• Membrane and Water Treatment
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• v.3 no.2
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• pp.133-140
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• 2012

The overall performance of BNR-MBR, so-called Anoxic-Anaerobic-Aerobic Membrane Bioreactor ($A^3$-MBR), developed for nutrient removal was studied to determine the efficiencies and mechanisms under different solid retention time (SRT). The reactor was fed by synthetic high-rise building wastewater with a COD:N:P ratio of 100:10:2.5. The results showed that TKN, TN and phosphorus removal by the system was higher than 95%, 93% and 80%, respectively. Nitrogen removal in the system was related to the simultaneous nitrification-denitrification (SND) reaction which removed all nitrogen forms in aerobic condition. SND reaction in the system occurred because of the large floc size formation. Phosphorus removal in the system related to the high phosphorus content in bacterial cells and the little effects of nitrate nitrogen on phosphorus release in the anaerobic condition. Therefore, high quality of treated effluent could be achieved with the $A^3$-MBR system for various water reuse purposes.

• Journal of Korean Society on Water Environment
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• v.22 no.2
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• pp.222-229
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• 2006

The treatment performance and operational parameters of a tertiary wastewater treatment process a biological filtration system were investigated. The biological filtration system consisted of a nitrification filter (Fiter 1) and a polishing filter with anoxic and aerobic parts (Filter 2). SS, T-C-BOD, and T-N in effluent were kept stable at less than 3, 5 mg/L, and 5 mgN/L, respectively, under a HRT in Filter (filter-bed) of 0.37~2.3 h. T-N at the outlet of Filter 2 were about 1~5 mgN/L under the condition of LV of 50~202 m/d. In Filter 2, denitrification was accomplished under LV of 50~168 m/d in a 1 m filter-bed. However, the denitrification capacity reached the maximum when the linear velocity was increased to 202 m/d. Relationship between increase in microorganism and headloss was clearer in Filter 2. As a result, the denitrification rate increased from 1.0~2.3 kgN/($m^3-filter-bed{\cdot}d$) as the headloss increased. The COD removal rate was 6.0~9.6 kgCOD/($m^3-filter-bed{\cdot}d$) when operated with Filters 1 and 2. These results mean that captured bacteria contributed a part of COD consumption and denitrification. The maximum nitrification and denitrification rate was 0.5 and 4 kgN/($m^3-filter-bed{\cdot}d$) in Filter 1 and 2.The ratio of backwashing water to the treated water was about 5~10 %. In Filter 1, wasted sludge in backwashing was only 0.7~5.3 gSS/($m^3$-treated water). In Filter 2, added methanol was converted into sludge and its value was 8.0~24 gSS/($m^3$-treated water). These results proved that this process is both convenient to install as tertiary treatment and cost effective to build and operate.

• Journal of Microbiology and Biotechnology
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• v.12 no.3
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• pp.377-381
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• 2002

Recently, interests to remove nitrogen in the nitritation process have increased because of its economical advantages, since it could be a short-cut process to save both oxygen for nitrification and carbon for denitrification compared to a typical nitrification. However, the kinetics related with the nitritation process has not yet been fully understood. Furthermore, many useful models which have been successfully used for wastewater treatment processes cannot be used to estimate effluent nitrite concentration for evaluating performance of the nitritation process, since the process rate equations and population of microorganisms for nitrogen removal in these models have been set up only for the condition of full nitrification. Therefore, the present study was conducted to estimate an effluent nitrite concentration in the nitritation process with a concept of enzymatic inhibition kinetics based on long-term laboratory experiments. Using a nonlinear least squares regression method, kinetic parameters were accurately determined. By setting up a process rate equation along with a mass balance equation of the nitrite-oxidizing step, an effluent nitrite concentration in the nitritation process was then successfully estimated.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.5
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• pp.589-599
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• 2007

This study was conducted to investigated the removal efficiency of BOD and nutrient for the treatment of low strength municipal wastewater by a biological nutrient removal system. In this experiment, the effect of operating parameter including HRT of 7.0hr, BOD/TN ratios of 2.62~4.08, internal recycle of 50~300%, and return sludge of 50~100%, were studied during winter season. Efficiencies of organic matter and T-P removal and denitrification were not significantly affected by the change of temperature in winter season. However, the specific nitrification rate and nitrification efficiency decreased at low temperature. Besides, denitrification efficiencies increased with increasing BOD/TN ratios. It was also found that the internal recycle and return sludge ratio below 50% is required for the effective denitrification of low strength municipal wastewater. With operating mode 4 of the optimum, the effluent BOD, T-N and T-P concentration were obtained to average 5.8, 14.6, and 0.84 mg/L, respectively. The temperature-activity coefficient (${\theta}$) of specific nitrification rate, specific denitrification rate and specific phosphorus uptake rate were obtained 1.044, 1.017, 1.028, respectively.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.5
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• pp.521-529
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• 2007

Nutrient removal from synthetic wastewater was investigated using a MLE (Modified-Ludzack Ettinger) type MBBR (Moving Bed Biofilm Reactor), with different phenol ($C_6H_5OH$) concentrations, in order to determine the inhibition effects of phenol on biological nutrient removal and the biodegradation of phenolic wastewater. The wastewater was prepared by mixing a solution of molasses with known amounts of phenol and nutrients. The experiments were conducted in a lab-scale MLE type MBBR, operated with four different phenol concentrations (0, 67, 100 and 168mg/L) in the synthetic feed. Throughout the experiments, the ratio of the phenolic COD concentration to the total COD was varied from 0 to 1. Throughout batch test, the SNR (Specific Nitrification Rate) and SDNR (Specific Denitrification Rate) were significantly influenced by changes of the phenol concentration. Phenol was inhibitory to the nitrification/denitrification process, and showed greater inhibition with higher initial phenol concentrations. The SNR observed with 0, 67, 100 and 168mg phenol/L were very different like 10.12, 6.95, 1.51 and $0.35mg\;NH_{3^-}N/gMLVSS$ hr, respectively. Similarly, the SDNR observed at 0, 67, 100 and 168mg phenol/L were different like 0.322, 0.143, 0.049and 0.006mgN/gMLVSS day, respectively.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.5
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• pp.537-546
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• 2005

