• Advances in materials Research
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• 제13권2호
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• pp.129-140
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• 2024

This study evaluates the ratio of Toluene di-isocyanate (TDI) functional group isocyanate (NCO) to the binder functional hydroxyl group (OH) in HTPB/AP/Al-based propellants on their mechanical properties, flow rate, and viscosity to determine the limitations of NCO/OH in the composition of solid propellants. The propellants consisted of hydroxyl-terminated polybutadiene (HTPB) polyurethane (PU), aluminum (Al) and tri-modal ammonium perchlorate (AP). The tri-modal AP consisted of 30% of coarse AP, 30% of medium AP, and 8% of fine AP. The ratio of NCO/OH varies from 0.73 to 0.85, with two binder percentages of 10.5% and 12%. An increase in NCO/OH ratio with 10.5% binder provided 20%, 95%, and 8 to 9% increments in UTS, modulus, and hardness, respectively. However, the propellant elongation, density, and flow rate decreased by 170%, 0.2%, and 11-12%, respectively. Viscosity increased 20% based on initial hour reading. The 12% binder provides 27%, 47%, and 5~6% an increment of UTS, modulus and hardness respectively. However, the propellant elongation, density, and flow rate decreased by 47%, 0.17% and 27%, respectively. The viscosity increased 30% based on initial hour reading. This study suggests the NCO/OH value of 0.77 and 10.5~11% binder content in propellant based on the mechanical properties, flow rate, and viscosity for better processing and pot life.

• 한국음향학회지
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• 제40권6호
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• pp.671-677
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• 2021

본 연구의 목적은 마감모르타르의 물결합재비가 공동주택 바닥충격음에 미치는 영향을 조사하는 것이다. 이를 위하여 동일한 동탄성계수를 지닌 Expanded Polystyrene(EPS) 완충재와 52 %, 66 %, 72 % 의 물결합재비를 가진 모르타르를 활용하여 뜬바닥구조를 시공하였으며, 표준실험동에서 바닥충격음을 측정하였다. 실험결과, 경량충격음에 있어서는 물결합재비 52 % 일 때, 밀도가 높은 관계로 경량충격음 전달특성이 높게 나타났다. 마감모르타르의 물결합재비가 높아지면 완충재 상부층 질량이 낮아지고, 이로 인해 뜬바닥구조의 고유진동수가 63 Hz 대역으로 이동하게 되면서 중량충격음의 음압레벨이 높게 나타났다. 이를 통하여 마감모르타르의 물결합재비가 중량충격음에 미치는 특성을 규명하였다.

• 콘크리트학회논문집
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• 제27권6호
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• pp.687-693
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• 2015

본 연구에서는 플라이애시(fly ash, FA) 및 고로슬래그 (ground granulated blast-furnace slag, GGBS)를 치환한 콘크리트의 등가 압축강도를 얻기 위한 물-결합재비 결정의 지표인 k-값을 제시하였다. 기존 콘크리트 실험결과(7,076 배합)를 기반으로 FA와 GGBS 치환율이 각각 50% 이내에서 다양한 물-결합재비에 대한 k-값을 결정하였다. k-값 수식의 유도를 위한 콘크리트의 압축강도와 물-결합재비의 관계는 지수함수로 모델링하였다. 일반적으로 등가 압축강도에 대한 k-값은 FA 및 GGBS의 치환율이 증가 할수록, 그리고 물-결합재비가 증가할수록 감소하였다. 물-결합재비 증가에 따른 k-값의 감소기울기는 FA 또는 GGBS 치환율에 의해 영향을 받지 않았다. 동일 물-결합재비에서의 k-값은 FA 치환 콘크리트에서보다 GGBS 치환 콘크리트에서 높았다. 궁극적으로, k-값은 물-결합재비와 FA 또는 GGBS 치환율의 함수로 일반화하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.85-88
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• 2006

This study describes the optimum mix proportion of the high strength and self-compacting concrete placed in main structures of LNG above tank. This concrete requires high strength level about $60{\sim}80MPa$, low hydration heat, balance between workability and consistency without vibrating in the actual work. For this purpose, low heat portland cement and fly ash are selected and design factors including water-binder ratio, replacement ratio of fly ash are tested. As experimental results, low heat portland cement shows lower the confined water ratio than another cement type and the optimum replacement ratio of fly ash in order to improve properties of the binder-paste shows 10% by cement weight considering test results of the confined water ratio$({\beta}p)$. Also, flowability of the high strength and self-compacting concrete by using fly ash about $10{\sim}20%$ is improved. The replacement ratio of fly ash 10% and water-binder ratio $25{\sim}27%$ are suitable to the design strength 80MPa and cost, In case of the design strength 60MPa, the replacement ratio of fly ash and water-binder ratio show 20% and $25{\sim}30%$ separately. Based on the results of this study, the optimum mix proportions of the high strength and self-compacting concrete will be applied to the construction of LNG above tank as a new type.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.777-780
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• 2005

