• Title/Summary/Keyword: Blue LED

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Luminescence properties of Eu- and Mn-activated $BaMgP_2O_7$ as a potential red phosphor for white emission

  • Kim, Yong-Kwang;Choi, Sung-Ho;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.581-584
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    • 2008
  • $BaMgP_2O_7$:Eu,Mn phosphors for white emission were synthesized and their luminescent properties were investigated under UV excitation. The phosphor emits two colors: a blue band by $Eu^{2+}$ and a red band by $Mn^{2+}$. Due to the efficient energy transfer from $Eu^{2+}$ to $Mn^{2+}$, the red emission positioned at 615 nm is greatly enhanced with increasing $Mn^{2+}$ content up to 17.5 mol%.

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졸-겔법에 의한 CdS 분산$SiO_2$ Glass 박막의 비선형광학특성

  • 문종수;강종봉;김경문
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1353-1364
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    • 1996
  • Recently semiconductor doped glasses have attracted attention as nonlinear optical materials because of their large third order nonlinear optical properties. The transparent and homogeneous CdS-doped SiO2 glass thin films were obtained by the dip=coating process of the sol-gel method. Thin films were consisted of glasses containing CdS microcrystallites which were formed by dissolved Cd2+ and S2- ions in a SiO2 matrix solutions. A subsequent thermal treatment of this samples led the formation of colloidal agglomerates and finally of microcrystallites. The size of CdS microcrystallites was about 4 to 15 nm after thermal treatments at various heating conditions. From the optical absorption spectra of the CdS-doped SiO2 glass films it was found that the absorption edge was blue-shifted compared with that of the bulk CdS crystal(~2, 4 eV) and that the amount of energy shift was inversely proportional to the crystal size. And the band gap energy increased with the decrease in crystallite size indicating that the quantum size effects occured.

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Single crystal growth and characterization of changeable colored cubic zirconia (변색효과 cubic zirconia의 단결정 성장과 특성평가)

  • Park, Byeong-Seok;Choi, Jong-Keon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.108-112
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    • 2007
  • Cubic Zirconia single crystals having changeable color with light source were grown by skull melting method. Strong absorption of yellow color region light by Co and Nd and the absorption in violet color region by Fe led the color change from blue-green to red-purple with the light source from fluorescent to incandescent lamp. Color of crystals varied not only by the dopants but yttria contents and the conditions far heat treatment.

Surface Lapping Process and Vickers Indentation of Sapphire Wafer for GaN Epitaxy (GaN 증착용 사파이어 웨이퍼의 표면가공에 따른 압흔 특성)

  • Shin Gwisu;Hwang Sungwon;Kim Keunjoo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.4 s.235
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    • pp.632-638
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    • 2005
  • The surface lapping process on sapphire wafer was carried out for the epitaxial process of thin film growth of GaN semiconducting material. The planarization of the wafers was investigated by the introduction of the dummy wafers. The diamond lapping process causes the surface deformation of dislocation and micro-cracks. The material deformation due to the mechanical stress was analyzed by the X-ray diffraction and the Vickers indentation. The fracture toughness was increased with the increased annealing temperature indicating the recrystallization at the surface of the sapphire wafer The sudden increase at the temperature of $1200^{\circ}C$ was correlated with the surface phase transition of sapphire from a $-A1_{2}O_{3}\;to\;{\beta}-A1_{2}O_{3}$.

Modification and Inactivation of Human Ceruloplasmin by Oxidized DOPA

  • Kang, Jung-Hoon
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.625-628
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    • 2004
  • Ceruloplasmin (CP), the blue oxidase present in all vertebrates, is the major copper-containing protein of plasma. It has been proposed that oxidation of L-3,4-dihydroxyphenylalanine (DOPA) may contribute to the pathogenesis of neurodegenerative disorders. The effect of the oxidized products of DOPA on the modification of human CP was investigated. When CP was incubated with the oxidized L-DOPA, the protein was induced to be aggregated and ferroxidase activity was decreased in a time-dependent manner. Radical scavengers and catalase significantly inhibited the oxidized DOPA-mediated CP aggregation. Copper chelatrors, Diethylenetriaminepenta acetic acid (DTPA) and Diethyldithiocarbamic acid (DDC), also inhibited the oxidative modification of CP. The results suggested that DOPA oxidation led to the formation of free radical and induced the CP aggregation.

