• 콘크리트학회논문집
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• 제22권1호
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• pp.131-141
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• 2010

이 연구에서는 GFRP 보강근의 정착길이 설계식을 제안하기 위하여 실험적 연구를 수행하고 실험결과의 통계적 분석을 실시하였다. 총 104개의 수정인발실험을 완료하였으며 실험변수는 보강근의 묻힘길이(보강근 지름의 15, 30, 45배), 순피복두께(보강근 지름의 0.5~2.0배), 상부근 효과, 보강근 종류(국내산 2종, 국외산 1종 등 3종) 및 보강근지름(D10, D13, D16)이었다. 수정인발실험을 통해 얻은 실험 결과 평균부착강도를 결정하고, 평균부착강도에 대한 2변수 선형회귀분석을 실시하였다. 2변수 선형 회귀분석의 결과에 대하여 5% 분위수를 적용하여 보수적인 방법으로 정착 길이 설계식을 제안하였다. 이 연구의 제안식과 ACI 440.1R-06 식을 비교하였다. 순피복두께가 $1.0\;d_b$를 초과하는 경우 이 연구의 제안식이 더 경제적이고 순피복두께가 $1.0\;d_b$ 이하인 경우에는 이 연구의 식이 더 보수적으로서 이 연구의식을 사용하는 경우 보다 경제적이고 안전한 설계가 가능할 것으로 판단된다. 피복두께는 GFRP 보강근의 부착강도 발현에 큰 영향을 주는 것으로 나타났다.

• 한국결정성장학회지
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• 제12권6호
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• pp.323-328
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• 2002

The model of the shortest chemical bonds is applied for the classification of acentric simple and binary Mo(VI) and W(VI) oxides. It is shown that on the plane of the shortest chemical bonds the compounds are located into the rosette of three intersected ellipses. The correlation between the optical nonlinearity and combination of the bond lengths is discussed.

• 산업기술연구
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• 제21권B호
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• pp.195-203
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• 2001

The purpose of this study is to estimate ultimate uplift capacity of permanent anchor which was cast into weathered rock. The ultimate uplift capacity was estimated from the load-displacement curve of four different anchors which have different bond length. The creep test was performed for 15minutes under the maximum load of each step in order to understand the load-transfer property of permanent anchor and to decide which anchor to choose. The destruction range of soil due to the changes in load was estimated by installing dial gauge on the ground which was cast into the weathered rock. Ultimately, the study on the behavior of the anchor case into the weathered rock was performed by comparing and analyzing the estimated result of the UUC obtained by the full scale pull out test in the field with the exsting theoretical and practical results of soil and rock anchor.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.605-608
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• 1999

The objective of this research is to examine whether the determination of development length for high strength concrete by the ACI Building Code 318-95 could be applied and the upped limit of compressive strength, 700kg/$\textrm{cm}^2$ is suitable. Eight beam specimens were tested. Each beam was designed to include two bars in tension, spliced at the center of the span. The beams were loaded in positive bending with the splice in a constant moment region. The variables used here were compressive strength and the space of stirrup within splice length. The results indicated that for (c$\div$Ktr)/db of the range of 1.5-2.0 compressive strength up to 800kg/$\textrm{cm}^2$ is acceptable with regard to bond strength and ductility, thus the limit of compressive strength in ACI 318-95 may be extended to 800kg/$\textrm{cm}^2$.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 봄 학술발표회 논문집
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• pp.25-29
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• 1994

A series of 6 reinforced concrete beams was tested to verify the effects of EBSP strengthened on cracked beams and to identify the various parameters affecting structure strengthening design(SSD). The parameters were the cross-sectional area of steel plates, the thickness of steel plates, and bond length of steel plates. In addition to these parameters, the effect of existing cracks on the strengthening was investigated. Test results show that EBSP is very effective and predictable for strengthening damaged structures. The results also show that the bond length of steel plates is the most important factor to develop ultimate load carrying capacities of strengthened beams. However, considerations in SSD should be given to assure the ductile failure at ultimate load such as the low ratio of thickness to the width of plates.

• 한국결정학회지
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• 제16권1호
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• pp.1-5
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• 2005

The structure of the title compound has been determined by single-crystal X-ray diffraction work. The crystals are orthorhombic, space group $Pna2_1$ with a=11.095(3), b=21.834(7), c=12.574(4) $\AA$, and R1=0.0667. The average carbon bond length in aromaticity In the molecule is 1.386(1) $\AA$ and the average single bond length linking the central benEene ring and peripheral phenyl rings is 1.491(3) $\AA$. The average dihedral angle between the central benzene ring and each of six peripheral phenyl rings is $67.1(1)^{\circ}$ and the average dihedral angle between neighboring two phenyl rings is $55.0(1)^{\circ}$. Thus the molecule adopts a quasi-propeller configuration with approximate six-fold rotation symmetry.

