• Journal of Applied Biological Chemistry
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• v.43 no.1
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• pp.37-43
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• 2000

1,3,2-Dioxaphosphorinanes are suitable compounds for studying the stereochemistry of substitution at phosphorus. Cis- and trans-5-hydroxymethl-5-methyl-2-thiono-2ethoxy-1,3,2-dioxaphosphorinane were prepared, and their structures and stereochemistry unambiguously assigned by NMR and X-ray crystallography with acetoxy and 3,5-dinitrobenzoyloxy derivatives, respectively. Trans isomer gave $^{31}P$ NMR signal at higher field than cis isomer, and the ring proton Spectrum of cis isomer showed characteristic pattern for identifying its geometry. In X-ray crystallography they adopted a chair conformation with the ethoxy groups in the axial positions, and the sulfide groups in the equatorial positions. A flattening of the ring around the phosphorus center was noted, the POC bond angles were about $120^{\circ}$, and the C-O bonds in the ring were significantly longer than the C-O bond for the ethoxy group or the C-O bond for hydroxyl group.

• International Journal of Highway Engineering
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• v.17 no.6
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• pp.47-54
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• 2015

PURPOSES : The objective of this study is to evaluate the early adhesive characteristic of asphalt emulsions, including polymer-modified emulsions, for chip seals using the surface energy concept, the bitumen bond strength (BBS) test, and the Vialit test. METHODS : Two general methods, the BBS test and Vialit test, were applied to investigate the bond strength and the aggregate loss, respectively. A new theory, the surface free energy (SFE) theory, was used to evaluate the adhesive characteristic between the emulsion and the aggregate. Based on the theory, the contact angles were measured, and then the surface energy components were calculated. Using those components, the work of adhesion (Wa) was calculated for each emulsion. To ensure reliable results, all the tests were performed under the same conditions, i.e., at $25^{\circ}C$ for 240 minutes of curing time. For the materials, three emulsions (CRS-2, CRS-2L, and CRS-2P) and one aggregate type (granite) were employed. RESULTS AND CONCLUSIONS : Under the same conditions, the modified emulsions showed better adhesive characteristics and curing behaviors than the unmodified emulsions. In addition, there was no significant difference between the various modified emulsions. One of the important findings is that the analysis by Wa presents more sensitive results than other methods. The results of the Wa showed that the CRS-2P emulsion has the best adhesive characteristics. Consequently, the use of modified emulsions for chip seals could prevent aggregate loss and allow open traffic earlier.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2008.06a
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• pp.191-192
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• 2008

• Computers and Concrete
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• v.12 no.5
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• pp.585-612
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• 2013

The paper presents quasi-static numerical simulations of the behaviour of short reinforced concrete beams without shear reinforcement under mixed shear-tension failure using the FEM and four various constitutive continuum models for concrete. First, an isotropic elasto-plastic model with a Drucker-Prager criterion defined in compression and with a Rankine criterion defined in tension was used. Next, an anisotropic smeared crack and isotropic damage model were applied. Finally, an elasto-plastic-damage model was used. To ensure mesh-independent FE results, to describe strain localization in concrete and to capture a deterministic size effect, all models were enhanced in a softening regime by a characteristic length of micro-structure by means of a non-local theory. Bond-slip between concrete and reinforcement was considered. The numerical results were directly compared with the corresponding laboratory tests performed by Walraven and Lehwalter (1994). The advantages and disadvantages of enhanced models to model the reinforced concrete behaviour were outlined.

• Journal of Power System Engineering
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• v.14 no.3
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• pp.77-82
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• 2010

In general, the control valves are essential components in hydraulic systems. Structural changes within the valves remain a challenge because many parameters of valve tend to interact in terms of static and dynamic performance. Therefore, the valve characteristics is applied directly to the stability of hydraulic system. Inner structure of the valve which is used mainly in the industries is made up poppet type and spool type. This paper made a description of the method for numerical analysis and modeling of the valve with a built-in moving part of four-type. Based on the physical parameters of the valves, a numerical model of objected valve is developed using the bond graph method. It is to verified the results that the moving part of four-type has an effect on pressure and flow characteristics. Also, It is analyzed the results which has an effect on response characteristic by angular of poppet valve face and inertia variation of the valve with a built-in moving part. In the results, it is confirmed that the rising and settling time vary with the shape of moving part in valve.