The paper presents details of an investigation into the effect of sand content upon the strength and shrinkage of mortar. This strategy was to produces more durable strength mortar with less cement. Cement mortars containing $20\;wt.\;\%$ Class F fly ash, and/or $6\;wt.\;\%$ silica fume were prepared at a water/binder ratio of 0.45 and sand/binder ratios of 2.0, 2.5, 2.7, and 3.0. The increase in sand/binder ratio caused a decrease in the mortar flow. However, the sand/binder ratio did not affect the strength development. Drying shrinkage decreased with increasing the sand contents.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.1035-1040
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• 2001

The effects of polymer-binder ratio and slag content on the properties of combined wet/dry-cured polymer-modified mortars using granulated blast-furnace slag (slag) are examined. As a result, the flexural and compressive strengths of polymer-modified mortar using slag reaches a maximum at a slag content of 40%, and is inclined to increase with increasing polymer-binder ratio. The water absorption, carbonation depth and chloride ion penetration depth tend to decrease with increasing polymer-binder ratio and slag content.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.567-572
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• 2002

This research investigates experimentally an effect on the quality performances of the high flowing concrete according to binder types. The purpose of this study is to determine the optimum mix proportion of the high flowing concrete having good flowability, viscosity and no-segregation. For this purpose, two types using belite cement＋lime stone powder(LSP) and furnace slag cement+lime stone powder are selected and tested by design factors including water cement ratio, fine and coarse aggregate volume ratio. As test results of this study, the optimum mix proportion for binder types is as followings. 1) One type based belite cement ; water cement ratio $51^{\circ}C$, fine aggregate volume ratio $43^{\circ}C$ and coarse aggregate volume ratio $53^{\circ}C$, replacement ratio of LSP $42.7^{\circ}C$. 2) Another type based slag cement : water cement ratio $41^{\circ}C$, fine aggregate volume ratio $47^{\circ}C$ and coarse aggregate volume ratio $53^{\circ}C$, replacement ratio of LSP $13.5^{\circ}C$.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.625-630
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• 1999

This study was carried out to investigate quantitatively the relatonship between the water binder ratio and the concrete strength using finely ground granulated furnace blast slag to apply f 0.5% type admixture. The experimental parameters are water-binder ratio (40, 45, 50, 55, 60%) and slag contents(0, 10, 20, 30%). As a result, it can make that the water-binder ratio of concrete contented slag can be calculated by equation using relationship between compressive strength of concrete and water-binder ratio which is consisted of mixing strength and cement strength K.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.925-928
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• 2006

The effects of polymer-binder ratio, antifoamer content and shrinkage-reducing agent content on the air content and strengths of high-fluidity polymer-modified pastes are examined. As a result, the air content of the polymer-modified pastes tends to decrease with increasing polymer-binder ratio and antifoamer content. Irrespective of the antifoamer content, the flexural and tensile strengths of the high-fluidity polymer-modified pastes tends to increase with increasing polymer-binder ratio, and tend to decrease with increasing shrinkage-reducing agent content. However, the compressive strength of the polymer-modified pastes decreases with increasing polymer-binder ratio and shrinkage-reducing agent content.

• 유기물자원화
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• 제12권4호
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• pp.95-104
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• 2004

본 연구에서는 가연성 건설폐기물 재활용의 일환으로, 폐발포폴리스티렌의 스티렌 용액에 가교제 및 개시제를 첨가하여 제조한 결합재와, 폐목재 칩을 이용하여, 폐목재-플라스틱 복합패널을 제조하였다. 전열 프레스를 이용하여 다양한 결합재량 및 충전재-결합재 비를 갖는 복합패널 공시체를 제조하였으며, 그 겉보기 밀도, 흡수율, 흡수에 의한 팽창률, 휨강도, 내수성 등에 관한 일련의 실험을 행하였다. 폐목재-플라스틱 복합패널의 겉보기밀도는 결합재량 및 충전재-결합재비의 증가에 따라 증대하며, 그 휨강도 및 습윤 휨강도는, 결합재량 35%, 충전재-결합재비 0.8에 있어서 최대치에 이른다. 흡수율 및 흡수에 의한 두께 팽창률은, 결합재량 및 충전재-결합재비의 증가에 따라 현저하게 감소한다. 결합재량 30%이상의 경우, 충전재-결합재비에 관계없이, 복합패널의 24h 상온 수중($20^{\circ}C$) 침지 및 2h 끓는 물중($100^{\circ}C$)＋1h상온 수중($20^{\circ}C$) 침지에 의한 휨강도의 감소는 거의 발생하지 않으며, 높은 내수성을 발현한다.