• Journal of Photoscience
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• 제8권1호
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• pp.9-12
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• 2001

The photoisomerization behavior of benzylideneacetophenones, known as chalcones, was studied. We synthesized the chalcone derivatives that have ether groups at 4 and 4＇ positions. Due to the electron donating ability of the ether oxygen, the bond order of the single bond between two phenyl ring of the chalcone strengthened, which eventually increased the rotational barrier of the single bond. The rotational barrier of the single bond is about 20-22 kcal/mole. Thermal recovery of this process took about 1 min. The UV-visible spectra of these chromophores exhibit two characteristic absorption peaks at 276 nm and 340 nm. The relative intensity of the peaks varies depending on the alkyl chain length of the substituent. Photo-irradiation with the 365 nm light monotonously decreases the 340 nm peak. However, the photo-irradiation with 254 nm light induce two competing processes and produced rather complicated absorption profile.

• 대한치과기공학회지
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• 제30권1호
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• pp.65-71
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• 2008

The use of titanium in the field of dentistry has increased, due to their excellent biocompatibility, appropriate mechanical properties, corrosion-resistance and low price. However, many difficulties with the use of titanium for metal-ceramic crowns remain to be solved. The objective of this study was to evaluate the influence of surface modifications on the bonding characteristics of specific titanium porcelain bonded to cast titanium. The surfaces of Titanium were prepared with 4 test groups, i) sandblasted with particles of different size, ii) sandblasted after treated oxidization and oxidized after sandblast. We observed the bond strength and node aspect of titanium and ceramic, and respect to the methods of modifying surface of titanium by the test of mean roughness of surface, Scanning Electron Microscope, and 3-point flexural bend test. The results show that, 1. The specimens, which treated oxidization after process of sandblast with particles of 50um size, were the better for the bond strength in comparison with other specimen. 2. The specimen with process of sandblasting after oxidization treatment were the better for stability of the bond strength. 3. The wettability of titanium surface affect the bond strength.

• 한국도로학회논문집
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• 제19권2호
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• pp.25-34
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• 2017

PURPOSES: The purpose of this paper is to evaluate interface performance while using various tack coat materials for asphalt overlay. METHODS : The evaluation was conducted with tracking test, permeability, and interface bond strength. Tracking test was conducted using an image processing technique, to investigate the susceptibility of the tack coat materials. BBS and pull-off test were conducted to evaluate bond strength. The permeability test was conducted to evaluate the effect of tack coat materials. RESULTS : Results reveal that the trackless tack coat material demonstrates less tracking compared to other materials. Moreover, both BBS and pull-off tests can effectively evaluate the bond strength at the interface. RSC-4 was measured less bond strength. Moreover, tack coat prevents water penetration through the surface and aids the extension of the surface life of asphalt pavement. CONCLUSIONS : Trackless tack coat demonstrated a high and consistent bond strength performance. The tack coat types demonstrate marginally different performance as function of curing times. Field applicability was tested based on visual observation. Therefore, these should be considered when trackless tack coat is slightly enhanced the pavement performance based on limited this study results. Finally, it is necessary to allow reasonable time for the tack coat to completely cure.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2008년도 추계학술대회 논문집
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• pp.1279-1284
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• 2008

This paper presents the operating characteristic of high voltage impulse(HVI) track circuit owing to the ill-contact of impedance bond lead wire. The characteristic operations of the track include rail voltage and current. Measurements are carried out using oscilloscope with current probe and it analyzed the abnormal operation due to connector of protective wire. Finally, suitable track circuit is proposed for conventional line, and operating characteristic of HVI track circuit is affected by bypass circuit.

• Computers and Concrete
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• 제16권2호
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• pp.311-327
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• 2015

Employing discrete elements for considering bond-slip effects in reinforced concrete structures is very time consuming. In this study, a new modified embedded element method is used to consider the bond-slip phenomenon in structural behavior of reinforced concrete structures. A comprehensive parametric study of RC slabs is performed to determine influence of different variables on structural behavior. The parametric study includes a set of simple models accompanied with complex models such as multi-storey buildings. The procedure includes the decrease in the effective stiffness of steel bar in the layered model. Validation of the proposed model with existing experimental results demonstrates that the model is capable of considering the bond-slip effects in embedded elements. Results demonstrate the significant effect of bond-slip on total behavior of structural members. Concrete characteristic strengths, steel yield stress, bar diameter, concrete coverage and reinforcement ratios are the parameters considered in the parametric study. Results revealed that the overall behavior of slab is significantly affected by bar diameter compared with other parameters. Variation of steel yield stress has insignificant impact in static response of RC slabs; however, its effect in cyclic behavior is important.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2003년도 춘계학술논문발표회논문집
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• pp.164-170
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• 2003

In this paper, we studied on the firing characteristics and electrical fire analysis of power cord deteriorated by thermal stress. The cross section of PVC insulating cord deteriorated by indirect flame decreased through heat convection. PVC insulating cord deteriorated by direct flame was bumpy shape. The exothermic peak of normal cord was shown at ($526.7^{\circ}C$), but the peaks or on(heat treatment temperature) ($150^{\circ}C$) cord was shown at ($299.6^{\circ}C$) and [$502.2^{\circ}C$]. The exothermic peaks according to high temperature were similar to those of amorphous carbon. In the FT-IR analysis, the absorption peak of normal cord indicated double bond of oxygen and carbon in benzene ring at 1720.0$cm^{1}$. As the HTT was high, the height of characteristic peak decreased and the peak of carbonyl group was shown at about 1625.7$cm^{-1}$. The characteristic peak of single bond(O-H) was shown at about 3479.2$cm^{-1}$. In case of the internal part of wire covering deteriorated by over current, the characteristic peak were shown at about 3417.3$cm^{-1}$ and 1600.2$cm^{-1}$. The above results show that we can distinguish the differences according to the fire pattern through the internalㆍexternal analysis of wire covering deteriorated by heat.