• Journal of Fashion Business
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• v.19 no.5
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• pp.157-174
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• 2015

This research intends to observe the effects of social capital regarding fashion social enterprises on the community sense of participating consumers, and verify the relationship of the effects that such social capital and community sense have on sustainability formation variable(shared values, suitability of values, behavioral flow, cognitive belief and long-term relationship orientation) of social enterprises. For such analysis, a sample of 400 consumers with experience of purchasing products of fashion social enterprises more than once was utilized, and path analysis was conducted utilizing AMOS 20.0. As a result of this research, first, information sharing, social participation among the characteristic factors of social enterprises' social capital had a meaningful impact on shared values, and self-pursuit and significance meaningfully affected the suitability of values. Second, mutual influence, sense of belonging, satisfaction of needs and emotional bond among the characteristic factors of community sense between social enterprises and consumers meaningfully affected shared values, whereas mutual influence, sense of belonging and emotional bond substantially influenced suitability of values. Third, shared values and suitability of values affected the relationship between behavioral flow and cognitive trust, and behavioral flow and cognitive trust both had meaningful impact on long-term relationship orientation.

• Transactions of the Korean Society of Automotive Engineers
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• v.2 no.6
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• pp.38-49
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• 1994

In this study, grindability of some representative engineering ceramics are experimentally investigated using resin bond diamond wheel with conventional surface grinding machine, and proper grinding conditions which can be obtained from various experimental results are established also for mechanical components which are proper to domestic circumstances with high reliability. And through the results of experiment, it is confirmed that grinding energies of the ceramics, especially in the case of $Al_2O_3$, are lower than steel with same machining condition in the conventional grinding because of their fine-brittle fracture mode type removal process, though the ceramics are well-known to unmachinable materials. And moreover, the total pass numbers needed for spark-out process to be completed are depend on their mechanical properties because that grinding stiffness is different from each other. The grinding force, ginding power and ground surface roughness are also measured and compared. Furthermore, the experiments carried out in this study, some useful results are obtained with can guide to grind engineering ceramics with conventional surface grinding machine.

• Journal of the Korea Concrete Institute
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• v.23 no.5
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• pp.675-682
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• 2011

Recently, in retrofit of RC structures using FRP (Fiber Reinforced Polymer), researches about Near-Surface-Mounted Rertofit (NSMR) method have been widely performed. In NSMR, FRP bar is normally inserted in the slit formed in the cover concrete and then bonded by using epoxy mortar. In this paper, the bond characteristic of NSMR using FRP plate instead of bar was studied experimentally. Fracture behavior is observed from bond test using the parameters of embedment length, shear key, and FRP plate layer. In addition, an equation to predict the splitting strength of NSMR using FRP is proposed using the test result. The results showed that when the longer embedment length and more layers of FRP are used, the higher bond strength is achieved. There was a good co-relationship between the test and calculated results using the proposed equation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.4A
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• pp.775-785
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• 2006

This study focused on the development of surface deformations of GFRP rebars with a better bond characteristic for reinforcing concrete, and simultaneously, of GFRP rebars with more simple and economic production process. This research paper describes a development and bond performance of GFRP rebar with molded deformations, which is composed of polymer resin and milled glass fiber. To determine proper mix ration of milled fibers, material test of hardened epoxy and pullout tests of GFRP rebar with various mix ratio were conducted. The test results indicate that the new strategy of using a mixture of epoxy resin and milled fiber could be successfully applied to a surface structure of GFRP rebar to enhance bond with concrete. The bearing resistance of the ribs was further enhanced by the milled fibers at mechanical and environmental loading state.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.6
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• pp.30-39
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• 2016

An experimental study was performed to investigate flexural performance and bond characteristics of RC beams strengthened using ductile polyethylene terephthalate(PET) with low elastic modulus. Bond tests were planned and completed following CSA S806. Test variables were fiber type and fiber amount. Also, total of 8 RC beams was tested. Major test variables of the beam tests included section ductility(${\mu}=3.4$, 7.0), fiber type(CF, GF, PET) and amount of fiber strengthening. Moment-curvature analyses of the beam sections were also performed. In bond tests, the bond stress distribution as well as the maximum bond stress increased with increasing amount of PET. In case of 10 layers of PET, the effective bond length was 60 mm with the maximum and the average bond stress of 2.33 and 2.10 MPa, respectively. RC beam test results revealed that the moment capacity of the RC beams strengthened using PET 10 and 20 layers increased over the control beam with little reduction in ductility by fiber strengthening. All beams strengthened using PET resulted in ductile flexural failure without any sign of fiber debonding or fiber rupture. It was important to include the mechanical properties of adhesive in the moment-curvature analysis of PET-strengthened beam sections.