• Title/Summary/Keyword: Bio-reduction

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Synthesis of Cyclic Type Semi-Fluorinated Disodium Alkanesulfonate

  • Chirumarry, Sridhar;Ko, Yohan;Jang, Kiwan;Shin, Dong-Soo
    • Journal of the Korean Chemical Society
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    • v.60 no.4
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    • pp.257-260
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    • 2016
  • A new perfluorobutyl substituted cyclic type disodium alkanesulfonate is designed, synthesized and characterized as alternative substance to perfluorooctane sulfonic acid (PFOS, 1), a well-known surfactant. Cylic type sulfonate was accomplished from commercially available 2,2,3,3,4,4,5,5-octafluoro-1,6-hexanediol in four steps. Bio-degradable perfluorobutyl moiety was introduced from fluorous diol, which is symmetrically substituted amphiphile via installation of an intermediate trifluoromethanesulfonyl ester and easily manipulated by double displacement of triflate using potassium malonate and further reduction followed by nucleophilic ring opening are key reactions to get target disodium alkanesulfonate. The efficiency and simplicity in the synthesis of this material offer a new strategy to design PFOS alternatives.

Characteristics of poly 3C-SiC micro resonators with doping concentrations (도핑농도에 따른 다결정 3C-SiC 마이크로 공진기의 특성)

  • Chung, Gwiy-Sang;Lee, Tae-Won
    • Journal of Sensor Science and Technology
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    • v.18 no.3
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    • pp.207-209
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    • 2009
  • This paper describes the characteristics of poly 3C-SiC micro resonators with $3{\times}10^{17}{\sim}1{\times}10^{19}cm^{-3}$ doping concentrations. The 1.2 ${\mu}m$ thick cantilever and the 0.4 ${\mu}m$ thick doubly clamped beam resonators with different lengths were fabricated using poly 3C-SiC thin films. The characteristics of poly 3C-SiC micro resonators were evaluated by quartz and a laser vibrometer in vacuum at room temperature. The resonant frequencies of micro resonators decreased with doping concentrations owing to reduction in the Young's modulus of poly 3C-SiC thin films. It was confirmed that the resonant frequencies of poly 3C-SiC resonators are controllable by doping concentrations. Therefore, poly 3C-SiC resonators could be applied to MEMS devices and bio/chemical sensor applications.

Evaluation of nano-sSOI wafer using pseudo-MOSFET (Pseudo-MOSFET을 이용한 nano-sSOI 기판의 특성 평가)

  • Jung, Myung-Ho;Kim, Kwan-Su;Choi, Chel-Jong;Cho, Won-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.11-12
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    • 2007
  • The electrical characteristics of strained-SOI wafer were evaluated by using pseudo-MOSFET. The electrical characteristics of sSOI pseudo-MOSFET were superior to conventional SOI device. Moreover, the electrical characteristics were enhanced by forming gas anneal due to reduction of back interface trap density between substrate and buried oxide.

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Self-Assembled Peptide Structures for Efficient Water Oxidation

  • Lee, Jae Hun;Lee, Jung Ho;Park, Yong Sun;Nam, Ki Tae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.280-280
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    • 2013
  • In green plants, energy generation is accomplished through light-harvesting photosystem, which utilize abundant visible light and multi-stepwise redox reaction to oxidize water and reduce NADP+, transferring electrons efficiently with active cofactors1. Inspired by natural photosynthesis, artificial solar water-splitting devices are being designed variously. However, the several approaches involving immobilization2, conjugation3, and surface modification4 still have limitations. We have made artificial photosynthesis templates by self-assembling tyrosine-based peptide to mimick photosystem II. Porphyrin sensitizer absorbing blue light strongly was conjugated with the templates and they were hybridized with cobalt oxide through the reduction of cobalt ions in an aqueous solution. The formation of hybrid templates was characterized using TEM, and their water oxidation performance was measured by fluorescence oxygen probe. Our results suggest that the bio-templated assembly of functional compounds has a great potential for artificial photosynthesis.

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Development of Complex Module Device for Odor Reduction in Sewage

  • KIM, Young-Do;KWON, Woo-Taeg
    • Journal of Wellbeing Management and Applied Psychology
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    • v.4 no.3
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    • pp.1-9
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    • 2021
  • Purpose: This study was conducted to develop a module with higher removal efficiency and effectiveness by adapting two or more deodorization techniques for main cause of odor pollution exposed citizen living near water treatment facilities. Research design, data and methodology: To consider the standard, unity, electrical wire, compatibility of detachable device by installing two types of dry deodorization device within one module for easy replacement. Complex odor, H2S, NH3 were collected from sewage treatment facilities for evaluation of deodorization device. Results: Using the developed application in this study, removal efficiency of complex odor, H2S, NH3 were 93%, 100%, 82%, respectively. Conclusions: The H2S removal efficiency of deodorization device was higher than bio-filter system, which were currently used by sewage treatment. Further, the device should be considered for use in efficient odor removal system.