• Computers and Concrete
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• 제4권5호
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• pp.377-402
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• 2007

The paper presents quasi-static plane strain FE-simulations of strain localization in reinforced concrete beams without stirrups. The material was modeled with two different isotropic continuum crack models: an elasto-plastic and a damage one. In case of elasto-plasticity, linear Drucker-Prager criterion with a non-associated flow rule was defined in the compressive regime and a Rankine criterion with an associated flow rule was adopted in the tensile regime. In the case of a damage model, the degradation of the material due to micro-cracking was described with a single scalar damage parameter. To ensure the mesh-independence and to capture size effects, both criteria were enhanced in a softening regime by nonlocal terms. Thus, a characteristic length of micro-structure was included. The effect of a characteristic length, reinforcement ratio, bond-slip stiffness, fracture energy and beam size on strain localization was investigated. The numerical results with reinforced concrete beams were quantitatively compared with corresponding laboratory tests by Walraven (1978).

• 한국도로학회논문집
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• 제16권6호
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• pp.121-128
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• 2014

PURPOSES : The objective of this study is to evaluate the tack-coating material's properties using the bitumen bond strength(BBS) test and damping test as function of changed curing times. In this study, bonding strength tests were performed according to the curing time of tack coating materials. METHODS : In order to investigate bonding characteristic of tack coating materials, the Pneumatic Adhesion tensile Testing Instrument(PATTI) device is used to measure the bond strength between the tack coating materials and aggregate substrate based on the AASHTO TP-91. Also, damping test as in situ test was used to determine an appropriate traffic openting time for construction vehicle. Four different tack-coating materials were used in this study. The BBS tests were performed a one hour curing and testing temperatures of $5^{\circ}C$, $15^{\circ}C$, and $25^{\circ}C$. Damping test was conducted at 30min, 60min, 90min, and 120 min of curing times with temperatures of $20^{\circ}C$ and $30^{\circ}C$. RESULTS and CONCLUSIONS : The BBS test results show various bond strength as function of tack coat materials. At the same testing condition, A tack coat material shows almost two times higher than D tack coat materials although both materials are satisfied the criteria of material's physical properties. Also, Dampting test results shows similar trend with BBS test result. The damping test result was significantly changed as function of tack coat materials. Based on this study, the tack coating material's curing time is very important. Therefore, both curing time and the bond strength's characteristic has to be considered in standard specification.

• Journal of Welding and Joining
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• 제33권2호
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• pp.69-77
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• 2015

High strength steels have been continually being developed to improve in fuel economy in automotive and ensure safety of passengers. New bonding and welding methods have been required for improving weldability on high strength steels. In this study, resistance spot welding and Weld-bond with nugget diameters of 4.0mm, 5.0mm, 6.0mm and 7.0mm were produced and tested, respectively. In order to confirm the effect of nugget diameters on tensile shear characteristic of the Weld-bond, tensile shear characteristics of Weld-bond were compared with those of resistance spot welding and adhesive bonding. Peak load of Weld-bond were increased as the nugget diameter increases. After appearing maximum peak load continuous fracture followed with second peak owing to load being carried by resistance spot weldment. Fracture modes of the adhesive layer in Weld-bond fractures were represented by mixed fracture mode, which are cohesive failure on adhesive part and button failure at resistance spot welds. The results showed that the tensile shear properties can be improved by applying Weld-bond on TRIP steel, and more apparent with nugget diameter higher than 5${\surd}$t.

• Bulletin of the Korean Chemical Society
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• 제32권1호
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• pp.277-280
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• 2011

We studied the relative stability and atomic structure of five $C_{20}^{2+}$ isomers obtained by two-electron ionization of a $C_{20}$ cage (the smallest fullerene). All the isomers are bond-stretch isomers, i.e., they differ in bond length. In particular, in one of the isomers with Ih symmetry, all the bond lengths are equal. Full geometry optimizations of the dipositive ion $C_{20}^{2+}$ were performed using the hybrid density functional (B3LYP/6-31G(d)) methods. All isomers were found to be true minima by frequency analysis at the level of B3LYP/6-31G(d) under the reinforced tight convergence criterion and a pruned (99,590) grid. The zero-point correction energy for the cage bond-stretch isomers was in the increasing order $D_{2h}<C_{2h}<C_2<T_h<I_h$ of $C_{20}^{2+}$. The energy difference among the isomers of cage dipositive ions was less than that among neutral cage isomers. Our results suggest that these isomers show bond-stretch isomerism and that they have an identical spin state and an identical potential energy curve. Although the predominant electronic configurations of the isomers are similar, the frontier orbital characteristics are different, implying that we could anticipate an entirely different set of characteristic chemical reactions for each type of HOMO and LUMO.