• Journal of Korean Institute of Industrial Engineers
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• v.22 no.1
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• pp.155-164
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• 1996

Biomass to methane via anaerobic digestion conversion is a good supply method of substitutable energy resources. The economic viability of this technology is contingent upon managing the production facilities in a cost effective manner. The problem is to determine the batch production sequence as well as the batch residence times in the digester so as to maximize total gas production over a given planning horizon. The problem is difficult to solve since the batch sequencing decisions and the batch residence time decisions cannot be isolated. This paper developes a heuristic algorithm which is based on a dynamic programming procedure for the multiple feedstock sequencing and scheduling biogas production systems and demonstrates to yield good results.

• KCID journal
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• v.18 no.2
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• pp.25-32
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• 2011

The 21 livestock farms considering future installation of biogas systems were studied. These farms were examined how to raise the livestock, to treat manure, to operate facility with respect to manure characteristics. The 15 farms out of 21 farms have applied to the marine dumping and consignment treatment for treating manure and even farms which have equipped liquid fertilizing system have less capacity facility than legal standards. Characteristics of manure were affected by the scale of swine barn, clean water usage, frequency of cleaning, cleaning method, feces-urine separating method, etc. Retention time in storage (over 20 days) has resulted in lower concentration of organic matter which could reduce biogas production. This indicates that systematic barn management system is required. Inhibition tests showed that disinfectant and citric acid did not affected digestion rates at 10 times higher concentration than recommendation. However hypochlorous acid is likely to affect the anaerobic microbial activity.

• Korean Journal of Environmental Agriculture
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• v.26 no.1
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• pp.1-6
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• 2007

In view of energy supply, biogas can be seen as alternative fuel by substituting considerable amount of fossil fuel and may be utilized for heat and power production or for transport fuel production ($CH_4-enriched$ biogas). The aim of this research is to analyse the emission of $NO_x$ and CO from biogas fired combustion engine for electric power production. The result indicate a significant effect of biogas composition ($CH_4-CO_2$ ratio) and biogas flow rate on the air pollutants emission. The emission factors from this study were compared with those of U.S. EPA. Low $CH_4-CO_2$ ratio condition typically shows the lower $NO_x$ and CO emission than higher $CH_4-CO_2$ ratio condition. At normal $CH_4-CO_2$ ratio (7:3) emission factors of $NO_x$ and CO were 1.29 and 30.43 g/MMBtu, respectively. At low $CH_4-CO_2$, ratio (6:4) emission factors of $NO_x$ and CO were 0.646 and 60.86 g/MMBtu, respectively, It should be emphasized that the actual emission may vary considerably from these results due to operating conditions including torque load and engine speed.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.35 no.2
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• pp.353-359
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• 2015

This study introduces a resource recycling system in urban apartment complex using four different technologies. The four technologies, called 4G, include a production technology for reclaimed water (Green water), a biogas production technology from organic waste (Green biogas), a reuse technology of rainwater (Green rainwater), and urban agropark (Green pyramid). Green water is the technology for producing the reclaimed water from wastewater, rainwater and underground water, and the average concentrations of BOD, SS, T-N and coliform of reclaimed water were 7.8mg/L, ND (not detected), 4.9mg/L and ND, respectively. Green biogas is the technology for producing biogas and effluent after treating organic wastes (e.g. food waste and night soil) discharged from households, and the average production rates of hydrogen and methane were $0.33m^3/m^3/d$ and $0.24m^3/m^3/d$, respectively. Green pyramid, agricultural farm operated by biogas and reclaimed water, provides a healthy and recreational space for residents, and plant growth rates using treated water and reclaimed water showed height of 1.32cm and weight of 112.8g. Therefore, 4G technologies can improve the recycling rate and treatment efficiencies of waste and wastewater in an apartment complex.

• Environmental Engineering Research
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• v.25 no.1
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• pp.80-87
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• 2020

Landfill waste decomposition generates a dark effluent named, leachate which is characterized by high organic matter content. To minimize these polluting effects, it becomes necessary to develop an effective landfill leachate treatment process. The objective of this study was to evaluate the performance of an innovative approach based on air stripping, anaerobic digestion (AD) and aerobic activated sludge treatment. A reduction of 80% of ammonia and an increase of carbon to nitrogen ratio to 25 were obtained, which is a suitable ratio for AD. This latter AD was performed in fixed bed reactor with progressive loading rate that reached 2 and 3.2 g COD/L/d for the raw and diluted leachate (1:2), respectively. The anaerobic treatment led to significant removal of chemical oxygen demand (COD) and biogas production, especially for the diluted leachate. The COD removal was of 78% for the raw leachate and a biogas production of 4 L/d with 70% methane content. The use of the diluted leachate led to 81% of COD removal and 7 L/d biogas with 75% methane content. It allowed a removal of 77% COD and more than 97% of the organic compounds present in the initial leachate sample.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.3
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• pp.227-234
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• 2016

The influence of mixing on biogas production and organic material removal performance of solid state anaerobic digestion of dairy manure and sawdust bedding mixtures was evaluated using 22 L volume lab-scale digesters. After 45 days of anaerobic digestion at $37^{\circ}C$, cumulative methane yield of unmixed test unit ($73.1N{\cdot}mL/g-VS$) was almost 1.3 times of that of mixed one ($56.3N{\cdot}mL/g-VS$). The biodegradable volatile solids removal rate of unmixed test unit was 67%, which was almost 28% greater than mixed one. Our results reveal that unmixed condition is better than mixed one in terms of biogas production and organic material reduction.