Exposure Assessment Study on Lithium-Ion Battery Fire in Explosion Test Room in Battery Testing Facility

  • Mi Sung Jo;Hoi Pin Kim;Boo Wook Kim;Richard C. Pleus;Elaine M. Faustman;Il Je Yu
    • Safety and Health at Work
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    • v.15 no.1
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    • pp.114-117
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    • 2024
  • A lithium-ion battery is a rechargeable battery that uses the reversible reduction of lithium ions to store energy and is the predominant battery type in many industrial and consumer electronics. The lithium-ion batteries are essential to ensure they operate safely. We conducted an exposure assessment five days after a fire in a battery-testing facility. We assessed some of the potentially hazardous materials after a lithium-ion battery fire.We sampled total suspended particles, hydrogen fluoride, and lithium with real-time monitoring of particulate matter (PM) 1, 2.5, and 10 micrometers (㎛). The area sampling results indicated that primary potential hazardous materials such as dust, hydrogen fluoride, and lithium were below the recommended limits suggested by the Korean Ministry of Labor and the American Conference of Governmental Industrial Hygienists Threshold Limit Values. Based on our assessment, workers were allowed to return to work.

Analysis of Effect on Pesticide Drift Reduction of Prevention Plants Using Spray Drift Tunnel (비산 챔버를 활용한 차단 식물의 비산 저감 효과 분석)

  • Jinseon Park;Se-Yeon Lee;Lak-Yeong Choi;Se-woon Hong
    • Journal of Bio-Environment Control
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    • v.32 no.2
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    • pp.106-114
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    • 2023
  • With rising concerns about pesticide spray drift by aerial application, this study attempt to evaluate aerodynamic property and collection efficiency of spray drift according to the leaf area index (LAI) of crop for preventing undesirable pesticide contamination by the spray-drift tunnel experiment. The collection efficiency of the plant with 'Low' LAI was measured at 16.13% at a wind speed of 1 m·s-1. As the wind speed increased to 2 m·s-1, the collection efficiency of plant with the same LAI level increased 1.80 times higher to 29.06%. For the 'Medium' level LAI, the collection efficiency was 24.42% and 43.06% at wind speed of 1 m·s-1 and 2 m·s-1, respectively. For the 'High' level LAI, it also increased 1.24 times higher as the wind speed increased. The measured results indicated that the collection of spray droplets by leaves were increased with LAI and wind speed. This also implied that dense leaves would have more advantages for preventing the drift of airborne spray droplets. Aerodynamic properties also tended to increase as the LAI increased, and the regression analysis of quadric equation and power law equation showed high explanatory of 0.96-0.99.

Experimental Study on Reduction Effects of Non-Point Pollutants by Improvement of Infiltration Capacity of Soil Filter Strip (토양여과대의 침투능 향상을 통한 비점오염물질 저감 효과에 관한 실험적 연구)

  • Woo, Su-Hye;Choi, I-Song;Oh, Jong-Min
    • Korean Journal of Ecology and Environment
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    • v.40 no.2
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    • pp.264-272
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    • 2007
  • Runoff of non-point pollutants has affected bad influence to water quality of river as reaching within short time. For this reason, reducing them prior to reaching aquatic systems or treating them after collection from discharge process of pollutants are desirable for efficient treatment of pollutants. This study was carried out to develop an ecotechnological method to prevent further aggravation of water quality by non-point source through vegetation filter strips. This study has placed a focus on improving infiltration capacity of soil for the optimum condition of vegetation filter strips. Therefore, we used titled soil filter strips instead of vegetation filter strips in this study. The three types of soil tilter strips were used in a bench scale experiment before applying to the field. The reduction efficiency of pollutants in soil filter strips (SS $84.5{\sim}92.5%$, BOD $67.9{\sim}80.6%$, T-N $43.4{\sim}76.6%$, T-P $40.6{\sim}87.4%$, Cu $28.3{\sim}48.1%$ Fe $92.1{\sim}97.7%$, Pb $81.4{\sim}97.3%$) was much higher than that of the controled group. And non-point pollutants reduction efficiency by soil filter strip's forms was estimated to be distinguishing in order of bio material, mixture of sand and gravel and lastly the whole gravel. In the event, the whole reduction efficiency of pollutants on the soil filter strips disclosed good results.

