• Title/Summary/Keyword: BiM

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Physical Properties of Polycrystalline Zinc-Substituted Lithium Ferrite (ZnO가 Lithium ferrite의 물리적 특성에 미치는 영향에 관한 연구)

  • 고재귀
    • Journal of the Korean Magnetics Society
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    • v.9 no.5
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    • pp.234-238
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    • 1999
  • Lithium ferrites are prominent in the element of microwave frequency communication core and high frequency memory core because of their low coercivity and the high squareness ratio. This paper reports primarily the development of lithium ferrites with the low coercivity and high squareness ratio. The materials with $Li_{0.48-0.5x}Bi_{0.02}Ni_{0.04}Zn_xFe_{2.46-0.5x}O_4$ (x = 0,0.01, 0.02, 0.03) have been prepared to investigate the physical properties. The addition of ZnO gave raised maximum induction $(B_m)$ and decreased coercive force $(H_c)$, but the squareness ratio $(R\;=\;B_m/B_r)$ was decreased. The specimen of squareness ratio R=0.82, coercive force $H_c=\;1.80\;Oe$ was obtained for $Li_{0.48-0.5x}Bi_{0.02}Ni_{0.04}Zn_xFe_{2.46-0.5x}O_4$ (X=0) sintered at 105$0^{\circ}C$. Also the sample of squareness ratio R = 0.75, coercive force $H_c=\;1.70\;Oe$ for $Li_{0.48-0.5x}Bi_{0.02}Ni_{0.04}Zn_xFe_{2.46-0.5x}O_4$ (X = 0) sintered at 110$0^{\circ}C$ was measured. The Tc was obtained 463$^{\circ}C$ and the Br of environmental temperature variation was stable.

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Synthesis of High-Aspect-Ratio BaTiO3 Platelets by Topochemical Conversion and Fabrication of Textured Pb(Mg1/3Nb2/3)O3-32.5PbTiO3 Ceramics

  • Zhao, Wei;E, Lei;Ya, Jing;Liu, Zhifeng;Zhou, Heping
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2305-2308
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    • 2012
  • Perovskite structured barium titanate particles ($BaTiO_3$) platelets were synthesized by molten salt synthesis and topochemical microcrystal conversion. As the precursors of $BaTiO_3$, plate-like $BaBi_4Ti_4O_{15}$ particles were first synthesized by the reaction of $Bi_4Ti_3O_{12}$, $BaCO_3$, and $TiO_2$ at $1080^{\circ}C$ for 3 h in $BaCl_2$-KCl molten salt. After the topochemical reactions, layer-structured $BaBi_4Ti_4O_{15}$ particles transformed to the perovskite $BaTiO_3$ platelets. $BaTiO_3$ particles with thickness of approximately $0.5{\mu}m$ and a length of $10-15{\mu}m$ retained the morphology feature of the $BaBi_4Ti_4O_{15}$ precursor. For <001> $Pb(Mg_{1/3}Nb_{2/3})O_3-32.5PbTiO_3$ (PMNT)-5 wt % PbO piezoelectric ceramics textured with 5 vol % of $BaTiO_3$ templates, the Lotgering factor reached 0.82, and $d_{33}$ was 870 pC/N.

A Study on Fabrication of $Sr_{0.9}Bi_{2.1}Ta_2O_9$ and $La_{0.5}Sr_{0.5}CoO_3$ Thin Films by Self-Patterning Technique (Self-Patterning을 이용한 강유전체 $Sr_{0.9}Bi_{2.1}Ta_2O_9$와 산화물 전극 $La_{0.5}Sr_{0.5}CoO_3$의 박막 제조에 관한 연구)

  • Lim, Jong-Chun;Cho, Tae-Jin;Kang, Dong-Kyun;Lim, Tae-Young;Kim, Byong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.116-119
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    • 2003
  • Self-patterning of thin films using photosensitive sol solution has advantages such as simple manufacturing process compared to photoresist/dry etching process. In this study, ferroelectric $Sr_{0.9}Bi_{2.1}Ta_2O_9$(SBT) and $La_{0.5}Sr_{0.5}CoO_3$(LSCO)thin films have been prepared by spin coating method using photosensitive sol solution. $Sr(OC_2H5)_2$, $Bi(TMHD)_3$ and $Ta(OC_2H)_5)_5$ were used as starting materials for SBT solution and $La(OCH_2CH_2OCH_3)_3$, $Sr(OC_2H_5)_2$, $CO(OCH_2CH_2OCH_3)_2$ were used for LSCO solution. Solubility difference by UV irradiation on LSCO thin film allows to obtain a fine patterning due to M-O-M bond formation. The lowest resistivity($4{\times}10^{-3}{\Omega}cm$) of LSCO thin films was obtained by annealing at $740^{\circ}C$.

