• BMB Reports
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• 제28권3호
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• pp.204-209
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• 1995

The pH dependence of kinetic parameters in the amination direction of the aspartase from Hafnia alvei has been determined. The V/K for fumarate is bell shaped with pK values of 6.4 and 8.7. The maximum velocity for fumarate is also bell shaped with pK values of 7.2 and 9.1. The pH dependence of 1/K, for potassium (competitive inhibitor of ammonia) decreases at low pH with pK 7.6. Together with data [Yoon and Cook (1994) Korean J. Biochem. 27, 1-5] on the deamination direction of the aspartase, these results are consistent with two enzyme groups which are necessary for catalysis. An enzymatic group that must be deprotonated has been identified. Another enzyme group must be protonated for substrate binding. Both the general base and general acid group are in a protonation state opposite that in which they started when aspartate was bound. A proton is abstracted from C-3 of the monoanionic form of L-aspartate by an enzyme general base with, a pK of 6.3~6.6 in the absence and presence of $Mg^{2+}$ Ammonia is then expelled with the assistance of a general acid group giving $NH_{4+}$ as the product.

• 한국추진공학회지
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• 제4권4호
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• pp.70-77
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• 2000

초음속 2단벨노즐(SDBN)은 종래의 축소확대형 초음속 노즐의 벽면에 변곡점을 설치하여, 비행체의 고도에 따른 노즐내부의 유동특성을 조절하기 위한 새로운 개념의 추진노즐이다. 본 연구에서는 이러한 SDBN의 유용성과 유동특성을 조사하기 위하여 축대칭 Navier-Stokes 방정식을 유한체적법으로 수치계산하였다. 본 연구의 결과로부터 SDBN의 Base 노즐의 길이는 SDBN 내부에서 발생하는 충격파 시스템에 영향을 미칠 뿐만 아니라, 노즐 유동의 박리위치가 변곡점에 고착되는 넓은 범위의 압력비가 존재한다는 것을 알았다. 또 SDBN의 최대추력은 노즐출구에서 유동이 적정팽창 상태일 때 발생한다는 것을 알았다.

• Advances in materials Research
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• 제6권2호
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• pp.185-220
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• 2017

Merits, attributes and challenges associated with the application of analytical modeling in electronics and photonics materials science are addressed, based mostly on the author's research during his tenure with Bell Labs, University-of-California, Portland State University, and small business innovative research (SBIR) ERS Co., USA. The emphasis is on practically important, yet often paradoxical, i.e., intuitively non-obvious, material behaviors. It is concluded that when material reliability is crucial, ability to effectively quantify it is imperative, and that analytical modeling is the most suitable, although never straightforward, technique to understand, explain and quantify material behaviors, especially in extreme, extraordinary and paradoxical situations.

• Bulletin of the Korean Chemical Society
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• 제6권5호
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• pp.280-284
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• 1985

Kinetic measurements of the 5-nitrofurfural-hydrazine reaction in various pH ranges of aquous solution were carried out by ultraviolet spectrophotometry at $25^{\circ},\;35^{\circ}\;and\;45^{\circ}C$. The observed rate of the reaction varies with the change in pH, which gives characteristic "bell-type" rate acidity profile. The maximum rate is shown in the vicinity of pH 4. This reaction procceds with rate-determining attack of hydrazine on the 5-nitrofurfural at low pH and undergoes a change in rate-determining step to dehydration of the addition intermediate as pH increases. The reaction has a "reactant-like transition state" which precedes intermediate in low pH and "product-like transition state" which follows it in neutral pH. The geometry of 5-nitrofurfural-hydrazine intermediate was estimated with PCILO method associated with CNDO/2 scheme.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제7권10호
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• pp.2430-2447
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• 2013

In recent years, HTTP adaptive streaming (HAS) has attracted considerable attention as the state-of-the-art technology for video transport. HAS dynamically adjusts the quality of video streaming according to the network bandwidth and device capability of users. Content-Centric Networking (CCN) has also emerged as a future Internet architecture, which is a novel communication paradigm that integrates content delivery as a native network primitive. These trends have led to the new research issue of harmonizing HAS with the in-network caching provided by CCN routers. Previous research has shown that the performance of HAS can be improved by using the H.264/SVC(scalable video codec) in the in-network caching environments. However, the previous study did not address the misbehavior that causes video freeze when overestimating the available network bandwidth, which is attributable to the high cache hit rate. Thus, we propose a new SVC-based adaptation algorithm that utilizes a drop timer. Our approach aims to stop the downloading of additional enhancement layers that are not cached in the local CCN routers in a timely manner, thereby preventing excessive consumption of the video buffer. We implemented our algorithm in the SVC-HAS client and deployed a testbed that could run Smooth-Streaming, which is one of the most popular HAS solutions, over CCNx, which is the reference implementation of CCN. Our experimental results showed that the proposed scheme (SLA) could avoid video freeze in an effective manner, but without reducing the high hit rate on the CCN routers or affecting the high video quality on the SVC-HAS client.

