• 분석과학
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• 제20권5호
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• pp.448-451
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• 2007

A new bis(dicyclohexylammonium) chromate dihydrate complex, $[(C_6H_{11})_2NH_2]_2[CrO_4]{\cdot}2H_2O$, (I), has been synthesized and its structure analyzed by FT-IR, EDS, elemental analysis, ICP-AES, and single crystal X-ray diffraction methods. The Cr(VI) complex (I) is tetragonal system, I${\bar{4}}$2d space group with a = 12.5196(1), b = 12.5196(1), c = $17.3796(3){\AA}$, a = ${\beta}$ = ${\gamma}$ = $90^{\circ}$, V = $2724.09(6){\AA}^3$, Z = 4. The crystal structure of complex (I) consists of tetrahedral chromate $[CrO_4]^{2-}$ anion, two organic dicyclohexylammonium $[(C_6H_{11})_2NH_2]^+$ cations and two lattice water molecules. The chromate anion and protonated dicyclohexylammonium cation is mainly constructed through the ionic bond. The cyclohexylammonium rings of the dicyclohexylammonium cation take the chair form and vertical configuration with each other. The N-H${\cdot}$O and O-H${\cdot}$O hydrogen bond networks between the $N_{dicyclohexylammonium}$, $O_{water}$ and $O_{chromate}$ atom lead to self-assembled molecular conformation and stabilize the crystal structure.

• Structural Engineering and Mechanics
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• 제67권4호
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• pp.391-401
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• 2018

Locally available Stainless Steel Wire Mesh (SSWM) bonded on a concrete surface with an epoxy resin is explored as an alternative method for the torsional strengthening of Reinforced Concrete (RC) beam in the present study. An experiment is conducted to understand the behavior of RC beams strengthened with a different configuration of SSWM wrapping subjected to pure torsion. The experimental investigation comprises of testing fourteen RC beams with cross section of $150mm{\times}150mm$ and length 1300 mm. The beams are reinforced with 4-10 mm diameter longitudinal bars and 2 leg-8 mm diameter stirrups at 150 mm c/c. Two beams without SSWM strengthening are used as control specimens and twelve beams are externally strengthened by six different SSWM wrapping configurations. The torsional moment and twist at first crack and at an ultimate stage as well as torque-twist behavior of SSWM strengthened specimens are compared with control specimens. Also the failure modes of the beams are observed. The rectangular beams strengthened with corner and diagonal strip wrapping configuration exhibited better enhancement in torsional capacity compared to other wrapping configurations. The numerical simulation of SSWM strengthened RC beam under pure torsion is carried out using finite element based software ABAQUS. Results of nonlinear finite element analysis are found in good agreement with experimental results.

• Nuclear Engineering and Technology
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• 제11권1호
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• pp.1-20
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• 1979

수화물 결정에 있어서 $H_2O$ 분자의 외부 각 운동을 조사하고저 NaBr-2$H_2O$ 및 BaCl$_2$-2$H_2O$ 분말시료에 대한 중성자비탄성산란실험을 수행하였으며, 관측된 진동수를 모두 이 외부 각 운동에 의한 것으로 보고 다중 및 다준위산란효과를 제거하므로서 평균진동수 분포함수를 구하였다. FG 행열법에 의해서 계산된 진동수의 이론 값들은 모두 복합 mode에 의한 것이였으며 따라서 그 중 포텔샬.에너지분포가 큰 mode로서 관측치에 대한 assignment를 하였다. 소수결합력은 Lippincott-Schroeder 포텐샬함수에서 추산하였으며, 절선형 및 분기형수소결합에 대한 이 함수의 유용성을 $H_2O$ 외부 각 운동 포텐샬함수 모양에 의거하여 검토하였다. 수소결합력의 성질에 대하여 더욱 자세한 자료를 얻기 위해서는 진동수 계산에 H…Y 신축상호작용 운만 아니라 O-H…Y 변각상호작용의 도입이 필요함을 논의하였고 또 $H_2O$ 외부 각 운동에 인어서 mode의 순수성 및 대칭성을 군론을 작용한 방법에 의거하여 논의하였다.

• Restorative Dentistry and Endodontics
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• 제33권5호
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• pp.472-480
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• 2008