• 대한화학회지
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• 제58권2호
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• pp.169-178
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• 2014

A new series of metal complexes of V(IV), Pd(II), Pt(IV), Ce(IV) and U(VI) with 3-[(3-chlorophenyl)-hydrazono]-pentane-2,4-dione (Cphpd) were synthesized and characterized by elemental analysis, molar conductivity, magnetic moment measurements, UV-vis, FT-IR and $^1H$ NMR as well as TG-DTG techniques. The data indicated that the Cphpd acts as a bidentate ligand through the hydrazono nitrogen and one keto oxygen. The kinetic parameters have been evaluated by using Coats Redfern (CR) and Horowitz-Metzeger (HM) methods. The thermodynamic data reflected the thermal stability for all complexes. The calculated bond length and the bond stretching force constant, F(U=O), values for $UO_2$ bond are $0.775{\AA}$ and $286.95Nm^{-1}$. The bond lengths, bond angles, dipole moment and the lowest energy model structure of the complexes have been determined with DFT calculations. The antimicrobial activity of the synthesized ligand and its complexes were screened.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 봄 학술발표회논문집(II)
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• pp.621-626
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• 1998

An experimental investigation on the reinforcing bar corrosion and relationshid of reinforcing bar and concrete bond strength has been conducted to establish the allowable limit of rust in the construction field. The reinforcing bars used in this study were rusted before embedding in concrete. The first component of this experiment is to make rust of reinforcing bar rust artificially based on Faraday's theory at certain rates such as 2, 4, 6, 8 and 10% of reinforcing bar weight. For estimation of the amount of rust by weight, Clarke's solution and Shot blasting were adopted and compared. Parameters include 240 and 450kg/㎠ of compressive strengths and diameter of reinforcing bar (16, 19 and 25mm) corresponding development length for pull-ort test. And, pull-out tests were carried. out according to KSF 2441 and ASTMC 234 to investigate the effect of the corrosion rate on reinforcing bar-concrete bond behavior. It is found from the test results that the test techniques for corrosion of bar used in this study is relatively effective and correct test method. Results shows that up to 2% of rust increases the bond strength regardless of concrete strength and diameter of reinforcing bar like the existing data. It might be because of the roughness from rust. As expected, the bond strength increases as compressive strength of concrete increases and the diameter of bar decreases.

• Computers and Concrete
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• 제7권5호
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• pp.403-419
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• 2010

The bond mechanism for reinforcing bars in concrete is equivalent to the normal contact and friction between the inclined ribs and the surrounding concrete. Based on the contact density model for the computation of shear transfer across cracks, an open-slip coupled model was developed for simulating three-dimensional bond behavior for reinforcing bars in concrete. A parameter study was performed and verified by simulating pull-out experiments of extremely different boundary conditions: short bar embedment with a huge concrete cover, extremely long bar embedment with a huge concrete cover, embedded aluminum bar and short bar embedded length with an insufficient concrete cover. The bar strain effect and splitting of the concrete cover on a local bond can be explained by finite element (FE) analysis. The analysis shows that the strain effect results from a large local slip and the splitting effect of a large opening of the interface. Finally, the sensitivity of rebar geometry was also checked by FE analysis and implies that the open-slip coupled model can be extended to the case of plain bar.

• Archives of Pharmacal Research
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• 제28권5호
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• pp.561-565
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• 2005

Bacterial arylsulfate sulfotransferase (ASST) catalyzes the transfer of sulfate group from a phenyl sulfate ester to a phenolic acceptor. The promoter region and the transcripti on start sites of Enterobacter amnigenus astA have been determined by primer extension analysis. Northern blot analysis resolved two mRNA species with lengths of 3.3 and 2.0 kb, which correspond to the distances between the transcriptional initiation sites and the two inverted repeat sequences (IRSs). By length, the 3.3 kb RNA could comprise the three-gene (astA with dsbA and dsbB) operon. ASST has three highly conserved cysteine residues. Reducing and non-reducing SDS-PAGE and activity staining showed that disulfide bond is needed for the activity of the enzyme. To identify the cysteine residues responsible for the disulfide bond formation, a series of Cys to Ser mutants has been constructed and the enzymatic activity was measured. Based on the results, we assumed that the first cysteine (Cys349) might be involved in disulfide bond mainly with the second cysteine (Cys445) and result in active conformation.