical Society
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    • v.22 no.12
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    • pp.45-55
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    • 2006
  • This paper presents the results of full-scale uplift load tests performed on 30 passive anchors grouted to various lengths at Taean site in Korea. Various rock types were tested, ranging from highly weathered to sound gneiss. Rock anchors were installed over a wide range of rock types and qualities with a fixed anchored depth of $1{\sim}4m$. The majority of installations used SD4O-D51 no high grade steel rebar to induce rock failure prior to rod failure. In many tests, rock failure was reached and the ultimate loads were recorded along with observations of the shape and extent of the failure surface. The test results, the failure mechanisms as well as uplift capacities of rock anchors depend mostly on rock type and quality, embedded fixed length, and the strength of rebar. Based on test results, the main parameters governing the uplift capacity of the rock anchor system were determined.

Using Mean Residual Life Functions for Unique Insights into Strengths of Materials Data

  • Guess Frank M.;Zhang Xin;Young Timothy M.;Leon Ramon V.
    • International Journal of Reliability and Applications
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    • v.6 no.2
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    • pp.79-85
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    • 2005
  • We show how comparative mean residual life functions (MRL) can be used to give unique insights into strengths of materials data. Recall that Weibull's original reliability function was developed studying and fitting strengths for various materials. This creative comparing of MRL functions approach can be used for regular life data or any time to response data. We apply graphical MRL's to real data from tests of tensile strength of high quality engineered wood.

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Analysis of Slab Joint Opening Due to Temperature Drop in Continuous Precast Concrete Slab Track (연속 프리캐스트 콘크리트 슬래브궤도에서의 온도하강에 따른 슬래브 이음매 개구량 해석)

  • Jang, Seung-Yup;Lee, Jeong-Wan
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.1659-1663
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    • 2011
  • Precast concrete slab track is a track structure to be installed by transporting and assembling precast concrete slabs manufactured at the factory. This method can improve concrete quality, provide easy maintenance and reduce construction time, compared with in-situ concrete track. However, the concrete slabs being continuously connected in longitudinal direction, due to the temperature change between summer and winter, the openings at slab joints have occurred. Thus, in this study, to identify the cause of this opening of slab joint, the joint opening caused by temperature drop in the longitudinally continuous precast concrete slab track has been predicted using three-dimensional finite element analysis, and compared with field measurements. Based on the proven model, the slab joint opening, and the stress pattern of concrete slab and steel reinforcement according to concrete slab-base friction properties, concrete-reinforcement bond properties, and prestressing were analyzed.

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In-Process Measurement of Insulating Layer in ELID-Grinding (ELID 연삭에서 부도체 피막의 실시간 계측)

  • Kim, Hwa-Young;Ahn, Jung-Hwan;Seo, Young-Ho
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.71-76
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    • 2001
  • In general, it is known that the wear rate of the abrasive and the removal rate of the metal bond of the grinding wheel should be balanced to maintain the depth of the insulating surface layer to an appropriate level. In order to accomplish, the high quality ELID grinding, therefore, it is necessary to measure the depth of the insulating layer in real-time and then to control the electrolytic conditions to keep the depth to a certain level. In this study, an in-process measurement system of the insulated layer using two gap sensors - a capacitor type and an eddy current type - developed and the change of the status of the insulated layer during ELID grinding is detected. And from the experimental data, we have chosen the best mathematical model to predict the depth of the insulating layer.

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Dynamic Performance Analysis for Secondary Suspension of Maglev Control Systems with a Combined Lift and Guidance (편심배치방식 자기부상 제어시스템의 2차 현가에 대한 동특성 해석)

  • Kim, Jong-Shik
    • Journal of the Korean Society for Precision Engineering
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    • v.9 no.1
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    • pp.53-65
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    • 1992
  • For improving the performance of maglev systems with a combined lift and guidance, it is suggested that the multivariable control systems and a secondary suspension should be added. The former is required to reject both track irregularities in vertical disturbances and wind gusts in lateral disturbances, and the latter to guarantee passengers against an unsatisfied criteria in ride quality. In this paper, bond graph model for the study of nonlinear dynamics of maglev systems with a combined lift and guidance is presented briefly. And, the secondary suspension is analyzed to understand the role of stiffness and damping factors in passive devices. Finally, LQG/LTR mulitivariable control systems are designed for the overall maglev systems with and without secondary suspension, and then the system performances in these two cases are evaluated.

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