• Journal of Environmental Health Sciences
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• v.19 no.3
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• pp.17-21
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• 1993

Characteristics of a downflow anaerobic packed bed reactor with raschig ring ceramics as a packing were measured and discussed for the basic evaluation of the process. A synthesized glucose substrate wastewater were used as a feed and process characteristics such as pH, biogas production, composition of produced gas, COD removal and VSS were measured with the hydraulic retention time (HRT) changing from 0.25 to 2 days. As a result, this type of reactor was applicable in continuous operation within the given HRT range and the transient period approaching the steady state was about 20 days. The content of methane in produced gas increase with HRT was always high above 50% enough to use as energy source. The COD removal efficiency increased gradually as HRT increased. The axial profile of VSS concentration in the reactor usually showed the maximum at the lower region and the minimum at the middle. The VSS concentration at the upper region and the exit appeared similarly. However, at 0.25 day of HRT, the VSS concentration of effluent became higher than that of the upper region. Therefore the optimum HRT of this reactor occurred about 0.5 day, at which the production of methane began to be just stabilized and loss of VSS and COD removal were resonable.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.3
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• pp.236-242
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• 2012

This study has been carried out the experiment for the possibility of biogas reforming using waste heat. The source of this waste heat is the exhaust gas from a small-sized gas engine generator. For recovering the waste heat, Two-stage heat exchanger is manufactured. The two-stage heat exchanger is composed of a heat exchanger for the exhaust gas and a heat exchanger for the water. This two-stage heat exchanger is used for reforming the biogas by means of on-site hydrogen production at the small-sized gas engine generator. The two-stage heat exchanger is coupled with the biogas reformer which is a kind of catalytic reformer. To confirm a heat recovery efficiency of the two-stage heat exchanger, temperature differences of inlet and outlet locations are measured. Also, the variations of syngas concentrations with various biogas flow rates are investigated. As a result using manufactured two-stage heat exchanger, the biogas can be reformed from waste heat recovery. This experiment suggests that the exhaust gas heat exchanger is available for reforming the biogas.

• Journal of Applied Biological Chemistry
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• v.66
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• pp.258-265
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• 2023

After application of veterinary antibiotics, they may be partially metabolized before they are excreted by feces or urine either as unaltered form or as metabolites. Residual antibiotics enter the adjacent agricultural environments by spraying manure-based compost and liquid fertilizer on farmlands and lead to secondary pollution. The objective of this study was to compare the residual concentrations of 6 veterinary antibiotics by different production stages of liquid fertilizer from livestock manure recycling facilities. The relationship between concentration change of the residual antibiotics and the amount of liquid fertilizer component was also assessed. Pre-treatment showed the recovery of 63.4-106.7% at ppb level and the limit of quantification of 0.009-0.037 ㎍/L.As the result of analyzing the relationship between the residual concentrations of antibiotics and the amount of N component in liquid fertilizer by different production stages, the residual concentrations of antibiotics and N tended to decrease as the stabilization period elapsed during the liquid fertilization process. Average concentrations of sulfamethazine in raw materials, middle and final products of liquid fertilizer were 40.85, 26.17, 3.54 ㎍/L, respectively. Those of chlortetracycline decreased from 2.32 to 1.25 ㎍/L. The other 4 antibiotics also showed a decreasing trend by different production stages of liquid fertilizer. The amount of liquid fertilizer component N decreased from 0.21 to 0.096% by production stages of liquid fertilizer. It is considered that the correlation between residual antibiotic concentrations and N content can be applied as basic data for setting antibiotic reduction indicators.

• Environmental Engineering Research
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• v.25 no.1
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• pp.114-122
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• 2020

This study was aimed at using the Central Composite Design (CCD) and Box-Behnken Design (BBD) to compare the efficiency and to elucidate the main interacting parameters in the upflow anaerobic sludge blanket (UASB) reactor, namely: Organic Loading Rate (OLR), Hydraulic Retention Times (HRT) and pH at a constant temperature of 35℃. Optimum HRT (15 h), OLR (3.5 kg.m^-3.d^-1) and pH (7) resulted in biogas production of 5,800 mL/d and COD removal of 80.8%. BBD produced a higher desirability efficiency of 94% as compared to the CCD which was 92%. The regression quadratic models developed with high R² values of 0.961 and 0.978 for both CCD and BBD, respectively, demonstrated that the interaction models could be used to pilot the design space. BBD model developed was more reliable with a higher prediction of biogas production (5,955.4 ± 225.3 mL/d) and COD removal (81.5 ± 1.014%), much close to the experimental results at a 95% confidence level. CCD model predictions was greater in terms of COD removal (82.6 ± 1.06% > 80.8%) and biogas production (4,636.31 mL/d ± 439.81 < 5,800 mL/d) which was less than the experimental results. Therefore, RSM can be adapted for optimizing various wastewater treatment processes.