• 제목/요약/키워드: Biaxial film

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AZO 박막의 전기전도특성 및 필름형 염료 태양전지의 광전 변환 특성 (Electrical Conduction Mechanism of AZO Thin Film and Photo-Electric Conversion Efficiency of Film-Typed Dye Sensitized Solar Cell)

  • 곽동주
    • 조명전기설비학회논문지
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    • 제24권4호
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    • pp.66-72
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    • 2010
  • 본 연구에서는 플렉시블 염료감응 태양전지(F-DSC)의 투명전도막으로서의 적용 가능성을 평가하기 위하여 PET 기판위에 AZO 박막을 증착하였다. 또한 ITO와 AZO 박막을 이용하여 동일한 조건하에서 F-DSC를 제작하여 광변환효율을 조사하였다. AZO의 경우 체적저항율 및 증착율은 220[W]의 전력조건하에서 각각 $1.8{\times}10^{-3}[{\Omega}{\cdot}cm]$와 25.5[nm/min] 정도였으며, 광투과율은 약 87[%]였다. AZO 박막의 전기전도 메카니즘의 방전전력 의존성은 XPS 분석결과 방전전력이 증가함에 따라 O1s/Zn2p의 성분비가 증가하여 산소성분에 의한 도너 제공에 크게 영향을 받는 것으로 나타났다. 한편, AZO 투명전도막으로 제작된 F-DSC의 변환효율은 약 2.79[%] 정도였으며, 이는 상용 ITO의 2.94[%]에 거의 필적되는 값으로 AZO의 F-DSC에의 응용 가능성이 충분함을 알 수 있었다.

롤 형상 필름 생산에서 두께평활도 개선을 위한 고정굴곡부 발현 모형 및 개선 모델 (A Model for Detection and Refinement of Fixed Bending Regions for Improving the Degree of Thickness Uniformity in Rolled Film Manufacturing)

  • 배재호
    • 산업경영시스템학회지
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    • 제38권3호
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    • pp.21-28
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    • 2015
  • As film products are increasingly used in a wide range of areas, from producing traditional flexible packaging to high-tech electronic products, a higher level of quality is demanded. Most film products are made in the form of rolled finished goods, therefore, various quality issues related to their shape characteristics must be addressed. The thickness of the film products is one of the most common and important critical-to-quality attributes (CTQs). Particularly, the degree of thickness uniformity is more important than other thickness parameters, because it will be potential causes of many secondary thickness-related quality problems, such as wrinkles or faulty windings. To control the degree of thickness uniformity, the fixed bending region is oneof the most important CTQs to manage. Fixed bending regions are special points in the transverse direction of a rolled product with consistent minute variations of the thickness gap. This paper describes the measurement and analysis of thickness uniformity data, which were performed in a real manufacturing field of biaxial oriented polypropylene (BOPP) film. In previous researches, quality function deployment (QFD) or fault tree analysis were used to find the most critical process attributes out to controlthe CTQ of thickness uniformity. Whereas, this paper uses traditional control charts to find the most critical process attributes out in this problem. In addition, the selection of one of the major critical process attributes (CTPs) that is expected to affect the CTQ of thickness uniformity is also described. The selected critical-to-process attributes are the controlled temperatures along the transverse direction. A dramatic improvement in thickness uniformity was observed when the selected CTPs were controlled.

합성형 반강자성 결합 재료의 자기장 세기에 따른 토오크 신호 분석 (Magnetic Field Dependence of Torque Signals in Synthetic Antiferromagnetic Coupled CoFeB/Ru/CoFeB Thin Film)

  • 윤석수;전우상;김동영
    • 한국자기학회지
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    • 제21권3호
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    • pp.83-87
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    • 2011
  • 본 연구에서는 합성형 반강자성 결합 특성을 갖는 CoFeB/Ru/CoFeB 박막 재료에서 자화용이축에서 측정한 플롭자기장($H_F$)과자화곤란축에서 측정한 포화자기장(Hs)을 경계로 달라지는 토오크 신호를 분석하였다. HF의 자기장 세기에서 음의 일축이방성 특성이 최소가 되며, 이는 반강자성 결합에 의한 자화 상쇄 효과로 강자성층의 자화용이축이 곤란축과 같은 역할을 하기 때문이다. $H_F$ < H < $H_s$의 자기장의 세기에서는 두 강자성층이 형성한 자화방향의 사이각이 증가하면서 쌍축이방성 특성을 유도시킨다. 이러한 쌍축이방성 유도 특성은 두 강자성층의 자화가 서로 수직이 되는 자기장의 세기에서 최대가 된다. 한편 자기장의 세기가 $H_s$ 이상에서는 CoFeB의 고유한 일축이방성 특성을 보인다. 이러한 자기이방성 특성은 두 강자성층의 반강자성 결합에 의한 자화 특성을 반영하고 있음을 Stoner-Wohlfarth 모델 분석을 통하여 알 수 있다.

