• Title/Summary/Keyword: Batch technique

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Immobilization of Penicillium citrinum by Entrapping Cells in Calcium Alginate for the Production of Neo-Fructooligosaccharides

  • Lim, Jung-Soo;Park, Seung-Won;Lee, Jin-Won;Oh, Kyeong-Keon;Kim, Seung-Wook
    • Journal of Microbiology and Biotechnology
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    • v.15 no.6
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    • pp.1317-1322
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    • 2005
  • This work describes neo-fructooligosaccharides (neo-FOSs) production using the immobilized mycelia of Penicillium citrinum. Some critical factors were evaluated to optimize maximal production of neo-FOS. Optimal alginate and cell concentrations were determined to be $1.96\%$ alginate and $7.17\%$ cell, respectively, by statistical analysis. The optimal concentration of $CaCl_{2}$, which is related to bead stability, was determined to be 2 M. It was possible to increase the neo-FOS production by adding 15 units of glucose oxidase to the batch reaction. By co-immobilizing cells and glucose oxidase, neoFOS productivity increased $123\%$ compared with the whole-cell immobilization process. Based on the results above, a co-immobilization technique was developed and it can be utilized for large-scale production.

Removal of Cd(II) and Cu(II) from Aqueous Solution by Agro Biomass: Equilibrium, Kinetic and Thermodynamic Studies

  • Reddy, Desireddy Harikishore Kumar;Lee, Seung-Mok;Seshaiah, Kalluru
    • Environmental Engineering Research
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    • v.17 no.3
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    • pp.125-132
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    • 2012
  • The removal of Cd(II) and Cu(II) from aqueous solution by an agricultural solid waste biomass prepared from Moringa oleifera bark (MOB) was investigated. The biosorbent was characterized by Fourier transform infrared spectroscopy and elemental analysis. Furthermore, the effect of initial pH, contact time, biosorbent dosage, initial metal ion concentration and temperature on the biosorption of Cd(II) and Cu(II) were studied using the batch sorption technique. Kinetic studies indicated that the biosorption process of the metal ions followed the pseudo-second order model. The biosorption data was analyzed by the Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin isotherm models. Based on the Langmuir isotherm, the maximum biosorption capacities for Cd(II) and Cu(II) onto MOB were 39.41 and 36.59 mg/g at 323 K, respectively. The thermodynamic parameters, Gibbs free energy (${\Delta}G^o$), enthalpy (${\Delta}H^o$), and entropy (${\Delta}S^o$) changes, were also calculated, and the values indicated that the biosorption process was endothermic, spontaneous and feasible in the temperature range of 303-323 K. It was concluded that MOB powder can be used as an effective, low cost, and environmentally friendly biosorbent for the removal of Cd(II) and Cu(II) ions from aqueous solution.

Environmental Assessment of Vitrified Mine Tailing Aggregate Using Various Leaching Methods (고농도 중금속 함유 광미를 이용한 유리화 처리 골재의 장기 용출특성에 따른 환경안전성 평가)

  • Lee, Sang-Woo;Chun, Sa-Ho;Lee, Ki-Kang;Lee, Sanghoon
    • Journal of Environmental Impact Assessment
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    • v.16 no.1
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    • pp.35-43
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    • 2007
  • Vitrified aggregates obtained by using mine tailings were evaluated using various leaching methods to assess their environmental safety. The leaching tests in this study include continuous batch leaching, Dutch availability leaching, pH-stat and tank diffusion test as well as TCLP (Toxicity Characteristic Leaching Procedure), which is commonly adopted. Vitrification technique has successfully been applied treating some solid wastes containing high level of heavy metals, such as EAF (Electric Arc Furnace) dust and mine tailings. The potentially most leachable element among trace metals was As and theoretically about 7% of total concentrations in the aggregate can be released under extreme condition. Zinc was leached about 4% and the other trace metals including Cd, Cr and Pb were hardly released from the vitrified mine tailing aggregate.