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A Study on the Characteristic of High Tc Oxide Superconductor, Bi-Pb-Sr-Ca-Cu-O System (Bi-Pb-Sr-Ca-Cu-O계 산화물 고온초전도체의 특성에 관한 연구)

  • Kim, Y.S.;Lee, M.S.;Lee, M.S.;Jin, Y.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.1
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    • pp.13-18
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    • 1991
  • The formation of high $T_c$ phase is very sluggish and c parameter of unit cell of high $T_c$ phase is about $37{\AA}$. High $T_c$ oxide superconductor with a $T_c$ above 100 K has been successfully prepared by solid state reaction method in BiSrCaCuO system by Pb adding. The microstructure related to the formation of the high $T_c$ phase has been investigated. As compared with YBCO compound, the formation reaction of the high $T_c$ requires long time heat treatment. It is due to the transformation from the low $T_c$ phase to high $T_c$ phase. The sintering just below the melting point of the calcined powder mixture is effective on the formation of the high $T_c$ phase in Pb-added BiSrCaCuO system. The growth of the high $T_c$ superconducting phase has a thin plate shape, which is characterized by the c parameter of $37{\AA}$. The formation of the high $T_c$ phases is delayed by the excessive addition of Pb. The lattice parameter(c) of the unit cell (both the low and high $T_c$ phases) is increased with increase of Pb.

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Effect of α-Fe Content on the Magnetic Properties of MnBi/α-Fe Nanocomposite Permanent Magnets by Micro-magnetic Calculation

  • Li, Y.Q.;Yue, M.;Zuo, J.H.;Zhang, D.T.;Liu, W.Q.;Zhang, J.X.;Guo, Z.H.;Li, W.
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.245-249
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    • 2013
  • A finite element model was built for MnBi/${\alpha}$-Fe nanocomposite permanent magnets, and the demagnetization curves of the magnets were simulated by micro-magnetic calculation. The microstructure of the cubic model is composed of 64 irregular grains with an average grain size of 20 nm. With the volume fraction of soft magnetic phase (t vol. %) ranged from 5 to 20 vol. %, both isotropic and anisotropic nanocomposite magnets show typical single-phase permanent magnets behavior in their demagnetization curves, illustrating good intergranular exchange coupling effect between soft and hard magnetic phases. With the increase of volume fraction of soft magnetic phase in both isotropic and anisotropic magnets, the coercive force of the magnets decreases monotonically, while the remanence rises at first to a peak value, then decreases. The optimal values of maximum energy products of isotropic and anisotropic magnets are 84 and $200kJ/m^3$, respectively. Our simulation shows that the MnBi/${\alpha}$-Fe nanocomposite permanent magnets own excellent magnetic properties and therefore good potential for practical applications.

Enhancing X-ray radiation protection with novel liquid silicone rubber composites: A promising alternative to lead aprons

  • Wesam Abdullah;Ramzun M. Ramli;Thair Hussein Khazaalah;Nurul Zahirah Noor Azman;Tasnim M. Nawafleh;Farah Salem
    • Nuclear Engineering and Technology
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    • v.56 no.9
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    • pp.3608-3615
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    • 2024
  • This study introduces a lead-free alternative for enhanced radiation protection. While lead aprons effectively attenuate ionizing radiation, concerns regarding flexibility, weight, and environmental hazards persist. In response, the present research is focused on producing an innovative sheet shielding comprised of carefully selected dense metal oxide microparticles (DMOs-MPs) and liquid silicone rubber (LSR). To evaluate the efficacy of the LSR samples, the current study uses rigorous testing procedures, such as microstructure characterization using EDX and FESEM. Furthermore, the study investigated key attenuation parameters within the LSR samples. Radiation protection was greatly and effectively supplied using DMOs-MPs filler (Bi-1 to Bi-7) in LSR samples; this protection reached 99.9% in the X-ray energy range. Due to the unique characteristics of the Bi-7, the results demonstrated that the samples' shielding efficiency improved with the addition of high atomic number and high-density fillers. It had the greatest attenuation coefficient and density. At 60 keV, Bi-7's density was 2.980 gcm-3, and its LAC and MAC were 19.2621 cm-1 and 6.4638 cm2/g, respectively. It also had the lowest half-value layer values in the energy range of 60-120 keV. The LSR samples showed effective radiation absorption for different energy levels, indicating that LSR can enhance the flexibility and comfort of the apron while providing adequate radiation protection. The incorporation of the DMOs-MPs with LSR represents an effective contribution and a noteworthy stride to enhance the safety and well-being of medical professionals routinely exposed to ionizing radiation.