Fluorescence Micropatterning Based on the Polymeric Photobase Generator Containing Oxime-Urethane Groups by Dansylation

  • Choi, Won San;Kim, Hak Soo;Chae, Kyu Ho
    • Rapid Communication in Photoscience
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    • v.2 no.1
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    • pp.24-27
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    • 2013
  • A polymeric photobase generator containing oxime-urethane groups is applied to a fluorescence micropatterning material. Polymer bearing oxime-urethane groups was prepared by copolymerization of methyl methacrylate with methacryloyloxyethyl benzophenoneoxime urethane (MBU). The reaction of amino groups in the irradiated copolymer film with dansyl chloride (Dns-Cl) was monitored by using UV absorption, IR absorption and fluorescence spectroscopy. The fluorescence spectrum of the Dns-Cl-treated irradiated copolymer film shows a strong fluorescence with a fluorescence maximum wavelength at 510 nm. A blue fluorescent micropattern with a line width of $2{\sim}3{\mu}m$ was obtained. Treatment of the irradiated copolymer film with Dns-Cl and rhodamine B mixture led to the formation of green, red, and orange-colored fluorescence micropatterns. Thus, various colored micropatterns on a single polymer film can be obtained by selective excitation of each dye molecules.

Study of n-ZnO/InGaN/p-GaN Lihgt Emitting Diodes

  • Gang, Chang-Mo;Nam, Seung-Yong;Gong, Deuk-Jo;Choe, Sang-Bae;Seong, Won-Seok;Lee, Dong-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.322.2-322.2
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    • 2014
  • Lighting emitting diodes of n-ZnO/MQW/p-GaN structure are fabricated and investigated. To realize this LED structure, n-ZnO/MQW/p-GaN are grown by MOCVD. At several bias voltages, blue-green light is emitted from the ZnO mesa edge. However, the emission is restricted near the mesa edge. It is seen that the hole current does not spread well. It is because conductivity of p-GaN is extremely small. The break down voltage of the device is small compared to conventional InGaN/GaN LEDs. It is seen that ZnO columnar grain boundaries act as leakage current paths and non-radiative recombination center.

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Morphology and Photoluminescence Characteristics of Halophosphate Phosphor Particles by Spray Pyrolysis and Flame Spray Pyrolysis

  • Sohn, Jong-Rak;Kang, Yun-Chan;Park, Hee-Dong;Yoon, Soon-Gil
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.803-806
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    • 2002
  • Flame spray pyrolysis was applied to improve the photoluminescence characteristics of blue-emitting $Sr_5(PO_4)_3Cl:Eu^{2+}$ phosphor particles with high brightness for the application to LED phosphor. $Sr_5(PO_4)_3Cl:Eu^{2+}$ prepared from conventional spray pyrolysis had poor PL intensity than that of commercial products under long-wavelength ultraviolet(UV). $Sr_5(PO_4)_3Cl:Eu^{2+}$ phosphor particles prepared by flame spray pyrolysis had PL intensity as same as that of commercial products under long-wavelength UV. Hollow morphology and porous structure of the particles prepared by the flame spray pyrolysis disappeared after posttreatment. Even though the $Sr_5(PO_4)_3Cl:Eu^{2+}$ phosphor particles prepared by the flame spray pyrolysis had irregular shape, the particles had dense structure and clear surface property.

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Color tunable electroluminescence with polymer blends composed of PVK and copolymer containing SiPh-PPV and MEH-PPV unit

  • Oh, Gwang-Chae;Yun, Je-Jung;Park, Su-Mi;Son, Sung-Hee;Han, Eun-Mi;Jin, Sung-Ho;Gu, Hal-Bon;Choi, Hyun-Chual
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.736-739
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    • 2002
  • We report on white light emission from a light emitting diode(LED) prepared by blending a red emitting copolymer, m-SiPh PPV-co-MEH PPV, and a blue emitting polyvinylcarbazole (PVK). White light emission was realized when the weight ratio of the m-SiPh PPV-co-MEH PPV : PVK equals to 1 : 30, in which the commission Internationale de L'Eclairage coordinates were x=0.3266 and y=0.3438.

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A Study on the Zeta-potential of CMP processed Sapphire Wafers (CMP 가공된 사파이어웨이퍼의 웨이퍼내 표면전위에 관한 연구)

  • Hwang Sung Won;Shin Gwisu;Kim Keunjoo
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.2
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    • pp.46-52
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    • 2005
  • The sapphire wafer was polished by the implementation of the surface machining technology based on nano-tribology, The removal process has been performed by grinding, lapping and chemical-mechanical polishing. For the chemical mechanical polishing process, the chemical reaction between the slurry and sapphire wafer was investigated in terms of the change of Zeta-potential between two materials. The Zeta-potential was -4.98 mV without the slurry in deionized water and was -37.05 mV for the slurry solution. By including the slurry into the deionized water the Zeta-potential -29.73 mV, indicating that the surface atoms of sapphire become more repulsive to be easy to separate. The average roughness of the polished surface of sapphire wafer was ranged to 1∼4$\AA$.