Growth of Optical Quality $Bi_{12}GeO_{20}$ Crystals and Preparation of SAW-Filter ($Bi_{12}GeO_{20}$단결정 육성 및 표면탄성파 소자 제조)

  • 이태근;정수진
    • Korean Journal of Crystallography
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    • v.2 no.2
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    • pp.32-40
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    • 1991
  • The effects of compositional variation, rotation speel and pulling rate on the growth of optical quality Bi120e02(1 crystals were examined. It was found to flatten the shape of crystal-melt interface for yowing a single crystals less than about 30mm in diameter at the rotation speed of 50rpm. Diameter of crystals with flat interface was increased as the pulling rate. The precipitation of Bi40e3012 phase set limits to pulling rate of BGO crystals. Precipitate-free BGO crystals were grown under pulling rate of 2mm l hr which released the stress resulted from too hi어 Pulling rate, and from 6. IBi203·GeO2 batch composition obtained by addition of 0.1 mole Bi203 into Bi-deficient melts to fill up the deficiency resulted from gradual volatilization of Bi2O). The pale-yellow colored crystals had good quality in that dislocation density was less than 103pits/cm, and it also exhibited transmittance of 70% and optical activity of 23°/mm. and SAW velosity was measured 1700m/sec on 111 cut 110 propagating BGO crystals. The SAW filter with electrode thickness of 9.8um was fabricated by using the electron beam and dry etching technique, it makes Bi12GeO20 devices intersting for color TV IF with half device size.

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An Assessment of the Feasibility of (I) : Condition of Aerobic (MTBE를 포함한 기타 가솔린 첨가제의 생 분해 적용 가능성 평가(I) : 호기성 조건)

  • Chung, Woo-jin;Chang, Soon-woong
    • Journal of Environmental Science International
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    • v.25 no.6
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    • pp.757-766
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    • 2016
  • MTBE and other gasoline additives contained in gasoline are known to be a refractory substance resistant to biodegradation. As a method of removing these substances, a research of method using native microbes of polluted soil was progressed and among these, bio-degradation possibility under aerobic condition was evaluated. All of the experiments were progressed based on batch experiment of lab scale and analyzed by GC-FID using HS-SPME technique. The result of bio-degradation experiment based on MTBE and other additives(ETBE, TAME) was observed below 1 mg/L, which initial concentration were 100 mg/L for each method. And through production of by-product and CO2, partial mineralization was confirmed. Degradation velocity of each additive was promptly represented in the order of TBA>ETBE>MTBE>TAME. Through this study, bio-degradation possibility of native microbes of oil polluted soil, MTBE and other gasoline additives was confirmed and it was considered that the result could be used for basic experiment data in removing oil pollutants of soil.

A Design of Filtering Technique on LBSNS using Spatial Join (LBSNS에서의 공간조인을 이용한 필터링 기법의 설계)

  • Lee, Eun-Sik;Cho, Dae-Soo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.05a
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    • pp.230-232
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    • 2011
  • Owing to the advent of digital devices which equipped with GPS, such as smartphone and tablet pc, a number of LBSNS applications have been released and even SNS applications serve various Location-Based Services. In twitter's case, the news of interesting area is provided to user not by being subscribed them automatically, but by being searched on web-site. This paper describes the system designed for users want to subscribe the local news without procedure like searching using operators. This system uses PBSM(Partition Based Spatial-Merge Join) which has no index for batch processing and against a massive query. The results from Spatial Join are stored in Materialized View then provided to user.

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Electrosorption and Separation of $Co^{2+}$ and $Sr^{2+}$ Ions from Decontaminated Liquid Wastes

  • Kim, Jun-Soo;Jung, Chong-Hun;Oh, Won-Zin;Ryu, Seung-Kon
    • Carbon letters
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    • v.3 no.1
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    • pp.6-12
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    • 2002
  • A study on the electrosorption of $Co^{2+}$ and $Sr^{2+}$ ions onto a porous activated carbon fiber (ACF) was performed to treat radioactive liquid wastes resulting from chemical or electrochemical decontamination and to regenerate the spent carbon electrode. The result of batch electrosorption experiments showed that applied negative potential increased adsorption kinetics and capacity in comparison with open-circuit potential (OCP) adsorption for $Co^{2+}$ and $Sr^{2+}$ ions. The adsorbed $Co^{2+}$ and $Sr^{2+}$ ions are released from the carbon fiber by applying a positive potential on the electrode, showing the reversibility of the sorption process. The possibility of application of the electrosorption technique to the separation of radionuclides was examined. The result of a selective removal experiments of a single component from a mixed solution showed that perfect separation of $Co^{2+}$ and $Sr^{2+}$ ions was possible by the electrosorption process.

