• Title/Summary/Keyword: Blending Process

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Optimal Mix Design of High-Performance, Low-Heat Self-Compacting Concrete (고성능 저발열 자기충전 콘크리트의 최적 배합설계)

  • Kim, Young-Bong;Lee, Jun-Hae;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.4
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    • pp.337-345
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    • 2022
  • The foundation of high-rise concrete building in coastal areas generally must be installed in an integrated manner, not separately, in order to prevent defects caused by stress on the upper and lower parts of the mounting surface and to manage the process smoothly. However, when performing integrated punching, there is a concern that temperature stress cracks may occur due to hydration heat. Due to the large member size, it is difficult to make a sufficient commitment, so it is necessary to mix concrete with high self-charging properties to ensure workability. In this research, the amount of high-performance spray and admixture used was adjusted as experimental variables to satisfy this required performance. Through the analysis of the results for each blending variable, it was found that the unit quantity was 155kg/m3 and the cement ratio in the binder was 18%, and the target values of the pre-concrete properties and compressive strength were satisfied. A four-component binder(18% cement, 50% slag fine powder, 27% fly ash, 5% silica fume) was used.

Evaluation of Neutralization and FAME Conversion of Low-grade Waste Oil as Biodiesel Feedstock (저급 폐유지의 바이오디젤 원료 활용을 위한 중화탈산 및 FAME 전환 가능성 평가)

  • Joon-pyo Lee;Jin-suk Lee;Ji-yeon Park;Min-cheol Kim;Jae-wan Cho;Deog-keun Kim
    • New & Renewable Energy
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    • v.19 no.4
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    • pp.2-10
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    • 2023
  • The current mandatory domestic biodiesel blending ratio is 3.5%, which is planned to be gradually increased to achieve carbon neutrality by 2050. The aim of this study was to improve domestic self-sufficiency in biodiesel raw oil by conducting a technical review on the possibility of utilizing waste oils, such as soup oil, chicken oil, and leather oil, as biodiesel feedstocks. These waste oils have an acid value that is too high to be converted directly into biodiesel. Therefore, a pretreatment to reduce the acid value is necessary. The neutralization process was examined as a potential technology for reducing the acid value. The oil recovery rate of the soup oil after neutralization was significantly low at 37.6 wt%. The oil recovery rates of leather oil and chicken oil were 66.49 wt% and 79.08 wt%, respectively. Based on biodiesel conversion experiment using waste oil with a reduced acid value, the conversions were analyzed as 89 wt%, 91.1 wt%, and 90.5 wt% for soup oil, leather oil, and chicken oil, respectively. Thus, it is technically possible to use soup oil, leather oil, and chicken oil as raw materials for producing biodiesel.

Preparation of Biodegradable Polymer Microparticles Containing 5-FU Using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 5-FU 함유 생분해성 고분자 미세입자 제조)

  • Jung, Ju-Hee;Jung, In-Il;Joo, Hyun-Jae;Shin, Jae-Ran;Lim, Gio-Bin;Ryu, Jong-Hoon
    • KSBB Journal
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    • v.23 no.5
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    • pp.452-459
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    • 2008
  • To obtain maximal efficacy with minimal systemic side-effects, many studies have been carried out to achieve the controlled release of 5-fluorouracil (5-FU). In this study, biodegradable poly(L-lactide) (L-PLA) microparticles containing 5-FU were prepared by a process, called aerosol solvent extraction system (ASES), utilizing supercritical carbon dioxide. The effects of various organic solvents, drug/polymer feeding ratio, polymer molecular weight, and blending with the same polymers with different molecular weights on the formation of 5-FU loaded microparticles were investigated under a predetermined operating condition from our previous study. The drug recovery, entrapment efficiency, and in vitro drug release kinetics were determined by HPLC assays. The drug recovery obtained from the ASES process was found to be very high, whereas the drug entrapment efficiency was considerably low in all the experiments due to the poor affinity between L-PLA and 5-FU. These results indicated that the precipitation rate of L-PLA might be quite different from that of 5-FU so that there was little chance to form 5-FU loaded L-PLA microparticles.