이 실험의 목적은 동일한 깊이의 상아질에서 제 6세대의 self-etching system을 사용하여 C-factor가 상아질과 복합레진 사이의 미세인장결합강도에 미치는 영향을 알아보는 것이다. 건전한 대구치 80개를 선정하여 와동의 바닥면적은 각각 $16mm^2$로 동일하게 하고 깊이를 조절하여 C-factor가 각각 0.25, 2, 3, 4인 4개의 군으로 나누었다. 각 군별로 총 20개의 치아를 할당하였으며 접착제와 복합레진의 조합에 따라 다시 4개의 소군에 치아 5개씩을 배정하였다 상아질 접착제는 AQ Bond Plus 또는 Xeno III를 사용하였고, 복합레진은 fantasists 또는 Ceram-X mono를 사용하였다. 제조사의 지시대로 상아질 접착제를 도포한 후 60초간 광중합하였다. 24시간 동안증류수에 보관후 단면적이 $1.0{\times}1.0mm^2$인 복합레진-상아질 beam을 형성하여 1mm/min의 속도로 미세 인장결합강도를 측정하였다. One-way ANOVA와 Tukey test, 그리고 Pearson correlation test로 통계 처리하여 다음과 같은 결과를 얻었다. 1. XenoIII와 Ceram-X mono군에서는 C-factor가 증가할수록 미세 인장결합강도가 유의하게 감소했으나 (p<0.05), 나머지 재료군에서 C-factor군간에 미세 인장결합강도의 유의한 차이가 없었다. 2. C-factor 3군에서는 Ad Bond Plus와 Fantasista군이 Xeno III와 Ceram-X mono군에 비해 높은 결합력을 보였으나 (p<0.05), C-factor 0.25군, 2군, 4군에서 4가지 접착제와 수복 레진의 조합 간에 유의한 차이가 없었다. 3. Fantasista군에서 C-factor와 미세 인장결합강도 사이에 일정한 상관관계를 발견할 수 없었고, Ceram-X mono군에서 C-factor가 증가할수록 미세 인장결합강도가 감소하는 경향을 보였다 (p<0.05). 이번 연구의 결과로 상아질의 깊이가 동일하고 6세대의 self-etching system을 사용하여 복합레진을 충전하는 경우 와동의 C-factor가 수복물의 미세 인장결합강도에 크게 영향을 미치지 않음을 알 수 있었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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• pp.589-596
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• 1998

Experimental studies are investigated for RC column retrofitting under cyclic load. Design considerations are jacketing of steel plate of carbon fiber with epoxy bonding, use of unbonded plate, additional concrete grouting, ratio of additional longitudinal steel reinforcement and longitudinal configuration of additional ties. Investigated results are 1) jacketing and additional reinforcements are effective for strengthening, 2) use of additional grouting is less effective with respect to increased section. Future studies are needed to evaluate the requirements about additional reinforcements for member stress level, 3) bond between original and additional grout concrete.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.848-851
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• 2003

In this paper, a separating system for used CRT recycling is presented. Depend on manufacturer CRTs has small differences in dimension for the same model, but the dimensions of the panel are nearly same. To simplifying configuration of the system, we developed CRT fixing pallets for every model of CRT. The height of cutting position for every model of CRT will be same. The cutting machine has two rotating arm and use metal-bond type diamond cutting wheel. Instead of water, two vortex tube type air-coolers are used for the cooling of cutter. Workers in recycling factory are generally old people. Therefore, control program should be easy to use and operate. Thus we developed GUI with very simple interface.

• Archives of Pharmacal Research
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• 제21권3호
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• pp.338-343
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• 1998

$2^1$-Fluorohexopyranosyl nucleosides 1a and 1b which contained a bioisosteric double bond and a fluorine were synthesized in 12 steps, starting from D-galactose. During diethylaminosulfur trifluoride (DAST) fluorination, retention of stereochemistry was observed through the participation of methoxy or chloro group at the 6-posiition of the purine base. The final nucleosides 1a and 1b were found to be inactive against HIV-1 and HSV-1,2.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 제2회 학술대회 논문집 일렉트렛트 및 응용기술전문연구회
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• pp.21-24
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• 2000

Traction motors driven by several type inverters have been subjected to increasing demands for higher operating temperature, more demands for duty cycles, higher starting current, frequent voltage transients and finally severe environmental exposure. For applications to inverter duty, traction motors needs a special insulation system, which has characteristics of increased bond strength, lower operating temperature and higher turn-to-tum insulation. Also it needs major contributors to insulation life and reliability of motors, which more considered by temperature, voltage, frequency, rise time, pulse configuration, wire thickness and insulation materials. In this paper, to evaluate of reliability and expected life, it is analyzed the several stresses and their degradation mechanism on insulation system of AC traction motor.

• Structural Engineering and Mechanics
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• 제43권5호
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• pp.623-636
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• 2012

The aim of the current work is to describe the flexural behaviour of simply supported concrete beams with tension reinforcement spliced at mid-span. The parameters included in the study were the type of the concrete, the splice length and the configuration of the hooked splice. Fifteen beams were cast using an ordinary concrete mix and two fiber reinforced concrete mixes incorporating steel and polypropylene fibers. Each concrete mix was used to cast five beams with continuous, spliced and hooked spliced tension steel bars. A test beam was reinforced on the tension side with two 12 mm bars and the splice length was 20 and 40 times the bar diameter. The hooked bars were spliced along 20 times the bar diameter and provided with 45-degree and 90-degree hooks. The test results in terms of cracking and ultimate loads, cracking patterns, ductility, and failure modes are reported. The results demonstrated the consequences due to short splices and the improvement in the structural behaviour due to the use of hooks and the confinement provided by the steel and polypropylene fibers.

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3265-3268
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• 2013

The multi-hydrogen bonded systems with the solvated electrons are investigated at the B3LYP/6-311++$G^{**}$ basis set level. The symmetrical linear geometrical characteristic is common for the dimer systems, while for the tetramer system, the tetrahedron configuration is generated. The NBO charge analyses demonstrate that the multi-hydrogen-multi-electron (mH-ne) coupling exist in these anion systems, as is supported by the electrostatic potential and the molecular orbital analyses. The positive chemical shift value of the central hydrogen ($H_c$) and the negative chemical shift value of the terminal hydrogen ($H_t$) indicate that the $H_c$ is electronegative while the $H_t$ is electropositive, respectively. Strong coupling between two central hydrogen atoms is demonstrated by the large spin-spin coupling constants. The solvated electron donates significant contributions for the stability of these systems.