• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.225-228
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• 2008

SC벽체는 뛰어난 후좌굴성의 특성을 지니고 있고 연성능력이 뛰어나 원자력 건물과 같은 주요건물에 주로 사용되고 있고 최근 국내 실정에 맞는 강도식 산정을 연구 중에 있다. 최근 일본학회(JEAG)에서 제안한 면외 전단강도식은 전단스팬비에 의한 아치강도를 지나치게 단순화한 경향이 있고, 짧은 전단스팬비에서 아치강도와 전단균열강도를 분리하여 대소관계로써 결정하고 있어 강도식을 재정립할 필요가 있다. 아치작용의 본질은 전단을 지점으로 직접 전달하는 것이고, 아치단부가 최대로 압축받지 않는 경우가 많으므로, 스터드에 의한 콘크리트와 강판의 부착강도와 평형관계를 통해 아치강도를 결정한다. 실험체 제작은 일본학회에서 실험한 내용과 같이, 원자력 벽체에 가해지는 하중형태를 단순화하고 벽체를 연속보의 형태로 가정, 전단스팬비를 변경하면서 면외전단실험을 진행한 후 강도식과 검증을 실시하였다. 전단스팬비 이외에도 스터드의 밀집도, 스터럽에 의한 전단보강 정도를 변수로 하여 실험결과를 비교 검증하였다. 예상식과 실험결과는 일본의 기존 강도식에 비해 비교적 접근하는 결과를 얻을 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제19권6호
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• pp.654-660
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• 1998

$[Fe^{II}Fe^{III}BPLMP(OAc)_2](BPh_4)_2$ (1), a new model for the reduced form of the purple acid phosphatases, has been synthesized by using a dinucleating ligand, 2,6-bis[((2-pyridylmethyl)(6-methyl-2-pyridylmethyl)amino) methyl]-4-methylphenol (HBPLMP). Complex I has been characterized by X-ray diffraction method as having (μ-phenoxo)bis(acetato)diiron core. Complex 1 was crystallized in the monoclinic space group C2/c with the following cell parameters: a=41.620(6) Å, b=14.020(3) Å, c=27.007(4) Å, β=90.60(2)°, and Z=8. The iron centers in the complex 1 are ordered as indicated by the difference in the Fe-O bond lengths which match well with typical $Fe^{III}-O\; and\; Fe^{II}-O$ bond lengths. Complex 1 has been studied by electronic spectral, NMR, EPR, SQUID, and electochemical methods. Complex 1 exhibits strong bands at 592 nm, 1380 nm in $CH_3CN$ (ε = 1.0 × 103 , 3.0 × 102). These are assigned to $phenolate-to-Fe^{III}$ and intervalence charge-transfer transitions, respectively. Its NMR spectrum exhibits sharp isotropically shifted resonances, which number half of those expected for a valence-trapped species, indicating that electron transfer between $Fe^{II}\;and\;Fe^{III}$ centers is faster than NMR time scale. This complex undergoes quasireversible one-electron redox processes. The $Fe^{III}_2/Fe^{II}Fe^{III}\;and\;Fe^{II}Fe^{III}/Fe^{II}_2$ redox couples are at 0.655 and -0.085 V vs SCE, respectively. It has $K_{comp}=3.3{\times}10^{12}$ representing that BPLMP/bis(acetate) ligand combination stabilizes a mixed-valence $Fe^{II}Fe^{III}$ complex in the air. Complex 1 exhibits a broad EPR signal centered near g=1.55 which is a characteristic feature of the antiferromagnetically coupled high-spin $Fe^{II}Fe^{III}$ system $(S_{total}=1/2)$. This is consistent with the magnetic susceptibility study showing the weak antiferromagnetic coupling $(J= - 4.6\;cm^{-1},\; H= - 2JS_1{\cdot}S2)$ between $Fe^{II}\; and \;Fe^{III}$center.

• 한국기계가공학회지
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• 제21권3호
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• pp.1-11
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• 2022

In this study, an electric resistance dual-spot welding process using a copper electrode inserted in a heating electrode is suggested for the spot welding of AZ31 magnesium sheets. This spot-welding process involves two heating methods for welding at the interfacial zone between the magnesium sheets, one of which is the heating method by thermal conduction from the heating electrode heated by the welding current induced to the steel electrode, and the other heating method uses the electric resistance between the contacted surfaces of the two sheets by the welding current induced to the copper electrode. This welding process includes the welding variables, such as the current induced in the heating electrode and the copper electrode, and the outer diameters of the heating electrode. This is because the heat conducted from the heating electrode can be maintained at a higher temperature in the welding zone, which has a slow cooling effect on the nugget of the melted metal after the welding step. The pressure exerted during the pressing of the magnesium sheets by the heating electrode can be increased around the nugget zone at the spot-welding zone. Thus, it not only reduces the warping effect of the elastoplastic deformation of sheets, but also the corona bond can make it less prone to cracking at the welded zone, thereby reducing the number of nuggets expelled out of the corona bond. In conclusion, it was known that an electric resistance dual spot welding process using the copper electrode inserted in the heating electrode can improve the welding properties in the electric resistance spot welding process of AZ31 magnesium sheets.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.463-468
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• 2002

For the Externally bonded FRP systems, flexural design method is studied focusing on the reinforcement layer of the carbon fiber sheets. As the FRP layer is added, strengthening rate increases, but not proportionally as the FRP layer increases. This is reflected in the design formula appropriately by the bond cofficients from the added layers. As the number of FRP layer increases, the stress reinforcement and FRP sheet decreases, and it generally corresponds to the decrease rate of member flexural strength. This phenomenon is appearing indentically in a design formula and experimental result. The rate of $M_{test}$ and $M_n$ is 1.19 and it is estimated as safety factor which is the reduction factor, ${\psi}_f = 0.85$.