Geochemistry of Cu-Pb-Zn-Ag Deposits from the Euiseong Mineralized Area (의성 광화대 동-연-아연-은 광상의 지화학적 연구)

  • Chi, Se-Jung;Doh, Seong-Jae;Choi, Seon-Gyu;Lee, Jae-Ho
    • Economic and Environmental Geology
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    • v.22 no.3
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    • pp.253-266
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    • 1989
  • The Cu-Pb-Zn-Ag hydrothermal vein type deposits which comprise the Dongil and Dong-cheogogsan mines occur within the Cretaceous sedimentary rocks in the Euiseong Basin of the southern Korean peninsula. The ore mineralization is contained within three stage(I,II and III) quartz and calcite veins. Ore minerals occur as dominant chalcopyrite, galena, sphalerite, tetrahedrite and Pb, Ag, Sb and Bi-bearing sulfosalts. Stage I ore minerals were deposited between $400^{\circ}C$ and $200^{\circ}C$ from the fluid with moderate salinities(7.0 to 4.5 eq. wt. % NaCl). Evidence of boiling suggests pressure of less than 150 bars during stage I mineralization. This pressure corresponds to maximum depths of 650 m and 1700 m, respectively, assuming lithostatic and hydrostatic loads. The data on mineralogy, temperature and salinity, together with information on the solubility of Cu complex, suggest that Cu deposition is a result of boiling coupled with declining temperature from $350^{\circ}$ to $250^{\circ}C$ or declining log $a_{o_2}$(from -29.8 to -35.9 atm.)and increasing in pH. Pb, Ag, Sb and Bi-bearing sulfosalts were deposited by cooling and dilution at temperature of less than $250^{\circ}C$ from the ore fluid with less than -35.9 atm. of log $a_{o_2}$.

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Electrical properties of (Na0.5Bi0.5)(Zr0.75Ti0.25)O3 ceramic

  • Lily, Lily;Yadav, K.L.;Prasad, K.
    • Advances in materials Research
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    • v.2 no.1
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    • pp.1-13
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    • 2013
  • Lead-free compound $(Na_{0.5}Bi_{0.5})(Zr_{0.75}Ti_{0.25})O_3$ was prepared using conventional ceramic technique at $1070^{\circ}C$/4h in air atmosphere. X-ray diffraction analysis showed the formation of single-phase orthorhombic structure. Permittivity data showed low temperature coefficient of capacitance ($T_{CC}{\approx}5%$) up to $100^{\circ}C$. Complex impedance studies indicated the presence of grain boundary effect, non-Debye type dielectric relaxation and evidences of a negative temperature coefficient of resistance. The ac conductivity data were used to evaluate the density of states at Fermi level and apparent activation energy of the compound.

Internal GPS Antenna for Mobile Phone (휴대단말기 내장형 GPS 안테나)

  • Hwang, Jae-Ho
    • Journal of Advanced Navigation Technology
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    • v.6 no.2
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    • pp.113-118
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    • 2002
  • In this paper, an internal GPS antenna for mobile phones is designed and fabricated. For the miniaturization of the antenna, high permittivity dielectric substrate((${\varepsilon}_r$=90) and small ground plane ($13mm{\times}13mm$) are used. To increase the receive gain, the antenna is composed with LNA(Low Noise Amplifier). Results of the manufactured antenna($13mm{\times}13mm{\times}8mm$) show that the maximum antenna gain is about 12 dBi, the axial ratio is less than 3 dB, and the current consumption of LNA is less than 4 mA.

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Preparation and characteristic of long 19-filamentary Bi-2223 tapes and coil

  • Heong, D.Y.;Kim, H.K.;Lee, H.Y.;Cha, M.K.;Jin, H.S.;Ha, H.S.;Oh, S.S.
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.291-291
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    • 1999
  • Long 19-filamentary Bi-2223 tapes were prepared using the so called "powder-in-tube" method. In the preparation, two types of precursor powders and two different reduction rates during rolling were used. Also two rolling method, which resulted in different filament geometry, were used. The characteristics of the tapes will be presented. Also A coil was prepared using two 56 m-long 19-filament tape. It was consisted of two double pancake coils. Each pancake, which is separated by FRP spacer, was composed of 98 turns. The experimental results will be presented and compared to the simulation result.

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