고농도의 Ge 함량을 가진 Biaxially Strained SiGe/Si Channel Structure의 정공 이동도 특성 (Hole Mobility Characteristics of Biaxially Strained SiGe/Si Channel Structure with High Ge Content)

  • 정종완
    • 한국전기전자재료학회논문지
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    • 제21권1호
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    • pp.44-48
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    • 2008
  • Hole mobility characteristics of two representative biaxially strained SiGe/Si structures with high Ge contents are studied, They are single channel ($Si/Si_{1-x}Ge_x/Si$ substrate) and dual channel ($Si/Si_{1-y}Ge_y/Si_{1-x}Ge_x/Si$ substrate), where the former consists of a relaxed SiGe buffer layer with 60 % Ge content and a tensile-strained Si layer on top, and for the latter, a compressively strained SiGe layer is inserted between two layers, Owing to the hole mobility performance between a relaxed SiGe film and a compressive-strained SiGe film in the single channel and the dual channel, the hole mobility behaviors of two structures with respect to the Si cap layer thickness shows the opposite trend, Hole mobility increases with thicker Si cap layer for single channel structure, whereas it decreases with thicker Si cap layer for dual channel. This hole mobility characteristics could be easily explained by a simple capacitance model.

Fabrication of TFA-MOD YBCO Films Using the $Y_2Ba_1Cu_1O_x$ and $Ba_3Cu_5O_8$ Powders

  • Lim, Jun-Hyung;Jang, Seok-Hern;Yoon, Kyung-Min;Lee, Seung-Yi;Joo, Jin-Ho;Lee, Hoo-Jeong;Kim, Chan-Joong
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1247-1248
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    • 2006
  • We fabricated YBCO film using a TFA-MOD method. In order to enhance the reaction kinetics and to control the formation of the second phases, $Y_2Ba_1Cu_1O_x$ and $Ba_3Cu_5O_8$ powders were used as precursors (the so called "211 process"). The films were calcined at $460^{\circ}C$ and then fired at $750^{\circ}C-800^{\circ}C$ in a 12.1% humidified $Ar-O_2$ atmosphere. We found that the microstructure varied significantly with the firing temperature. The textures of all of the films were similar and mainly biaxial. For the film fired at $775^{\circ}C$, the critical current was obtained to be 39 A/cm-width (corresponding critical current density is 2.0 MA/$cm^2$).

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이축연신 PP/EVOH 블렌드 필름의 차단 성질 및 모폴로지 (Barrier Property and Morphology of Biaxially Oriented PP/EVOH Blend Film)

  • 여종호;이종훈;박찬석;이기준;남재도
    • 폴리머
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    • 제24권6호
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    • pp.820-828
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    • 2000
  • 본 연구에서는 블렌드 내의 분산상을 잘 발달된 판상 구조로 발현시켜 폴리프로필렌 (PP)/에틸렌 비닐알코올 공중합체 (EVOH) 블렌드의 차단 성질을 향상시키기 위하여 필름 제조 공정으로써 이축연신 공정을 사용하였다. 분산상 수지와 연속상 수지의 점도비로부터 용융 압출 공정시 변형의 정도를 파악하기 위하여 각 수지의 유변물성을 측정하였으며, 상용화제 함량과 연신 배율 및 연신 온도 등이 이축연신 블렌드 필름의 산소 투과도와 모폴로지에 미치는 영향을 조사하였다. l5 wt%의 EVOH를 첨가한 PP/EVOH 블렌드 필름의 산소차단성은 EVOH 분산상이 이축연신에 의해 넓은 면적의 판상구조로 발현되어 순수 PP에 비해 10배 정도까지 증가한 것으로 나타났다. 모폴로지를 조절하친 두 상간의 계면결합력을 증진시키기 위하여 PP-g-MAH와 ionomer를 사용한 결과, 차단 효과를 효과적으로 향상시키기 위해서는 상용화제를 블렌드에 최적의 함량으로 첨가해야 한다는 사실을 알 수 있었다. 또한 높은 연신 배율과 연신 온도로 이축연신하여 제조된 블렌드 필름에서 더욱 뚜렷한 판상 모폴로지가 관찰되었으며, 차단효과는 증가한 것으로 나타났다.

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축 처짐과 선미관 저널 베어링 유막 압력의 상호작용을 고려한 추진축계 정렬 해석 (Propulsion Shafting Alignment Analysis Considering the Interaction between Shaft Deflection and Oil Film Pressure of Sterntube Journal Bearing)

  • 조대승;장흥규;진병무;김국현;김성찬;김진형
    • 대한조선학회논문집
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    • 제53권6호
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    • pp.447-455
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    • 2016
  • Precise propulsion shafting alignment of ships is very important to prevent damage of its support bearings due to excessive reaction forces caused by hull deflection, forces acted on propeller and crankshaft, and so forth. In this paper, a new iterative shafting alignment calculation procedure considering the interaction between shaft deflection and oil film pressure of Sterntube Journal Bearing (SJB) bush with single or multiple slopes is proposed. The procedure is based on a pressure analysis to evaluate distributed equivalent support stiffness of SJB by solving Reynolds equation and a deflection analysis of shafting system by a finite element method based on Timoshenko beam theory. SJB is approximated with multi-point biaxial elastic supports equally distributed to its length. Their initial stiffness values are estimated from dynamic reaction force calculated by assuming SJB as single rigid support. Then, the shaft deflection and the support stiffness of SJB are sequentially and iteratively calculated by applying a criteria on deflection variation between sequential calculation results. To demonstrate validity and applicability of the proposed procedure for optimal slope design of SJB, numerical analysis results for a shafting system are described.

