• 제목/요약/키워드: Blue emitting

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Blue organic light emitting diodes with carbazole based small molecules and color tunning by controlled side group

  • Kim, Y.B.;Ahn, Y.J.;Park, J.H.;Khang, M.W.;Woo, H.S.;Park, J.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.514-516
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    • 2003
  • We have fabricated an air stable blue emitting organic electroluminescent devices (OLEDs) with a carbazole based emitting molecule, Bis(3-N-ethylcarbazolyl)terephthalidene (BECP). Our device emits strong blue at 472 nm with the luminance efficiency of near 1 lm/W at a voltage and current density of 8 V and 5.7 mA/cm2, respectively, reaching the brightness up to 5000 cd/m2 at 270 mA/cm2. Finally, in order to tune the emission color from blue to green, we have used Bis(3-N-ethylcarbazolyl)cynoterephthalidene (BECCP), a derivative of BECP by adding cyno group in side chain, and compared the electroluminscence (EL) of OLEDS prepared by BECCP to that of BECP based OLEDs.

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Emission Properties of White Organic Light-Emitting Diodes with Blue Emitting Layer (청색 발광층에 의한 백색 OLED의 발광 특성)

  • Chun, Hyun-Dong;Na, Hyunseok;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.6
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    • pp.451-456
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    • 2013
  • To study emission properties of white phosphorescent organic light emitting devices (PHOLEDs), we fabricated white PHOLEDs of ITO(150 nm) / NPB(30 nm) / TcTa(10 nm) / mCP(7.5 nm) / light-emitting layer(25 nm) / UGH3(5 nm) / Bphen(50 nm) / LiF(0.5 nm) / Al(200 nm) structure. The total thickness of light-emitting layer with co-doping and blue-doping/co-doping using a host-dopant system was 25 nm and the dopant of blue and red was FIrpic and $Bt_2Ir$(acac) in UGH3 as host, respectively. The OLED characteristics were changed with position and thickness of blue doping layer and co-doping layer as light-emitting layer and the best performance seemed in structure of blue-doping(5 nm)/co-doping(20 nm) layer. The white PHOLEDs showed the maximum current density of $34.5mA/cm^2$, maximum brightness of $5,731cd/m^2$, maximum current efficiency of 34.8 cd/A, maximum power efficiency of 21.6 lm/W, maximum quantum efficiency of 15.6%, and a Commission International de L'Eclairage (CIE) coordinate of (0.367, 0.436) at $1,000cd/m^2$.

Ultrahigh Efficiency from Novel Blue Emitters Using a Rational Molecular Design

  • Kim, Soo-Kang;Park, Young-Il;Park, Jong-Wook
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.921-924
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    • 2008
  • We investigated new deep blue emitting materials including a novel side group such as CB-203. CB-203 shows relatively 40% increased PL quantum efficiency and higher Tg of $30^{\circ}C$ compared to MADN. It exhibits high External Quantum Efficiency (EQE) of 7.18% that is two times bigger than MADN's, which is the best efficiency in case of non-doped blue fluorescence OLED device to our knowledge. And deep blue emitting materials with a new core structure (CB-301) have been synthesized. CB-301 exhibit excellent blue fluorescence properties. Undoped OLED devices using CB-301 as blue emitters was found to deep blue CIE value (0.154, 0.078) and exhibit high luminance efficiencies of 2.01cd/A at $10\;mA/cm^2$.

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Fluorescent White OLEDs with a High Color-rendering Index Using a Silicon-Cored Anthracene Derivative as a Blue Host

  • Kwak, Jeong-Hun;Lyu, Yi-Yeol;Lee, Hyun-Koo;Char, Kook-Heon;Lee, Chang-Hee
    • Journal of Information Display
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    • v.11 no.3
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    • pp.123-127
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    • 2010
  • Fluorescent white organic light-emitting diodes showing high color-rendering indices (CRIs) of up to 81 was demonstrated, with a silicon-cored anthracene derivative (PATSPA) doped with DPAVBi utilized as the deep-blue host and dye materials, and the commercial dyes rubrene and DCM2 utilized as the orange- and red-light-emitting dyes. The devices, consisting of three emissive layers, showed bright-white-light emission, but the ratio of the blue peak to the orange and red peaks changed with the current density and the thickness of the blue emissive layer. A high CRI was achieved with the use of a deep-blue emitter doped in a novel host and by optimizing the blue-layer thickness. The device with a blue-layer thickness of 10 nm showed the Commission Internationale de l'Eclairage (CIE) color coordinate of (0.33, 0.35), a high CRI of 81, and a moderate external quantum efficiency of 2% at a current density of $2.5\;mA/cm^2$.

