• Title/Summary/Keyword: Battery Storage

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Carbon-free Polymer Air Electrode based on Highly Conductive PEDOT Micro-Particles for Li-O2 Batteries

  • Yoon, Seon Hye;Kim, Jin Young;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.220-228
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    • 2018
  • This study introduced a carbon-free electrode for $Li-O_2$ cells with the aim of suppressing the side reactions activated by carbon material. Micro-particles of poly(3,4-ethylenedioxythiophene) (PEDOT), a conducting polymer, were used as the base material for the air electrode of $Li-O_2$cells. The PEDOT micro-particles were treated with $H_2SO_4$ to improve their electronic conductivity, and LiBr and CsBr were used as the redox mediators to facilitate the dissociation of there action products in the electrode and reduce the over-potential of the $Li-O_2$ cells. The capacity of the electrode employing PEDOT micro-particles was significantly enhanced via $H_2SO_4$ treatment, which is attributed to the increased electronic conductivity. The considerable capacity enhancement and relatively low over-potential of the electrode employing $H_2SO_4$-treated PEDOT micro-particles indicate that the treated PEDOT micro-particles can act as reaction sites and provide storage space for the reaction products. The cyclic performance of the electrode employing $H_2SO_4$-treated PEDOT micro-particles was superior to that of a carbon electrode. The results of the Fourier-transform infrared spectroscopic analysis showed that the accumulation of residual reaction products during cycling was significantly reduced by introducing the carbon-free electrode based on $H_2SO_4$-treated PEDOT micro-particles, compared with that of the carbon electrode. The cycle life was improved owing to the effect of the redox mediators. The refore, the use of the carbon -free electrode combined with redox mediators could realize excellent cyclic performance and low over-potential simultaneously.

A feasibility study on the hybrid power generation system considering of electricity needs' fluctuation of coastal area's houses (해안지역 주거시설을 위한 전력수요 변동 대응형 하이브리드 발전시스템 도입 효과 예측에 관한 사례연구)

  • Hwang, Kwang-Il
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.8
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    • pp.977-983
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    • 2013
  • Based on the consideration of the hourly patterns of the electricity power consumption, this study predicted the effectiveness of hybrid power generation system, which is composed with wind power generator and photovoltaic generator. And this case study is performed at Konrido, which is a affiliated island of Kyeongsangnam-do. As the results, it is obvious that it is not efficient to cover the whole electricity power consumption only with any single power generating system, because the hourly patterns of electricity power consumption, wind power generation and photovoltaic generation are quite different. And because the wind is being through almost 24 hours, it is also found out that wind power generating system with storage battery is the most efficient combination for this case study.

Particle Swarm Optimization Using Adaptive Boundary Correction for Human Activity Recognition

  • Kwon, Yongjin;Heo, Seonguk;Kang, Kyuchang;Bae, Changseok
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.8 no.6
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    • pp.2070-2086
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    • 2014
  • As a kind of personal lifelog data, activity data have been considered as one of the most compelling information to understand the user's habits and to calibrate diagnoses. In this paper, we proposed a robust algorithm to sampling rates for human activity recognition, which identifies a user's activity using accelerations from a triaxial accelerometer in a smartphone. Although a high sampling rate is required for high accuracy, it is not desirable for actual smartphone usage, battery consumption, or storage occupancy. Activity recognitions with well-known algorithms, including MLP, C4.5, or SVM, suffer from a loss of accuracy when a sampling rate of accelerometers decreases. Thus, we start from particle swarm optimization (PSO), which has relatively better tolerance to declines in sampling rates, and we propose PSO with an adaptive boundary correction (ABC) approach. PSO with ABC is tolerant of various sampling rate in that it identifies all data by adjusting the classification boundaries of each activity. The experimental results show that PSO with ABC has better tolerance to changes of sampling rates of an accelerometer than PSO without ABC and other methods. In particular, PSO with ABC is 6%, 25%, and 35% better than PSO without ABC for sitting, standing, and walking, respectively, at a sampling period of 32 seconds. PSO with ABC is the only algorithm that guarantees at least 80% accuracy for every activity at a sampling period of smaller than or equal to 8 seconds.