Ecological Notes on Narcissus Flycatcher, Musciapa narcissina zanthopygia HAY - With special reference to the breeding process and feeding habits of nestlings during their nesting period- (흰눈섭황금새(Muscica narcissina zanthopygia HAY)의 생태-특히 번식경과와 육령기의 식습성)

  • WON, Pyong-Oh;RHEE, Kyung-Jho
    • The Korean Journal of Zoology
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    • v.8 no.2
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    • pp.89-127
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    • 1965
  • 1. This report is on the outcome of observation made up the breeding process of Narcissus flycatcher, Muscicapa narcissina zanthopygia, using 15 ness-boxes at Seoul and Kwang Nung Experimental forest in 1964, and the relevant feeding habit was studied by the collar method of wrapping the necks of thenestlings for 50-60 minutes or more in some cases from 1963 to 1964. 2. The Narcissus flycatcheris a common summer resident throughout Korea arriving at the end of April. The earliest data of arrival of this species in Seoul, is April 26, 1964. They migrate southward from the later part of September to early part of October. 3. In a week after their arrival , they start to build nest after a brief courtship. Male and female prepare their nest ina nestboxes in 4 or 5 days. Nests are usually found in the moss, which provide definite frame-work. The inner side of the nest is usually composed of roots of Gramineae or leaves of pine, oak or other broad leave tree. 4. The laying period is generally from the later part of April to the middle of June : and the number of eggs laid is from 3 to 8 , therefore 5 in average : eggs are pink with traces of milky yellow blending of light auburn and orange red spots and chicken-egg-like in shape. 5.The incubation takes place for 7-12 days from the middle part of May to the middle of June, in the order of male and female . The hatching rate tends to increase in proportion to clutch size. 6. The feeding period usually lasts 15 days in average from the early part of June to the middle of July and the feeding urge tends to increase in proportion to brood size. 7. The animals invading into their nest-boxes are red ants, chipmunks, bees , barkbeetles and philippine red-tailed shirkes, etc. 8. On the basis of analysis covering 714 birds in 31 nests, the food they consumed during the nesting period of nestlings were mostly of animal matters composing of : insect larvae form-39. 88% insect adult form 36.26%, insect pupae-0.19%, spider-17.75% and other animal matters 5.92% , Besides a small amount of plant pieces were found . As to the insect larvae, Lepidoptera was the largest in the content followed by Hymenoptera , Orthoptera and Coleoptera. As to the insect adult, Diptera was the largest in the content followed by Coleoptera, and Hymenoptera. In view of forest protection, noxious insect was of 69.38%, useful insect 4.39%, and spider 17.75%. 9. The rich assortment of its food, the ability of acquiring various insect (adults as well as larvae), its destruction of great numbers of harmful insects , and its quick assimilation artificial nesting with the nest-boxes of 2.5-3cm entrance hole employed, allow us to conclude that the flycatcher may be successfully employed in the elimination of fores pests. The above results are only that part obtained near Seoul in the middle of Korea, however, if we would extend the scheme to other broad areas using similar techniques, the nest-boxes could not only be well used by the birds, but also it would help to prevent the increase of harmful. insects.

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Optimization of Processing Conditions for Making a Black Ginger and Design Mixture for Black Ginger Drinks (흑생강 제조 공정 최적화 및 기능성 흑생강 음료 제조)

  • Ban, Young-Ju;Baik, Moo-Yeol;Hahm, Young-Tae;Kim, Hye-Kyung;Kim, Byung-Yong
    • Food Engineering Progress
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    • v.14 no.2
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    • pp.112-117
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    • 2010
  • Black ginger, obtained from steaming and drying process, provides the various functional properties. This study was performed to investigate the optimum processing conditions for black ginger with high content of biologically active substance such as anti-oxidations. Optimum processing conditions such as temperature and time for black ginger was determined by response surface methodology (RSM) with manufacturing process and functionality. The optimum steaming condition was determined 6 hours at 93.2$^{\circ}C$, and 82.7 mg/L DPPH scavenging activities was obtained at this condition. The black ginger drink was made with black ginger extracts, Japanese apricot, and honey. Interaction effects of these ingredients were investigated by modified distance based on design and analyzed by linear, nonlinear regression model, and RSM. The optimization of mixture ratio was made by statistical modeling using DPPH scavenging activities and sensory properties which are the important target constraints in drink. Total flavonoids showed a linear canonical form, while preference and antiradical activity showed a nonlinear canonical form indicating the higher interaction among mixtures. The response trace plot revealed that antiradical activity, sensory properties and total flavonoids were quite sensitive to the drink blending. The optimum formulation of the drink was set at 14.2% of black ginger extracts, 5% of Japanese apricot, and 10.8% honey.