Study of Deep Blue Organic Light-Emitting Diodes Using Doped BCzVBi with Various Blue Host Materials

  • Kim, Tae-Gu;Oh, Hwan-Sool;Kim, You-Hyun;Kim, Woo-Young
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.2
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    • pp.85-88
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    • 2010
  • Deep blue organic light emitting diodes (OLEDs) were fabricated using 5 wt.% doped BCzVBi with various blue host materials such as NPB, DPVBi, MADN and TPBi. A blue OLED device, using DPVBi as host material, was constructed via NPB ($500\;{\AA}$) / DPVBi:BCzVBi ($200\;{\AA}$) / Bphen ($300\;{\AA}$) / LiF ($20\;{\AA}$) / Al ($1,000\;{\AA}$) and it shows a maximum luminescence of $4,838\;cd/m^2$, a current density of $32.7\;mA/cm^2$, a luminous efficiency of 3.3 cd/A and CIExy coordinates of (0.19, 0.15) at 4.5 V whereas the luminous efficiencies and CIExy coordinates of other blue OLEDs using NPB, MADN and TPBi as host materials have 1.1, 2.6 and 2.0 cd/A and (0.15, 0.11), (0.15, 0.10) and (0.15, 0.10), respectively. Energy transfer mechanisms between BCzVBi and its host materials were discussed with an energy band structure of host materials.

Enhancement of the efficiency stabilization and the color coordinates in blue organic light-emitting devices with double emitting layers

  • Bang, H.S.;Han, S.M.;Lee, D.U.;Kim, T.W.;Kim, J.H.;Seo, J.H.;Kim, Y.K.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1030-1033
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    • 2006
  • The efficiency stabilization and the color coordinates in blue organic light-emitting devices (OLEDs) with a double emitting layer (DEL) consisting of 4,4'-Bis(carbazol-9-yl)biphenyl (CBP) and 4,4'-Bis(2,2-diphenyl-ethen-1-yl)diphenyl were investigated. The efficiency of the OLEDs with a DEL did not significantly change with an increase in current density. The Commission Internationale de l'Eclairage coordinates of the OLEDs with a DEL 11 V were (0.150, 0.137), indicative of a deep blue color.

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Improvement of electroluminescent efficiency by using interfacial exciton blocking layer in blue emitting electrophosphorescent organic light emitting diodes

  • Kim, Ji-Whan;Kim, Joo-Hyun;Yoon, Do-Yeung;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1381-1382
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    • 2005
  • We report improved efficiency in blue electrophosphorescent organic light emitting diodes by introducing an interfacial exciton blocking layer between light emitting layer (EML) and hole transport layer (HTL). Iridium(III) bis [(4,6-di-fluorophenyl)- pyridinato -N,C2']picolinate (FIrpic) was used as blue phosphorescent dopant and JHK6-3 with carbazole and electron transporting group as host and also as the interfacial layer, resulting in drastic increase in quantum efficiency.

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Efficient White Phosphorescent Organic Light-emitting Diodes for Solid-State Lighting Applications Using an Exciton-confining Emissive-Layer Structure

  • Lee, Jong-Hee;Lee, Jeong-Ik;Lee, Joo-Won;Lee, Jun-Yeob;Kang, Dong-Min;Yuanc, Wei;Kwon, Soon-Ki;Chu, Hye-Yong
    • Journal of Information Display
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    • v.10 no.2
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    • pp.92-95
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    • 2009
  • Highly efficient blue and white phosphorescent organic light-emitting diodes (PHOLEDs) with an exciton-confining structure were investigated in this study. Effective charge confinement was achieved by stacking two emitting layers with different charge-transporting properties, and blue PHOLEDs with a maximum luminance efficiency of 47.9 lm/W were developed by using iridium(III) bis(4,6-(difluorophenyl) pyridinato-N,C2')picolinate (FIrpic) as an electrophosphorescent dopant. Moreover, when the optimized green and red emitting layers were sandwiched between the two stacked blue emitting layers, white PHOLEDs (WOLEDs) with peak external and luminance efficiencies of 19.0% coupling technique.and 54.0 lm/W, respectively, were obtained without the use of any out-coupling technique.

Synthesis and Electroluminescence Properties of Novel Deep Blue Emitting 6,12-Dihydro-diindeno[1,2-b;1',2'-e]pyrazine Derivatives

  • Park, Young-Il;Son, Ji-Hee;Kang, Ji-Soung;Kim, Soo-Kang;Lee, Ji-Hoon;Park, Jong-Wook
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.545-548
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    • 2008
  • We report the synthesis of blue emitting materials with a new core structure containing indenopyrazine. Non-doped device using one of these materials as a blue emitter was found to exhibit high external quantumn efficiency of 4.6% and excellent color purity of (0.154, 0.078) as well as narrow emission band of 47nm FWHM.

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Efficient Deep-Blue Organic Light-emitting Diodes with Double-Emission Layers

  • Seo, Ji-Hoon;Park, Jung-Sun;Seo, Bo-Min;Lee, Kum-Hee;Park, Jung-Keun;Yoon, Seung-Soo;Kim, Young-Kwan
    • Journal of Information Display
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    • v.10 no.3
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    • pp.107-110
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    • 2009
  • Efficient deep-blue organic light-emitting diodes were demonstrated using 4,4'-bis(9-ethyl-3-carbazovinylene)-1,1'-biphenyl doped in double-emission layers (D-EMLs). The D-EML system, which consists of 2-methyl-9,10-di(2-naphthyl)anthracene and 1,4-(dinaphthalen-2-yl)-naphthalene as blue hosts, was employed to broaden the recombination zone and to ensure the good confinement of the holes and electrons. The optimized device showed a peak current efficiency of 4.47 cd/A, a peak external quantum efficiency of 4.09%, and Commission Internationale de L'Eclairage coordinates of (0.16, 0.10).