• Journal of the Korean Institute of Gas
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• v.17 no.6
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• pp.27-32
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• 2013

Renewable gas fuels such as biogas and landfill gas are obtained from the biodegradable organic wastes so that they inherently have carbon-neutral nature which can respond global warming. Therefore, attentions are paid to use this renewable gases as a main fuel for internal combustion engines. However, the composition of the fuel varies by its origin or conversion process, it is necessary to make stable combustion and accomplish high efficiency when used in power generating spark ignition (SI) engines. In this study, efforts have been made to investigate the effect of the composition of renewable gas fuel on the engine performance and exhaust emissions. In addition, a new spark plug with a long electrode was tested and compared with a base spark plug as a way to improve engine efficiency and reduce harmful emissions.

• Journal of Microbiology and Biotechnology
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• v.27 no.12
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• pp.2165-2172
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• 2017

Lignocellulose is now a promising raw material for biofuel production. However, the lignin complex and crystalline cellulose require pretreatment steps for breakdown of the crystalline structure of cellulose for the generation of fermentable sugars. Moreover, several fermentation inhibitors are generated with sugar compounds, majorly furfural. The mitigation of these inhibitors is required for the further fermentation steps to proceed. Amino acids were investigated on furfural-induced growth inhibition in E. coli producing isobutanol. Glycine and serine were the most effective compounds against furfural. In minimal media, glycine conferred tolerance against furfural. From the $IC_{50}$ value for inhibitors in the production media, only glycine could alleviate growth arrest for furfural, where 6 mM glycine addition led to a slight increase in growth rate and isobutanol production from 2.6 to 2.8 g/l under furfural stress. Overexpression of glycine pathway genes did not lead to alleviation. However, addition of glycine to engineered strains blocked the growth arrest and increased the isobutanol production about 2.3-fold.

• The Korean Journal of Ecology
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• v.9 no.1
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• pp.59-71
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• 1986

Net production, dead material increments were measured, and annual respiration loss was simulated through a year to determine the gross production at the Phragmites longivalvis, Carex scabrifolia and Zoysia sinica stand on Okryudeung, a sand bar of the Nagdong river estuary. The maximum live biomass for above-ground organs of the three stands occured in October, i.e., 1, 985, 744 and 1, 013g/m2, and belowground net productions were estimated to be 650, 440 and 412g/m2, respectively. Materials died or shedding from live aboveground organs during the growth season were estimated to be 167, 81 and 0 g/$m^2$. From the results of simulation, annual variation of respiratiion was primarily dependent on the annual variation of temperature through a year. For annual respiration loss in three stands, 21.893, 6.147 and 5.036kg $CO_2/m^2$ were calculated, respectively. Corresponding gross productions were 72, 203, 22, 109 and 19, 909kcal/$m^2$. Respiration of belowground organs corresponded to 65%, 66% and 37% of the total plant respiration, and annual respiration loss accounted for 85%, 78% and 71% of the annual gross production. In view of efficiency of solar energy utilization, 5.8%, 1.8% and 1.6% of incident light energy were converted to gross production of plants during a year. With incident light energy during the growth season from April to September, energy utilizations for net production were estimated to be 1.2%, 0.4% and 0.6% at the three stands.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.5
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• pp.685-695
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• 2004

Size-segregated measurements of aerosol composition are used to estimate the transport of natural and anthropogenic aerosols at Gosan site during May 2002. The results of measurement show that not only soil dust but also anthropogenic aerosols, including sulfur and enriched trace metals such as Pb, Zn, Cu, are transported to Gosan. This study combines the size- and time-resolved aerosol composition measurements with factor analysis in order to identify some source materials. As a result, coarse particles (2.5${\mu}m$~12${\mu}m$) are influenced by soil, sea-salt, coal, coal combustion, and nonferrous sources. But fine particles have different sources. The fine particles, which the diameter is from 0.56${\mu}m$ to 2.5${\mu}m$, are more affected by road dust, oil combustion, industry. municipal incineration, and ferrous metal sources. The very fine particles, from 0.09${\mu}m$ to 0.56${\mu}m$, mainly supplied by biomass burning, oil combustion, nonferrous and ferrous metal sources.

• Applied Chemistry for Engineering
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• v.20 no.4
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• pp.355-362
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• 2009

Fuels based on petroleum will eventually run out in the near future. DME (Di-methyl Ether) is a clean energy source that can be manufactured from various raw materials such as natural gas, coal as well as biomass. As DME has no carbon-carbon bond in its molecular structure and is an oxygenate fuel, its combustion essentially generates no soot as well as no SOx. Because the physical properties of DME are similar to those of LPG, the LPG distribution infrastructure can be converted to use with DME. DME has such high cetane number of 55~60 that it can be used as a diesel engine fuel. Practical use of DME as a next-generation clean fuel or next-generation chemical feedstock is advancing in the fields of power generation, diesel engines, household use, and fuel cells, among others. The purpose of this paper is review the characteristics, standardization, status of research and development in domestic and foreign countries of DME.