Optimization of Synthesis Conditions for Improving Ti3AlC2 MAX Phase Using Titanium Scraps (타이타늄 스크랩 활용 Ti3AlC2 MAX 상분율 향상을 위한 합성 조건 최적화)

  • Taeheon Kim;Jae-Won Lim
    • Resources Recycling
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    • v.33 no.1
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    • pp.22-30
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    • 2024
  • To synthesize the Ti3AlC2 MAX phase, a crucial precursor for generating the two-dimensional material MXene, the use of Ti scrap as an initial material is an economically feasible approach. This study aims to optimize the synthesis conditions for the phase fraction of the Ti3AlC2 MAX phase utilizing Ti scrap as the Ti source. The deoxidation of Ti powders, prepared through the hydrogenation-dehydrogenation process from Ti scrap, was effectively accomplished using the deoxidation in solid-state (DOSS) process. The optimal synthesis conditions were established by blending DOSS-Ti, Al, and graphite powders with particle sizes ranging from 25 ~ 32 ㎛ in a molar ratio of 3:1.1:2. The resulting phase fractions were as follows: Ti3AlC2 at 97.25 wt.%, TiC at 0.93 wt.%, and Al3Ti at 1.82 wt.%. Furthermore, the oxygen content of the Ti3AlC2 MAX powder, spanning from 25 ~ 45 ㎛, was measured at 4,210 ppm.

Hydrophilic Modification of Porous Polyvinylidene Fluoride Membrane by Pre-irradiating Electron Beam (전자빔 전조사를 이용한 Polyvinylidene Fluoride 다공막의 친수화 개질)

  • Choi, Yong-Jin;Lee, Sung-Won;Seo, Bong-Kuk;Kim, Min
    • Membrane Journal
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    • v.21 no.2
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    • pp.118-126
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    • 2011
  • A method of light pre-irradiation, one of methods modifying hydrophobic surface to hydrophilic surface in a membrane, was proposed to overcome the drawback of previous methods such as blending, chemical treatment and post-irradiation, Process of membrane preparation in the study was comprised of 4 parts as follows: firstly process of precursor preparation to introduce hydrophilic nature under atmosphere and aqueous vapor by irradiating electron beam (EB), secondly process of dope solution preparation to cast on non-woven fabrics, thirdly process of casting to prepare membrane and finally process of coagulation in non-solvent to form porous structure. The merit of this method might show simple process as well as homogenous modification compared to previous methods. To carry it out, precursor was prepared by irradiating EB to powder PVDF at 75~125 K Gray dose. Precursor prepared was analyzed by FTIR, EDS and DSC to confirm the introduction of hydrophilic function and its mechanism. From their results, it was inferred I conformed that hydrophilic function was hydroxy1 and it was introduced by dehydrozenation. Hydrophilicity of membranes prepared was evaluated by contact angle (pristine PVDF : $62^{\circ}$, 125 K Gray-PVDF$13^{\circ}$). Porosity was evaluated by mercury intrusion method, simultaneously morpholoy and surface pore size were observed by SEM phothographs. The result showed the trend that more dose of EB led to smaller pore size and to lower porosity (pristine PVDF : 82%, 125 K Gray-PVDF : 63%). Trend of water permeability was similar to result above (pristine PVDF : 892 LMH, 125 K Gray-PVDF : 355 LMH).