Y2Ba1Cu1Ox공정을 이용한 TFA-MOC YBCO 박막 공정 개발 (Fabrication of TFA-MOD YBCO Films Using Y2Ba1Cu1Ox Process)

  • 임준형;장석헌;김규태;이진성;윤경민;하홍수;주진호;나완수
    • 한국세라믹학회지
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    • 제43권2호
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    • pp.98-105
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    • 2006
  • YBCO film was synthesized by using a new approach to the TFA-MOD method. In the fabrication process, $Y_2Ba_1Cu_1O_x\;and\;Ba_3Cu_5O_8$ powders were used as precursors (the so called '211 process'), instead of Y-, Ba-, and Cu-based acetates, and dissolved in trifluoroacetic acid followed by calcining and firing heat treatment. Consequently, we successfully fabricated YBCO film and evaluated the phase formation, texture evolution, and critical properties as a function of the calcining and firing temperature and humidity, in order to explore its possible application in coated conductor fabrication. The films were calcined at $430-460^{\circ}C$ and then fired at $750-800^{\circ}C\;in\;a\;0-20\%$ humidified $Ar-O_2$ atmosphere. We observed that $BaF_2$ phase was effectively reduced and that a sharp and strong biaxial texture formed under humidified atmosphere leading to increased critical properties. In addition, we found that the microstructure varied significantly with the firing temperature: the grain grew further, the film became denser, and the degree of texture and phase purity varied as the firing temperature increased. For the film fired at $775^{\circ}C$ after calcining at $460^{\circ}C$, the critical current was obtained to be 39 A/cm-width (corresponding critical current density is $2.0\;MA/cm^2$ which was probably attributed to such factors as the enhanced phase purity and out-of-plane texture, the moderate film density and grain size, and crack-free surface.

Sputter Etching한 Poly(ethylene terrephthalate)와 Nylon 6 Film의 표면특성 (Surface Characteristics of Sputter Etched Poly(ethylene terephthalate) and Nylon 6 Films)

  • Kang, Koo;Wakida, T.;Cho, In-Sul;Cho, Hwan
    • 한국염색가공학회지
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    • 제3권2호
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    • pp.25-33
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    • 1991
  • Poly(ethylene terephthalate)(PET) and nylon 6 films stretched uniaxially and biaxially were sputter etched in the presence of argon gas. The surface of the etched films was investigated using a scanning electron microscope(SEM). While cracks perpendicular to the stretched direction were observed in the uniaxil stretched films sputter etched for 30 min., many protrusions were formed in the biaxial stretched films at the height of 0.3-0.4 gm for PET and $0.1-0.2\mum$ for nylon 6. The tops of two or three protrusions merged etching time increased to 60 min. The contact angle to water of the sputter etched PET and nylon 6 films decreased steeply when etched for one to 3 min. In order to investigate chemical changes on the surface ESCA analysis was carried out. In both films sputter etched $C_{1s}$ intensity decreased and $O_{1s}$ intensity increased compared with the unetched ones.

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적외선 센서 재료로 사용되는 고순도 ZnTe박막의 평가 (Evaluation of the High Purity ZnTe which is an Far-Infrared Sensor Material)

  • Kim, B.J.
    • 한국표면공학회지
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    • 제35권5호
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    • pp.305-311
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    • 2002
  • Optical measurements have been used to study the biaxial tensile strain in heteroeptaxial ZnTe epilayers on the (100) GaAs substrate by hot wall epitaxy (HWE) with Zn reservoir. It is effect on the low-temperature photoluminescence spectrum of the material. Optimum growth condition has been determined by a four-crystal rocking curve (FCRC) and a low temperature photoluminescence measurement (PL). It was found that Zn partial pressure from Zn reservoir has a strong influence on the quality of grown films. Under the determined optimum growth condition, ZnTe epitaxial films with thickness of 0.72~24.8$\mu\textrm{m}$ were grown for studying the effect of the thickness on crystalline quality. The PL and FCRC results indicated that the quality of ZnTe films becomes higher rapidly with increase of thickness up to 6$\mu\textrm{m}$. The best value of the FWHM of the four crystal rocking curve, 66 arcsec, was obtained on the film with 12$\mu\textrm{m}$ in thickness. The PL spectrum shows the splitted strong free exciton emissions and very weak deep band emissions. These results show the high quality of films.