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Multiferroic Property and Crystal Structural Transition of BiFeO3-SrTiO3 Ceramics

  • Kim, A-Young;Han, Seung-Ho;Kim, Jeong-Seog;Cheon, Chae-Il
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.307-311
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    • 2011
  • Solid solutions of the (1-x)$BiFeO_3-xSrTiO_3$ ceramic system (x = 0~0.4) are explored here in attempts to obtain multiferroic properties in these systems. The polarization-electric field hysteresis, magnetization-magnetic field curves, and dielectric properties are also characterized. This solid-solution system shows a crystal structural transition from a noncentrosymmetric (R3c) structure to a centrosymmetric (Pm-3m) structure at 0.3 < x < 0.4. The solid solution ceramic shows unsaturated M-H behavior and low remanent magnetization over the composition region of 0.1 ${\leq}$ x ${\leq}$ 0.3. The $0.7BiFeO_3-0.3SrTiO_3$ system shows the largest value of $M_s$ at 0.17 emu/g and the smallest value of $H_c$ at 1.06 kOe. The P-E hysteresis curves were not saturated under an electric field as high as E = 70 kV/cm. This system is considered to have multiferroic characteristics in the composition range of 0.1 ${\leq}$ x ${\leq}$ 0.3.

Characteristics of Mn-Ni-Co system for automobile fuel shortage detecting sensor with $Bi_2O_3$ addition ($Bi_2O_3$를 첨가한 Mn-Ni-Co계 써미스타의 자동차 연료 부족 감지용 센서 특성)

  • 윤중락;이헌용;김두용;오창섭
    • Electrical & Electronic Materials
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    • v.9 no.5
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    • pp.455-462
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    • 1996
  • Automobile Fuel Shortage Detecting Sensor, in this paper, was fabricated by using heat dissipation coefficient difference between gasoline and air condition the NTC thermistor of Mn-Ni Co system with the composition ratio of Mn$_{3}$O$_{4}$ : 9wt%, NiO : 28wt%, and CO$_{3}$O$_{4}$ : 61wt%. The condition of sensor operation is that, for turn-on characteristics, the time of arriving at 135mA must be less than 180 second when the DC voltage of 11V is applied in the air condition of -10.deg. C and that, for turn-off characteristics, the saturation current must be less than 60mA when the DC voltage of 15V is applied in the gasoline condition of 60.deg. C. It is known, from the experimental results, that the resistance range and B-constant for the Automobile Fuel Shortage Detecting Sensor with dimension of 5*3*0.9mm were 850-1150.ohm. and 1150-1250.deg. C, respectively and the resistance range and B-constant were agree with that of sensor operation condition. When Bi$_{2}$O$_{3}$ of 0-0.5wt% was added to Mn$_{3}$O$_{4}$ : 9wt%, NiO : 28wt%, and CO$_{3}$O$_{4}$ : 61wt% composition, the resistivity and B-value were 380-430(.ohm.-cm) and 1930 - 2030, respectively. Particularly, for Bi$_{3}$O$_{3}$ of 0.25-0.5wt%, the sintering density of over 90% and the operation characteristics necessary to Automobile Fuel Shortage Detecting Sensor were obtained. The difference of heat dissipation coefficient gasoline and air condition was 15 times.

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An Integrated Si BiCMOS RF Transceiver for 900 MHz GSM Digital Handset Application (I) : RF Receiver Section (900MHz GSM 디지털 단말기용 Si BiCMOS RF송수신 IC개발 (I) : RF수신단)

  • Park, In-Shig;Lee, Kyu-Bok;Kim, Jong-Kyu;Kim, Han-Sik
    • Journal of the Korean Institute of Telematics and Electronics S
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    • v.35S no.9
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    • pp.9-18
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    • 1998
  • A single RF transceiver chip for an extended GSM handset application was designedm, fabricated and evaluated. A RFIC was fabricated by using silicon BiCMOS process, and then packaged in 80 pin TQFP of $10 {\times} 10 mm^{2}$ in size. As a result, it was achieved guite reasonable integraty and good RF performance at the operation voltage of 3.3V. This paper describes development results of RF receiver section of the RFIC, which includes LNA, down conversion mixer, AGC, switched capacitor filter and down sampling mixer. The test results show that RF receiver section is well operated within frequency range of 925 ~960 MHz, which is defined on the extended GSM specification (E-GSM). The receiver section also reveals moderate power consumption of 67 mA and minimum detectable signal of -105 dBm.