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Removal of 2,4-Dinitrophenol from an Aqueous Solution by Wood-Based Activated Carbon (목질계 활성탄을 이용한 수중의 2,4-Dinitrophenol 흡착 제거)

  • Ju, Chang-Sik;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.26 no.5
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    • pp.609-619
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    • 2017
  • The removal characteristics of 2,4-dinitrophenol (2,4-DNP) from an aqueous solution by commercial Wood-based Activated Carbon (WAC) have been studied. The effects of various experimental parameters were investigated using a batch adsorption technique. The adsorption capacity of 2,4-DNP by WAC increased with a decrease in the dosage and particle size of WAC, temperature and the initial pH of the solution, and increased with an increase in the initial concentration of the solution. The adsorption equilibrium data were best described by the Redlich-Peterson isotherm model. The maximum adsorption capacities of 2,4-DNP by WAC were 573.07 mg/g at 293 K, 500.00 mg/g at 313 K, and 476.19 mg/g at 333 K, decreasing with increasing temperature. The kinetic data were well fitted to the pseudo-second-order model, and the results of the intra-particle diffusion model suggested that the adsorption process was mainly controlled by particle diffusion. The thermodynamic analysis indicated that the adsorption of 2,4-DNP by WAC was an endothermic and spontaneous process.

Photo Catalytic Activity of CNT-TiO2 Nano Composite in Degrading Anionic and Cationic Dyes

  • Kim, Sang-Jin;Im, Ji-Sun;Kang, Phil-Hyun;Kim, Tae-Jin;Lee, Young-Seak
    • Carbon letters
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    • v.9 no.4
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    • pp.294-297
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    • 2008
  • A CNT-$TiO_2$ nano composite was prepared from titanium chloride ($TiCl_4$) via sol-gel process using multi walled carbon nano tube (MWCNT) followed by calcination at $450^{\circ}C$. Spectral analysis revealed that the formed $TiO_2$ resided on the carbon in anatase form. The effect of adsorption was investigated using aqueous solution of methylene blue and procion blue dye. The photochemical reaction of CNT-$TiO_2$ composite in aqueous suspensions was studied under UV illumination in batch process. The reaction was investigated by monitoring the discoloration of the dyes employing UV-Visible spectro-photometeric technique as a function of irradiation time. The catalyst composites were found to be efficient for the photodegradation of the dye.

Adsorption Characteristics of Sr(II) and Cs(I) ions by Zeolite Synthesized from Coal Fly Ash (Coal Fly Ash로 합성한 제올라이트에 의한 Sr(II)과 Cs(I) 이온의 제거 특성)

  • Lee, Chang-Han;Park, Jeong-Min;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.23 no.12
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    • pp.1987-1998
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    • 2014
  • Zeolite was synthesized from power station waste, coal fly ash, as an alternative low-cost adsorbent and investigated for the removal of Sr(II) and Cs(I) ions from single- and binary metal aqueous solutions. In order to investigate the adsorption characteristics, the effects of various operating parameters such as initial concentration of metal ions, contact time, and pH of the solutions were studied in a batch adsorption technique. The Langmuir model better fitted the adsorption isotherm data than the Freundlich model. The pseudo second-order model was found more applicable to describe the kinetics of system. The adsorption capacities of Sr(II) and Cs(I) ions obtained from the Langmuir model were 1.7848 mmol/g and 0.7640 mmol/g, respectively. Although the adsorption capacities of individual Sr(II) and Cs(I) ions was less in the binary-system, the sum of the total adsorption capacity (2.3572 mmol/g) of both ions in the binary-system was higher than the adsorption capacity of individual ion in the single-system. Comparing the homogeneous film diffusion model with the homogeneous particle diffusion model, the adsorption was mainly controlled by the particle diffusion process.