Odor reduction effect of microbially activated peat in broiler houses (육계사에서의 미생물 활성 토탄의 악취저감 효과)

  • Kim, Gyurae;Lee, Sang-Joon;Kim, Taeyeon;Krisdianti, Krisdianti;Aufa, Sulhi;Min, Hyunsook;Go, Gyeongchan;Cho, Ho-Seong;Oh, Yeonsu
    • Korean Journal of Veterinary Service
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    • v.45 no.2
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    • pp.111-116
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    • 2022
  • The purpose of this study is to evaluate the reduction effect of microbially activated peat on odor generated by livestock farms. The odor gas was measured by stirring the livestock manure sample with the existing litter and the microbially activated peat (Healtha Peat) was developed by this research team. In outdoor farm experiment, the measurements were performed by comparing broilers farm using rice husks and microbially activated peat as litter. The weight, mortality, shipment date, and odor levels (NH3) were measured before and after experiment. The result showed that NH3 levels were reduced by 100% in the Healtha Peat mixed group, Healtha Peat and rice husks mixed group. In the peat mixed group, Healtha Peat and saw dust mixed group showed reduce value at 99.6% and 99.1%, respectively. However the rice husks mixed group and saw dust mixed group showed a relatively weak NH3 reduction effect with values of 57.5% and 84.8%, respectively. After 3 months, the Healtha Peat mixed group and Healtha Peat and rice husks mixed group showed the highest NH3 reduction effect persistence. In the outdoor farm experiment, NH3 was present in farms using rice husks, but not in farms using Healtha Peat. In farms using Healtha Peat, the mortality and NH3 were reduced by 75% and >90%, respectively. The average body weight increased 18% and resulted to 10% decrease in the shipping date. These results implied that microbially activated peat has a clear effect on farm NH3 reduction and affects the productivity of farm animals.

Analysis of Patient Effective Dose in PET/CT; Using CT Dosimetry Programs (CT 선량 측정 프로그램을 이용한 PET/CT 검사 환자의 예측 유효 선량의 분석)

  • Kim, Jung-Sun;Jung, Woo-Young;Park, Seung-Yong
    • The Korean Journal of Nuclear Medicine Technology
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    • v.14 no.2
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    • pp.77-82
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    • 2010
  • Purpose: As PET/CT come into wide use, it caused increasing of expose in clinical use. Therefore, Korea Food and Drug Administration issued Patient DRL (Diagnostic Reference Level) in CT scan. In this study, to build the basis of patient dose reduction, we analyzed effective dose in transmission scan with CT scan. Materials and Methods: From February, 2010 to March 180 patients (age: $55{\pm}16$, weight: $61.0{\pm}10.4$ kg) who examined $^{18}F$-FDG PET/CT in Asan Medical Center. Biograph Truepoint 40 (SIEMENS, GERMANY), Biograph Sensation 16 (SIEMENS, GERMANY) and Discovery STe8 (GE healthcare, USA) were used in this study. Per each male and female average of 30 patients doses were analyzed by one. Automatic exposure control system for controlling the dose can affect the largest by a patient's body weight less than 50 kg, 50-60 kg less, 60 kg more than the average of the three groups were divided doses. We compared that measured value of CT-expo v1.7 and ImPACT v1.0. The relationship between body weight and the effective dose were analyzed. Results: When using CT-Expo V1.7, effective dose with BIO40, BIO16 and DSTe8 respectably were $6.46{\pm}1.18$ mSv, $9.36{\pm}1.96 $mSv and $9.36{\pm}1.96$ mSv for 30 male patients respectably $6.29{\pm}0.97$ mSv, $10.02{\pm}2.42$ mSv and $9.05{\pm}2.27$ mSv for 30 female patients respectably. When using ImPACT v1.0, effective dose with BIO40, BIO16 and DSTe8 respectably were $6.54{\pm}1.21$ mSv, $8.36{\pm}1.69$ mSv and $9.74{\pm}2.55$Sv for 30 male patients respectably $5.87{\pm}1.09$ mSv, $8.43{\pm}1.89$ mSv and $9.19{\pm}2.29$ mSv for female patients respectably. When divided three groups which were under 50 kg, 50~60 kg and over 60 kg respectably were 6.27 mSv, 7.67 mSv and 9.33 mSv respectably using CT-Expo V1.7, 5.62 mSv, 7.22 mSv and 8.91 mSv respectably using ImPACT v1.0. Weight and the effective dose coefficient analysis showed a very strong positive correlation(r=743, r=0.693). Conclusion: Using such a dose evaluation programs, easier to predict and evaluate the effective dose possible without performing phantom study and such dose evaluation programs could be used to collect basic data for CT dose management.

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