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PREPARATION AND CHARACTERIZATION OF MULTIFERROIC 0.8 $BiFeO_3$-0.2 $BaTiO_3$ THIN FIMLS BY PULSED LASER DEPOSITION

  • Kim, K.M.;Yang, P.;Zhu, J.S.;Lee, H.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.313-313
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    • 2010
  • $BiFeO_3$ (BFO), when forming a solid solution with $BaTiO_3$ (BTO), shows structural transformations over the entire compositional range, which not only gives a way to increase structural stability and electrical resistivity but also applies a means to have better ferromagnetic ordering. In this respect, we have prepared and studied 0.8 BFO-0.2 BTO thin films on Pt(111)/$TiO_2/SiO_2$/Si substrates by pulsed laser deposition. Various deposition parameters, such as deposition temperature and oxygen pressure, have been optimized to get better quality films. Based on the X-ray diffraction results, thin films were successfully deposited at the temperature of $700^{\circ}C$ and an oxygen partial pressure of 10mTorr and 330mTorr. The dielectric, ferroelectric, and magnetic properties have then been characterized. It was found that the films deposited under lower and higher oxygen pressure corresponded to lower leakage current. Magnetism measurement showed an induced ferromagnetism. The microstructures associated with the magnetic and dielectric properties of this mixed-perovskite solid solutions were observed by transmission electron microscopy, which revealed the existence of complicated ferroelectric domains, suggested that the weak spontaneous magnetization was closely associated with the decrease in the extent of rhombohedral distortion by a partial substitution of $BaTiO_3$ for $BiFeO_3$.

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Stability Analysis of Some Agronomical Characters and Yield Components of Barley in Response to Irrigation Period

  • Anisuzzaman, M.;Alam, Iftekhar;Rahman, A.H.M.Mahbubur;Islam, A.K.M.R.;Ahsan, Nagib
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.52 no.4
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    • pp.469-473
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    • 2007
  • With the aim to analyze stability performance of six promising barley genotypes, eleven yield related characters were evaluated employing varied irrigation treatments under the tropical climate of Northern part in Bangladesh. Analysis of variance(ANOVA), phenotypic index, regression co-efficient(bi) and deviation from regression($s^2_d$) of the individual genotypes were estimated to evaluate the stable performance of the genotypes. A significant interaction was observed between the genotypes and irrigation period($G{\times}T$). Among all the genotypes, BSH-2 showed stable performance for plant height under different irrigation period, where $P>\bar{X},\;bi{\sim}1\;and\;s^2_d{\sim}0$. High phenotypic index, lower bi value and low deviations from regression were observed in case of spikelet number per spike and grain number per spike for genotype BSH-2 and plant height, spike length and harvest index per plant for BB-2 which suggest that those parameters were not usually affected by irrigation. On the other hand the genotype BSH-2 for tiller number and BB-1 for the fertile tiller number were not suitable for favorable moisture content, where $P<\bar{X},\;bi>1.0\;and\;low\;s^2_d$. Thus we suggest that genotype BSH-2 might have transmit high mean and increased phenotypic stability to the next progenies, which may consider as an ideal genotype for developing improved barely cultivars.

Kinetics of Malonyl-CoA Synthetase from Rhizobium trifolii and Evidences for Malonyl-AMP Formation as a Reaction Intermediate

  • Kang, Sang-Won;Hong, Sung-Yu;Ryoo, Hyung-Don;Rhyu, Gyung-Ihm;Kim Yu-Sam
    • Bulletin of the Korean Chemical Society
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    • v.15 no.5
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    • pp.394-399
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    • 1994
  • The catalytic mechanism of malonyl-CoA synthetase from Rhizobium trifolii was investigated by the steady state kinetics and intermediate identification. Initial velocity studies and the product inhibition studies with AMP and PPi strongly suggested ordered Bi Uni Uni Bi Ping-Pong Ter Ter system as the most probable steady state kinetic mechanism of malonyl-CoA synthetase. Michaelis constants were $0.17{\pm}0.04 {\mu}M,\;0.24{\pm}0.18 {\mu}M\;and\;0.045{\pm}0.26 {\mu}$M for ATP, malonate and CoA, respectively. The TLC analysis of the $^{32}P-labelled$ products in reaction mixture containing $[{\gamma}-^{32}P]$ ATP in the absence of CoA showed that PPi was produced after the sequential addition of ATP and malonate. Formation of malonyl-AMP, suggested as an intermediate in the kinetically deduced mechanism, was confirmed by the analysis of $^{31}P-NMR$ spectra of AMP product isolated from the $^{18}O$ transfer experiment using $[^{18}O]$malonate. Two resonances were observed, corresponding to AMP labelled with zero and one atom of $^{18}O$, indicating that one atom of $^{18}O$ transferred from $[^{18}O]$malonate to AMP through the formation of malonyl-AMP. Formation of malonyl-AMP was also confirmed through the TLC analysis of reaction mixture containing $[{\alpha}-^{32}P]$ATP. These results strongly support the ordered Bi Uni Uni Bi Ping-Pong Ter Ter mechanism deduced from the initial velocity and product inhibition studies.