The Study on the Structure and Meaning of UlsanSoeburisoree (울산쇠부리소리의 민속연행적 구조와 의미 연구)

  • Sim, Sang-Gyo
    • (The) Research of the performance art and culture
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    • no.37
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    • pp.127-155
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    • 2018
  • This paper considers the structure and meaning of the folktale accompaniment of the sound of UlsanSoeburisoree. The review process examined the meaning of each structure of the UlsanSoeburisoree in the preparation process while preparing the main elements of the structural features along with the historical background of the structure. UlsanSoeburisoree is Poongcheol ritual ceremony which means prayer ceremony for the production of iron. The sound of UlsanSoeburisoree is 1-Gilnori 2-Gosa 3-The sound of blowing smelting process 4-The sound of process of iron smelting 5-The sound of tabooline 6-The sound of blowing smelting process 7-The sound of blowing matches 8-The After-party. This structure is in line with the structure of folk play called Gilnory-Gosa-Performance-After-party. This is similar to the basic structure of folk beliefs Cheongsin(請神)-Osin(娛神)-Songsin(送神). Thus, the sound of UlsanSoeburisoree was formulated in a sequential parallel structure. The sound of UlsanSoeburisoree resemble the sacrifice of heaven ceremony since the time of the SamHan dynasty. The sound of the birth of life by physical sacrifice also plays the role of the song of creation of new life. The sound of UlsanSoeburisoree can be seen not only in Korea 's folk culture but also in folk culture of GyeongnamDo area. There are many festivals to pray for the abundance of life for UlsanSoeburisoree. Soil plays an absolute role in the process of producing iron. For those who soak it, the earth is a religious object. Among the folk tales handed down in the Yeongnam area, there are a lot of performances that are passed down through the blending of the people 's affection to overcome the harshness of life. In the case of the sound of UlsanSoeburisoree, it can be said that it was made and mixed with the wind that wanted to go beyond the harshness of life and the spirit of art.

Thermal Decomposition and Mechanical Properties of Polycarbonate/ABS Blends Prepared by High Shear Rate Processing (고속전단에 의한 폴리카보네이트/ABS 블렌드의 열분해 및 기계적 특성 연구)

  • Yoo, Jae Jung;Yong, Da Kyoung;Lee, Han Ki;Kim, Dae Sik;Lee, Hyung Il;Kim, Sun Hong;Lee, Kee Yoon;Lee, Seung Goo
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.471-476
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    • 2014
  • Polycarbonate (PC) and acrylonitrile-butadiene-styrene (ABS) blends were prepared using a high shear extruder to investigate their thermal decomposition and mechanical properties with shear rate and shear time. In this experiment, high shear rate, from 1000 to 3000 rpm, in blending process was applied for 10 to 40 sec, respectively. At high shear rate over than 2000 rpm, the initial decomposition temperature was dropped significantly compared to a compounded sample because of thermal decomposition of the blend by high shear. Consequently, high shear processing gave an important effect on the mechanical and thermal properties of the PC/ABS blend. In particular, elongation of the blend decreased significantly with shear rate.

Electrochemical Properties of Ionic Liquid Composite Poly(ethylene oxide)(PEO) Solid Polymer Electrolyte (이온성 액체 복합 Poly(ethylene oxide)(PEO) 고체 고분자 전해질의 전기화학적 특성)

  • Park, Ji-Hyun;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.101-106
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    • 2016
  • In this study, we prepared an ionic liquid composite solid polymer electrolyte (PEO-LiTFSI-$Pyr_{14}TFSI$) with poly(ethylen oxide), lithium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide by blending-cross linking process. Although the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte displayed a small peak at 4.4 V, it had high electrochemical oxidation stability up to 5.7 V. Ionic conductivity of the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte increased with increasing temperature from $10^{-6}S\;cm^{-1}$ at $30^{\circ}C$ to $10^{-4}S\;cm^{-1}$ at $70^{\circ}C$. To investigate the electrochemical properties, the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte assembled with $LiFePO_4$ cathode and Li-metal anode. At 0.1 C-rate, the cell delivered $40mAh\;g^{-1}$ for $30^{\circ}C$, $69.8mAh\;g^{-1}$ for $40^{\circ}C$ and $113mAh\;g^{-1}$ for $50^{\circ}C$, respectively. The PEO-LiTFSI-$Pyr_{14}TFSI$ solid polymer electrolyte exhibited good charge-discharge performance in Li/SPE/$LiFePO_4$ cells at $50^{\circ}C$.