• Nuclear Engineering and Technology
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• 제52권1호
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• pp.148-154
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• 2020

The radiation induced segregation of Cr at grain boundaries (GBs) in Ferritic/Martensitic steels was modeled assuming vacancy and interstitialcy diffusion mechanisms. In particular, the dependence of segregation on temperature and grain boundary misorientation angle was analyzed. It is found that Cr enriches at grain boundaries at low temperatures primarily through the interstitialcy mechanism while depletes at high temperatures predominantly through the vacancy mechanism. There is a crossover from Cr enrichment to depletion at an intermediate temperature where the Cr:Fe vacancy and interstitialcy diffusion coefficient ratios intersect. The bell-shape Cr enrichment response is attributed to the decreasing void sinks inside the grains as temperature rises. It is also shown that low angle grain boundaries (LAGBs) and special Σ coincidence-site lattice (CSL) grain boundaries exhibit suppressed radiation induced segregation (RIS) response while high angle grain boundaries (HAGBs) have high RIS segregation. This different behavior is attributed to the variations in dislocation density at different grain boundaries.

• 한국광물학회지
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• 제12권1호
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• pp.1-10
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• 1999

Talc (Mg3Si4O10(OH)2), one of the sheet silicate minerals, which is the hydrothermal alteration product of serpentinite at Cheongarm mine was prepared for the high pressure compressibility studies. Energy dispersive X-ray diffraction experiment was carried out using the Synchrotron Radiation with the Mao-Bell type diamond anvil cell at room temperature. Polycrystalline talc was mixed with MgO powder for pressure sensor as well as pressure medium in the sample chamber. High pressure runs were performed at pressures up to 35.2 GPa. Talc shows no phase transition within the present high pressure region. Bulk modulus of this talc was determined by the Birch-Murnaghan equation of state to be 78 GPa assuming its first pressure derivative Ko' of 4.

• 대한산업공학회지
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• 제15권2호
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• pp.93-101
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• 1989

The classic machine repair problem is extended to the case where a number of different machines are arranged in the sequence of operation. The steady-state availability of the system with a series of operating machines is maximized under some constraints such as total cost, available space. In order to find the optimal numbers of spare units and repair channels for each operating machine, the problem is formulated as non-linear integer programming(NLIP) problem and an efficient algorithm, which is a natural extension of the new Lawler-Bell algorithm of Sasaki et al., is used to solve the NLIP problem. A numerical example is given to illustrate the algorithm.

• 한국의류학회지
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• 제18권5호
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• pp.727-738
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• 1994

It has been representing the delicate changes which express new sentiments through the floating, fluid, free look with the transparent, sheer material in fashion during the early 1990's. The concept of lightness is selected to describe the phenomenon of recent fashion. The purpose of this study is to identify the distinctive characteristics of lightness as external forms and internal meaning in fashion of the early 1990's. The data were collected from fashion magazines such as American Vogue, Italian Vogue from 1987 to 1994. The characteristics of lightness of fashion in the early 1990's are as follows; The external forms are consisted of the material such as the transparent, sheer, soft material, of slim and bell silhouette which occupying the more space in bottom, of the drapery, pleats to shape the unfitted look and is identified as the open, whole, indeterminate and planar intergration form according to the category of clothing form suggested by Belong. It is also the reflection of the social changes which is getting out of the modernity. It is the results of the dominant social state which are diffused the sensual pleasures, transitoriness.

• 품질경영학회지
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• 제19권1호
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• pp.129-140
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• 1991

This paper deals with on (S-1, S) spare-part inventory model for multi-stage machine repair problem with attrition. The steady-state availability of the system is maximized under some constraints such as total cost, available space etc.. The problem is formulated as a closed queueing network and the system availability is calculated by Buzen's computational algorithm. In order to find the optimal numbers of spare units and repair channels for each operating stage, the problem is formulated as a non-linear integer programming(NLIP) problem and an efficient algorithm. which is a natural extension of the new Lawler-Bell algorithm of Sasaki et el., is used to solve the NLIP problem. A numerical example is given to illustrate the algorithm.