Dynamic Stability of a Railroad Bridge Using Bi-prestressing Technology (바이프리스트레싱 기법을 이용한 철도교량의 동적안정성)

  • Choi, Sanghyun;Lee, Changsoo;Lim, Jaehoon;Lee, Seungjoon;Yang, Sungdon
    • Journal of the Society of Disaster Information
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    • v.9 no.2
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    • pp.188-194
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    • 2013
  • As the high speed railroad line increases, researches on developing a more economic high speed railroad bridge system have been actively conducted. In this paper, a new type of prestressed concrete girder based on the bi-prestressing technique, which can introduce additional prestress, is presented. The additional prestress can be introduced using a wedge-shaped pin bar into the upper part of the girder section. The applicability of the new girder technique to the high speed railroad bridge is verified via the dynamic stability analysis. Dynamic moving load analyses using the KTX train load are conducted on bridge systems with the span lengths of 30m, 35m, and 40m, respectively. The results of the analysis show that all bridge systems satisfy the limits prescribed in the design specifications to ensure structural stability, driving safety, and ride quality.

Analysis of a.c. Characteristics in $ZnO-Bi_2O_3-Cr_2O_3$ Varistor Using Dielectric Functions (유전함수를 이용한 $ZnO-Bi_2O_3-Cr_2O_3$ 바리스터의 a.c. 특성 분석)

  • Hong, Youn-Woo;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.14-14
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    • 2009
  • In this study, we investigated the effects of Cr dopant on the bulk trap level and grain boundary characteristics of $Bi_2O_3$-based ZnO (ZB) using dielectric functions such as $Z^*$, $Y^*$, $M^*$, ${\varepsilon}^*$, and $tan{\delta}$. More than two bulk traps of $Zn_i$ and $V_o$ probably in different ionization states could be identified in ZBCr($ZnO-Bi_2O_3-Cr_2O_3$). The grain boundaries of ZBCr could be electrochemically divided into two types: sensitive to ambient oxygen and thus electrically active one and oxygen-insensitive and thus electrically inactive one.

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Dielectric and Piezoelectric Characteristics of Low Temperature Sintering PbTiO3 System Ceramics with amount of Bi2O3 Addition (Bi2O3 첨가량에 따른 저온소결 PbTiO3계 세라믹스의 유전 및 압전특성)

  • Yoo, Ju-Hyun;Kim, Do-Hyung;Lee, Sang-Ho;Sohn, Eun-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.771-775
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    • 2007
  • In this study, in order to develop low temperature sintering ceramics for thickness vibration mode multilayer piezoelectric transformer, $PbTiO_3$ system ceramics were fabricated using $Na_2CO_3,\;Li_2CO_3,\;MnO_2\;and\;Bi_2O_3$ as sintering aids and their dielectric and piezoeletric properties were investigated according to the amount of $Bi_2O_3$ addition. At the sintering temperature of $900^{\circ}C\;and\;Bi_2O_3$ addition of 0.1 wt%, density, grain size, thickness vibration mode eletromechanical coupling factor($k_t$), thickness vibration mode mechanical quality factor($Q_{mt}$) and dielecteic constant(${\varepsilon}_r$) showed the optimum value of $6.94g/cm^3,\;2.413{\mu}m$, 0.497, 3,162 and 209, respectively, for thickness vibration mode multilayer piezoelectric transformer application.

Thermoelectric Property of Ball Milled Bi-Te-Sb Powder (볼밀링한 Bi-Te-Sb계 분말의 열전특성에 관한 연구)

  • Yu Ji-Hun;Bae Seung-Chul;Ha Gook-Hyun;Kim Byoung-Kee;Lee Gil-Gun
    • Journal of Powder Materials
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    • v.12 no.6 s.53
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    • pp.387-392
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    • 2005
  • The p-type semiconductor $Bi_2Te_3-Sb_2Te_3$ thermoelectric materials were fabricated by melting, milling and sintering process and their thermoelectric properties were characterized. The compound materials were ball-milled with milling time and the powders were sintered by spark plasma sintering process. The ball milled powders had equiaxial shape and approedmately $1\~3{\mu}m$ in size. The figure of meritz of sintered thermoelectric materials decreased with milling time because of lowered electrical resistivity. The thermoelectric properties of $Bi_2Te_3-Sb_2Te_3$ materials have been discussed in terms of electrical property with ball mill process.