• Bulletin of the Korean Chemical Society
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• 제28권10호
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• pp.1787-1791
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• 2007

Several hydroxylated cinnamic acid derivatives were prepared from the corresponding acids and amino acid residues, and their hypocholesterolemic activities were evaluated in high cholesterol-fed mice. The presence of the double bond in hydroxylated cinnamide derivatives decreases cholesterol-lowering activities and the number of free phenolic hydroxy groups affect greatly the activities. 3,4-Dihydroxy hydrocinnamides obtained from amino acid derivatives containing a hydrophobic side chain such as alanine, valine, phenylalanine, and isoleucine exhibited potent cholesterol-lowering activities.

• Journal of Welding and Joining
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• 제18권1호
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• pp.52-58
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• 2000

Spot welding, namely a kind of electric resisting welding has been used widely in field of automobile and aircraft industries because of easiness to apply. Specimens used in this study was a mild steel of 1.2mm thickness and the electrode was a Cu-Cr alloy of 6mm diameter. The surface sheared of specimens after testing of tensile shear was observed by SEM(scanning electron microscope) after ultrasonic cleaning for 10min., and microstructures and grain size of all specimens were measured with using of O.M.(Optical microscope). By the means of measurement and observations of tensile shear load, fatigue strength and share surface, the weldability of spot welding was evaluated. When tensile shearing testing, fracture starting point in all specimens was took place at the bond between HAZ(Heat affected zone) and nugget. With increasing in number of layers, fatigue strength was decreased. With increasing in electric current, grain size in the HAZ became more fine.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.55-60
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• 2001

Influencing factors on flexural toughness of ring-type fiber reinforced concrete(RSFRC) are investigated. An experiment proceeding ASTM C 78 is peformed to make a comparison between ring-type fibers and double-hook type fibers. Most specimen with ring type fibers have failed by the cone type failure, while discrete hook type fibers have failed by fiber pullout. For the hook-type fiber reinforced concrete(SFRC), the first crack load increases, as the fiber mixing volume increases. Aspect ratio(fiber length/fiber diameter) is critical for hook type fibers, so the flexural toughness increases significantly, as the length of fiber increases. However, for the ring type, the toughness indices Increase as the number of fibers in the specimen increases. Since there is no bond problem between the ring fiber and the concrete matrix, the aspect ratio does not affect the performance of the composite material with the newly developed steel fibers. Influencing factors with respect to flexural toughness RSFRC were observed to be ring diameter, diameter of steel fiber and fiber content.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.178.1-178.1
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• 2011

DME is generally expected to be used as a promising clean alternative fuel to diesel fuel. DME is not natural product but a synthetic product that is produced either through the dehydration of methanol or a direct synthetic from syngas. As DME has no carbon-carbon bond in its molecular structure and is an oxygenate fuel, it's combustion essentially generates no soot. DME has such cetane number of 55~60 that it can be used as a diesel engine fuel. However, DME has low lubricity but a proven method to solve the poor lubricity is by adding lubricity improver. Therefore, the aim of this study is to develop lubricity improver of DME as a transport fuel in Korea. In this study, we investigated a possibility of fatty acid ester compounds as a candidate to improve DME lubricity as compared with current lubricity improver of diesel. We also evaluated quality characteristics, storage stability of DME with lubricity additives.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.285-290
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• 2000

The present study was conducted to determine flooding heat transfer limitation of a two-phase closed thermosyphon using PFC as working fluid. The variables such as pipe inner diameter, working fluid property, operating temperature were examined by way of analytic method. Comparison of experimental data on flooding heat transfer limitation shows a fairly good agreement with the analytic results. An expression fur flooding maximum heat transfer rate was formulated as a function of Bond number and saturation pressure and written as follows ; $Q_{max} =0.989{\cdot}P_s^{0.286}{\cdot}Bo^{1.74}$.

• 생약학회지
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• 제10권2호
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• pp.55-59
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• 1979

Mass spectra of the dammarane triterpenes having open side chain and $C_{20}-C_{25}-epoxy$ side chain were measured. Principal fragment ions were assigned and plausible mechanisms for the formation of the fragment ions were proposed. In general, the triter-penoids of $C_{20}-C_{25}-epoxy$ side chain. produce $h_{1}-species$ fragment ions by the deletion of side chain at $C_{20}-C_{22}$ bond and open side chain triterpenoids produce $h_{2}$ species fragmentions whose mass numbers are higher by two mass unit than those of $h_{1}$ species. The mass number of h species fragment ions will serve as the diagnostic tool for the elucidation of side chain structure of tetracyclic triterpenoids.