The Characterization of New Type of Alkaline Fuel Cell using Hydrogen Storage Alloys (수소저장합금을 이용한 신개념의 알칼라인 연료전지의 특성에 관한 연구)

  • Kim, Jin-Ho;Lee, Ho;Lee, Han-Ho;Lee, Paul S.;Lee, Jal-Young
    • Journal of Hydrogen and New Energy
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    • v.13 no.2
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    • pp.135-142
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    • 2002
  • 본 연구는 Chemical hydride 형태의 수소발생제를 포함한 액체연료를 이용한 신개념의 알칼라인 연료전지의 특성을 분석하였다. Chemical hydride는 연료전지의 수소공급원으로써 사용될 수 있으며, 본 연구팀은 KOH 전해질에 수소발생제인 Sodium Borohydride ($NaBH_4$)를 첨가하여 제조된 액체연료를 알칼라인 연료전지에 공급함으서 상온에서 매운 우수한 전기 화학적 성능결과를 얻을 수 있었다. 이때 음극 찰물질로 $ZrCr_{0.8}Ni_{1.2}$ 수소저장합금이 사용되었으며, 양극은 방수처리된 카본지 위에 분산된 Pt/C 가 사용되었고, air가 latm으로 양극에 공급되었다. 음극에 대한 XRD 분석결과 음극에서의 산화에 의해 Sodium Borohydride ($NaBH_4$)가 분해되어 수소가 발생되며, 연속적으로 액체연료가 주입되어도 전지가 작동하는 것을 확인할 수 있었다. 이때 에너지밀도는 6,000 Ah/kg (for $NaBH_4$ or $KBH_4$)이다.

A study on RFID Middleware protocol for management of sensor node and network implementation in Ubiquitous environment (유비쿼터스 환경에서 센서 노드의 관리와 망 구성을 위한 RFID 미들웨어 프로토콜에 관한 연구)

  • Choi, Yong-Sik;Kim, Sung-Sun;Shin, Seung-Ho
    • Journal of the Korea Society of Computer and Information
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    • v.12 no.3
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    • pp.155-163
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    • 2007
  • In this paper, Though sensors of Ubiquitous Middle-ware System based on RFID/USN can usually be reacted from six mouths to two years, they can be exhausted their power of storage battery only one day by communication rates and ranges. That is, the lifetime of sensor node is depended on how much spending power under wireless communication that can communicate its sensing data to its destination. Therefore, it is necessary that each sensor should be designed the Routing path to its destination, in order to remote collecting data. But, in order to improve lifetime of sensor node and modify inner setting, it is opposite to simple searching path method of sensor node by entering external commands. accordingly, 1:n sensor arrangement of n form command and data send-receive that is possible simulation do without interference other sensors and research to different sensor data analysis and conversion ways to convert Sensing data that accept from sensors to actuality information.

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Behavior Analysis of a Self Excited Induction Generator with Various Loads for a Hybrid Electric Propulsion System (하이브리드 전기추진시스템 구축을 위한 SEIG의 출력 특성 분석)

  • Yang, Joo-Ho;Choi, Gyo-Ho;Lee, Jae-Min;Jeong, Seok-Kwon
    • Journal of Power System Engineering
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    • v.22 no.1
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    • pp.41-47
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    • 2018
  • This paper analyzes the output characteristics of a self excited induction generator with isolated mode according to change of its speeds and loads for building a hybrid electric propulsion system in special purpose ships by using power take off. The induction generators are being considered as an alternative choice to the well-developed generators because of their lower unit cost, inherent ruggedness, operational and maintenance simplicity. However, the generator working by stand alone has a few problems that the reactive power is required to establish the air gap magnetic flux, and the induced voltage and magnetizing current fluctuate when the load is varied. In spite of its advantages, basic design data of the capacitor bank and behaviors of the output characteristics of the generator are not sufficient for the system. Based on the operating condition(speed range of main engine) of the target boat, a reduced experimental equipment system was constructed to analyze the output characteristics of the SEIG. And a suitable capacitor bank of a stand-alone generator and its output characteristics under various loads was investigated in detail through these experiments. According to the experimental result, it was confirmed that the capacitor bank should be $70{\mu}F{\sim}100{\mu}F$, and the proper SEIG induced voltage should be DC 80 V ~ 250 V in order to storage electrical energy into a battery.

Amorphous Vanadium Titanates as a Negative Electrode for Lithium-ion Batteries

  • Lee, Jeong Beom;Chae, Oh. B.;Chae, Seulki;Ryu, Ji Heon;Oh, Seung M.
    • Journal of Electrochemical Science and Technology
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    • v.7 no.4
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    • pp.306-315
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    • 2016
  • Amorphous vanadium titanates (aVTOs) are examined for use as a negative electrode in lithium-ion batteries. These amorphous mixed oxides are synthesized in nanosized particles (<100 nm) and flocculated to form secondary particles. The $V^{5+}$ ions in aVTO are found to occupy tetrahedral sites, whereas the $Ti^{4+}$ ions show fivefold coordination. Both are uniformly dispersed at the atomic scale in the amorphous oxide matrix, which has abundant structural defects. The first reversible capacity of an aVTO electrode ($295mAhg^{-1}$) is larger than that observed for a physically mixed electrode (1:2 $aV_2O_5$ | $aTiO_2$, $245mAhg^{-1}$). The discrepancy seems to be due to the unique four-coordinated $V^{5+}$ ions in aVTO, which either are more electron-accepting or generate more structural defects that serve as $Li^+$ storage sites. Coin-type Li/aVTO cells show a large irreversible capacity in the first cycle. When they are prepared under nitrogen (aVTO-N), the population of surface hydroxyl groups is greatly reduced. These groups irreversibly produce highly resistive inorganic compounds (LiOH and $Li_2O$), leading to increased irreversible capacity and electrode resistance. As a result, the material prepared under nitrogen shows higher Coulombic efficiency and rate capability.