• Analytical Science and Technology
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• v.30 no.4
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• pp.174-181
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• 2017

Bio-liquid is a liquid by-product of the hydrothermal carbonization (HTC) reaction, converting wet biomass into solid hydrochar, bio-liquid, and bio-gas. Since bio-liquid contains various compounds, it requires efficient sampling method to extract the target compounds from bio-liquid. In this research, fatty acid methyl ester (FAME) in bio-liquid was extracted based on hollow fiber supported liquid phase microextraction (HF-LPME) and determined by Gas Chromatography-Flame Ionization Detector (GC-FID) and Gas Chromatography/Mass Spectrometry (GC/MS). The well-known major components of biodiesel, including methyl myristate, palmitate, methyl palmitoleate, methyl stearate, methyl oleate, and methyl linoleate had been selected as standard materials for FAME analysis using HF-LPME. Physicochemical properties of bio-liquid was measured that the acidity was 3.30 (${\pm}0.01$) and the moisture content was 100.84 (${\pm}3.02$)%. The optimization of HF-LPME method had been investigated by varying the experimental parameters such as extraction solvent, extraction time, stirring speed, and the length of HF at the fixed concentration of NaCl salt. As a result, optimal conditions of HF-LPME for FAMEs were; n-octanol for extraction solvent, 30 min for extraction time, 1200 rpm for stirring speed, 20 mm for the HF length, and 0.5 w/v% for the concentration of NaCl. Validation of HF-LPME was performed with limit of detection (LOD), limit of quantitation (LOQ), dynamic range, reproducibility, and recovery. The results obtained from this study indicated that HF-LPME was suitable for the preconcentration method and the quantitative analysis to characterize FAMEs in bio-liquid generated from food waste via HTC reaction.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.6
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• pp.398-405
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• 2014

Salt accumulation at soil surface is one of the most detrimental factors for crop production in reclaimed tidal land. This study was conducted to investigate the effect of capillary barriers beneath the soil surface on dynamics of soil salts at coarse-textured reclaimed tidal land. A field experiment was conducted at Saemangeum reclaimed tidal land for two years (2012-2013). Capillary barriers ($3.5{\times}12m$) were treated with crushed-stone, oyster shell waste, coal briquette ash, coal bottom ash, rice hull and woodchip at 40-60 cm depth from soil surface. Silage corn (Zea mays) was cultivated during the experimental period and soil salinity was monitored periodically. Soil salinity was significantly reduced with capillary barrier compared to that of control. Oyster shell waste was one of the most effective capillary barrier materials to control soil salinity at Saemangeum reclaimed tidal land. At the first growing season capillary barrier did not influence on corn growth regardless of types of the material, but plant biomass and withering rate of corn were significantly improved with capillary barrier at the second growing season. The results of this study showed that capillary barrier was effective on the control of soil salinity and improvement of corn growth, which indicated that capillary barrier treatment can be considered one of the best management practices for stable crop production at Saemangeum reclaimed tidal land.

• Resources Recycling
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• v.15 no.1 s.69
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• pp.3-11
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• 2006

Fast pyrolysis of Quercus acutissima was carried out in a fluidized bed pyrolyser and then the physicochemical properities of obtained bio-oil were analyzed using GC/MS. The yields of bio-oil of Quercus acutissima and Larix leptolepis from a fluidized bed pyrolyzer were maximized at $350^{\circ}C\;and\;400^{\circ}C$, respectively. This is due to the difference or cellulose content between the two tree species. Above the optimum temperature, the yields of char and oil decreased as the reaction temperature increased, but the yield of gas-phase and water fraction increased. It is concluded that this phenomenon is occured by secondary pyrolysis in the free board. The feeding rate of the sample in a fluidized bed pyrolyser did not affect the yields and composition of products, because of a sufficient mixing between bed materials and sand.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.40 no.3
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• pp.315-320
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• 2020

Pellets are manufactured using wood by-products. The combustion efficiency of pellets depends on the pellet manufacturing process, the types of materials mixed while manufacturing and the wood pellet stoves themselves. In this study, we developed a multi-layer combustor to be used in a wood pellet stove, for the purpose of reducing environmental pollution and energy waste due to incomplete combustion. The multi-layer combustor was designed to compensate for the shortcomings of existing combustors. A CAD (Computer Aided Design) model was verified using a 3D printer and a prototype was developed. The combustion experiments were conducted on commercial and proposed combustors using pellets of the same brand, manufacturing date, place and specifications. From the experiments, it was found that the proposed combustor produced the lowest carbon monoxide (CO) emission and highest thermal efficiency.

• Advances in environmental research
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• v.9 no.1
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• pp.65-84
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• 2020

The potential use of Sargassum boveanum algae for the removal of uranium from aqueous solution has been studied by varying three independent parameters (pH, initial uranium ion concentration, S. boveanum dosage) using a central composite design (CCD) under response surface methodology (RSM). Batch mode experiments were performed in 20 experimental runs to determine the maximum metal adsorption capacity. In CCD design, the quantitative relationship between different levels of these parameters and heavy metal uptake (q) were used to work out the optimized levels of these parameters. The analysis of variance (ANOVA) of the proposed quadratic model revealed that this model was highly significant (R² = 0.9940). The best set required 2.81 as initial pH(on the base of design of experiments method), 1.01 g/L S. boveanum and 418.92 mg/L uranium ion concentration within 180 min of contact time to show an optimum uranium uptake of 255 mg/g biomass. The biosorption process was also evaluated by Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models represented that the experimental data fitted to the Langmuir isotherm model of a suitable degree and showed the maximum uptake capacity of 500 mg/g. FTIR and scanning electron microscopy were used to characterize the biosorbent and implied that the functional groups (carboxyl, sulfate, carbonyl and amine) were responsible for the biosorption of uranium from aqueous solution. In conclusion, the present study showed that S. boveanum could be a promising biosorbent for the removal of uranium pollutants from aqueous solutions.