This study was carried out to evaluate EPS and SMP variation of sludge and effluent in nitrification and denitrification process with zeolite addition, a possible reduction of effluent DOC by URC(Ultra Rapid Coagulation) process. As a biological wastewater treatment result, EPS formation of both aeration and anoxic sludges are not affect by SRT variation. However, EPS concentration of sludges is higher in aeration tank than in anoxic tank by 6~8 mg EPS/ g VSS. Linear relationship between SMP to DOC indicates that SMP of bulk solution contributes to most of the biological treatment effluent DOC. DOC and turbidity removal efficiency was more improved with URC process than in a conventional coagulation. For pretreatment of UF filtration DOC removal was advanced by URC process than only UF filtration.

• Membrane and Water Treatment
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• v.15 no.1
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• pp.1-9
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• 2024

Biological nutrient removal is gaining increasing attention in wastewater treatment plants; however, it is adversely affected by low temperatures. This study examined temperature effects on nutrient removal and morphological stability of the granular and denitrifying phosphorus accumulating organisms (PAO and DPAO, respectively) using sequencing batch reactors (SBRs) at 5, 10, and 20 ℃. Lab-scale SBRs were continuously operated using anaerobic-anoxic and anaerobic-oxic cycles to develop the PAO and DPAO granules for 230 d. Sludge granulation in the two SBRs was observed after approximately 200 d. The average removal efficiency of soluble chemical oxygen demand (SCOD) and PO₄^3--P remained >90% throughout, even when the temperature dropped to 5 ℃. The average removal efficiency of NO₃^--N remained >80% consistently in DPAO SBR. However, nitrification drastically decreased at 10 ℃. Hence, the removal efficiency of NH₄⁺-N was decreased from 99.1% to 54.5% in PAO SBR. Owing to the increased oxygen penetration depth at low temperatures, the influence on nitrification rates was limited. The granule in DPAO and PAO SBR was observed to be unstable and disintegrated at 10 ℃. In conclusion, morphological characteristics showed that changed conversion rates at low temperatures in aerobic granular sludge altered both nutrient removal efficiencies and granule formation.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.7
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• pp.479-484
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• 2013

This study was performed to examine the effect of copper on the biodegradability, nitrification, denitrification and oxygen uptake rate (OUR) using batch reactor and continuous flow stirred tank reactor (CSTR) of anaerobic/anoxic/oxic ($A_2/O$). The results of this study can be summarized as follows. In the case of the effect of copper on organic treatment, the bad effect initiated when it was above 4.5 mg/L copper with batch reactor and above 2.0 mg/L copper with CSTR. Concerning the case on nitrification and removal of nitrogen, it showed bad effect when copper was above 4.5 mg/L with batch reactor for nitrification and 1.0 mg/L with CSTR for the removal of nitrogen. The bad effect on the removal of phosphorus began when it was 4.5 mg/L copper with batch reactor and 2 mg/L copper with CSTR. In the case of OUR, it decreased as microbial activity was affected when copper concentration was above 1.5 mg/L in both case of batch reactor and CSTR.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.5
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• pp.547-555
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• 2009

The objectives of this research were focused on the effects of various operating parameters on nitrous oxide emission such as C/N ratio, ammonia concentration and HRT in the hybrid and suspension reactors. With the decreasing of C/N ratios, $N_2O$ emission rates in the both processes were increased because organic carbon source for denitrification was depleted. In case of biofilm reactor operated using medium, $N_2O$ release from the nitrification was not affected by the variation of ammonia concentration. But in the suspension reactor, $N_2O$ production from the nitrification was rapidly increased with the increase of ammonia. Nitrite accumulation caused by undesirable nitrification conditions could be a important reason for the increase in the $N_2O$ production from the aerobic reactor. And rapid increase in $N_2O$ production was reflected by the decrease of HRT, similar to the results observed in the results of ammonia loading changes. So it could be said that it is very important to put in consideration both its optimum conditions for wastewater treatment efficiency and suitable conditions for $N_2O$ diminish, simultaneously, in order to development an eco-friendly and advanced wastewater treatment, especially in BNR process.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.4
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• pp.228-233
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• 2015

This study was performed to examine the effect of zinc on the biodegradability, nitrification, denitrification and oxygen uptake rate (OUR) using batch reactor and continuous flow stirred tank reactor (CSTR) of anaerobic/anoxic/oxic ($A^2/O$). The results of this study can be summarized as follows. In the case of the effect of zinc on organic treatment, zinc had no effect up to 12 mg/L with batch reactor but biodegradability was lowered when it was above 3.0 mg/L with CSTR. Concerning the case on nitrification and removal of nitrogen, nitrification rate was lowered when zinc was above 6.0 mg/L with batch reactor and removal rate of nitrogen was lowered when zinc was above 3.0 mg/L with CSTR. Removal rate of phosphorus was lowered when it was above 6.0 mg/L zinc with batch reactor and above 3.0 mg/L zinc with CSTR. In the case of OUR, it decreased as microbial activity was affected when zinc concentration was above 3.0 mg/L in CSTR.