Electrode properties upon the substitution of Mo for Mn in Zr-basd AB2-type Hydrogen Storage Alloys (Zr1-xTixV0.4Ni1.2Mn0.4-yMoy계 합금전극의 Mo 함량에 따른 물성 및 전극특성)

  • Seo, Chan-Yeol;Park, Choong-Nyeon
    • Journal of Hydrogen and New Energy
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    • v.11 no.4
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    • pp.189-202
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    • 2000
  • $AB_2$ type Zr-based Laves phases alloys have been studied for potential application as a negative electrode in a Ni-MH battery. The $AB_2$-type electrodes have a much higher energy density than $AB_5$-type electrodes per weight, however they have some disadvantages such as poor activation behavior and cycle life etc. Nonetheless, the $AB_2$-type electrodes have been studied very extensively due to their high energy density. In this study, in order to develop the cycle life, the Mn of $AB_2$ alloy composition was substituted partially by Mo. The alloys were melted by arc furnace and remelted 4-5 times for homogeneity. The alloy powder was used below 200-325 mesh for experiments. The structures and phases of the alloys were analyzed by XRD, SEM and EDS, and measured the curve of a pressure-composition isotherms. The electrodes were prepared by cold pressing of the copper-coated(25 wt%) alloy powders, and tested by a half cell. The results are summarized as follows. The cycle life was improved with the increase of Mo amount in $Zr_{1-x}Ti_xV_{0.4}Ni_{1.2}Mn_{0.4}Mo_y$(x=0.3, 0.4) and the activation was faster, whereas the discharge capacity decreased.

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Coordinated Voltage Control Scheme for Multi-Terminal Low-Voltage DC Distribution System

  • Trinh, Phi Hai;Chung, Il-Yop;Kim, Taehoon;Kim, Juyong
    • Journal of Electrical Engineering and Technology
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    • v.13 no.4
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    • pp.1459-1473
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    • 2018
  • This paper focuses on voltage control schemes for multi-terminal low-voltage direct current (LVDC) distribution systems. In a multi-terminal LVDC distribution system, there can be multiple AC/DC converters that connect the LVDC distribution system to the AC grids. This configuration can provide enhanced reliability, grid-supporting functionality, and higher efficiency. The main applications of multi-terminal LVDC distribution systems include flexible power exchange between multiple power grids and integration of distributed energy resources (DERs) using DC voltages such as photovoltaics (PVs) and battery energy storage systems (BESSs). In multi-terminal LVDC distribution systems, voltage regulation is one of the most important issues for maintaining the electric power balance between demand and supply and providing high power quality to end customers. This paper focuses on a voltage control method for multi-terminal LVDC distribution system that can efficiently coordinate multiple control units, such as AC/DC converters, PVs and BESSs. In this paper, a control hierarchy is defined for undervoltage (UV) and overvoltage (OV) problems in LVDC distribution systems based on the control priority between the control units. This paper also proposes methods to determine accurate control commands for AC/DC converters and DERs. By using the proposed method, we can effectively maintain the line voltages in multi-terminal LVDC distribution systems in the normal range. The performance of the proposed voltage control method is evaluated by case studies.

Influence of Heat Treatment on Separators for Lithium Secondary Batteries (리튬 이차전지용 분리막에 대한 열처리의 영향)

  • Lee, Sae-Me;Ryu, Sang-Woog
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.93-97
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    • 2012
  • Heat treatment effect of polyethylene (PE) separators was investigated after storage at 80, 100 and $120^{\circ}C$ for 1 h. All the samples showed enhanced tensile strength and modulus after heat treatment, but thermal shrinkage up to 15% was observed in PE films having newly formed dimple structure on the surface of fiber after annealed at 100 and $120^{\circ}C$. Although there was 5% of thermal shrinkage after annealing at $80^{\circ}C$, no such serious changes in PE fiber was observed. Furthermore, the separator was found to have enhanced cell performance with 1.3 and 2.3 times higher tensile strength and modulus after heat treatment at $80^{\circ}C$ for 1 h.