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http://dx.doi.org/10.5012/jkcs.2014.58.2.169

Synthesis, Spectral, Characterization, DFT and Biological Studies of New 3-[(3-Chlorophenyl)-hydrazono]-pentane-2,4-dione Metal Complexes  

Sadeek, Sadeek A. (Department of Chemistry, Faculty of Science, Zagazig University)
Zordok, Wael A. (Department of Chemistry, Faculty of Science, Zagazig University)
El-Farargy, Ahmed F. (Department of Chemistry, Faculty of Science, Zagazig University)
El-Desoky, Sameh I. (Department of Quality Control, Ceramica Royal)
Publication Information
Journal of the Korean Chemical Society / v.58, no.2, 2014 , pp. 169-178 More about this Journal
Abstract
A new series of metal complexes of V(IV), Pd(II), Pt(IV), Ce(IV) and U(VI) with 3-[(3-chlorophenyl)-hydrazono]-pentane-2,4-dione (Cphpd) were synthesized and characterized by elemental analysis, molar conductivity, magnetic moment measurements, UV-vis, FT-IR and $^1H$ NMR as well as TG-DTG techniques. The data indicated that the Cphpd acts as a bidentate ligand through the hydrazono nitrogen and one keto oxygen. The kinetic parameters have been evaluated by using Coats Redfern (CR) and Horowitz-Metzeger (HM) methods. The thermodynamic data reflected the thermal stability for all complexes. The calculated bond length and the bond stretching force constant, F(U=O), values for $UO_2$ bond are $0.775{\AA}$ and $286.95Nm^{-1}$. The bond lengths, bond angles, dipole moment and the lowest energy model structure of the complexes have been determined with DFT calculations. The antimicrobial activity of the synthesized ligand and its complexes were screened.
Keywords
Cphpd; Transition metal complexes; FT-IR; Mass spectra;
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