• Title/Summary/Keyword: Basic catalyst

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Addition of α,α-Difluoroiodomethyl Ketones to Alkenes with a Copper Catalyst

  • Kwak, Kyung-Chell;Lee, Woo-Yiel;Zheshan, Quan;Lee, Young-Hang;Yun, Young-Gab;Kwak, Gyu-Beum;Chung, Hun-Taeg;Kwon, Tae-Oh;Chai, Kyu-Yun
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.97-102
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    • 2005
  • The addition reactions of $\alpha$,$\alpha$-difluoroiodomethyl n-butyl ketone, α,α-difluoroiodomethyl cyclohexyl ketone, or $\alpha$,$\alpha$-difluoroiodomethyl phenyl ketone to alkenes were successfully accomplished in good yields in the presence of copper powder. The reaction was also applicable to alkenes containing a variety of functional groups such as ester, trimethylsilyl, or ether group. Acetonitrile was determined to be the best solvent in the present study and the reaction was performed at 55 ${^{\circ}C}$ for 15-22 h. This reaction provides a new, efficient and general method for the synthesis of $\alpha$,$\alpha$-difluoro functionalized ketones.

Development of Monopropellant Thruster for Spacecraft Propulsion System (우주추진기관용 단일추진제 추력기 연구개발)

  • Kim, Su-Kyum;Won, Su-Hee
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.295-296
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    • 2012
  • In Korea, study of monopropellant thruster have been started from 1990s by KARI (Korea Aerospace Research Institute). 5N hydrazine thruster that is a first Koreanized hydrazine thruster, have been used as flight model for several satellite. In parallel, in order to retain core technology for monopropellant thruster, catalyst and test facility development have been carried out and successfully completed. On the basis of these technology, KARI is performing development of 1N/200N hydrazine thruster and basic research of green propellant thruster.

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Status and Strategy on Recycling of Domestic Used Chemical Catalysts (국내 사용 후 화학촉매제품의 재자원화 현황 및 향후 방향)

  • Kim, Young-Chun;Kang, Hong-Yoon
    • Resources Recycling
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    • v.26 no.3
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    • pp.3-16
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    • 2017
  • Chemical catalyst products are applied to various fields such as petrochemical process, air pollution prevention facility and automobile exhaust gas purifier. The domestic and overseas chemical catalyst market is increasing every year, and the amount of waste catalyst generated thereby is also increasing. Most of the used chemical catalyst products, such as desulfurized waste catalysts and automobile waste catalysts containing valuable metals are important recyclable resources from a substitute resource point of view. The recycling processes for recovering valuable metals have been commercialized through some urban mining companies, and SCR denitration catalysts have been recycled through some remanufacturing companies. In this paper, the amount of domestic production and recycling of major catalyst products have thus been investigated and analyzed so as to be used as basic data for establishing industrial support policy for recycling of used chemical catalyst products. Also tasks for promoting the recycling of used chemical catalyst products are suggested.

Research on Step-Type Chemical Liquid Deodorizer using Liquid Catalyst

  • WOO, Hyun-Jin;KWON, Lee-Seung;JUNG, Min-Jae;YEO, Og-Gyu;KIM, Young-Do;KWON, Woo-Taeg
    • The Korean Journal of Food & Health Convergence
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    • v.6 no.5
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    • pp.19-25
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    • 2020
  • The purpose of this study was to research and develop a step-type chemical liquid deodorizer including a liquid catalyst that can prevent civil complaints due to odor due to its excellent deodorizing performance. The main composition of chemical liquid deodorizer including liquid catalyst is cleaning deodorization, catalyst deodorization, chemical deodorization, water film plate, deodorization water circulation device, deodorization water injection device, catalyst management system, gas-liquid separation device, chemical supply device, deodorizer control panel, etc. It consists of a device. The air flow of the step-type liquid catalyst chemical liquid deodorizer is a technology that firstly removes basic odor substances, and the liquid catalyst installed in the subsequent process stably removes sulfur compounds, which are acidic odor substances, to discharge clean air. The efficiency of treating the complex odor of the prototype was 98.5% for the first and 99.6% for the second, achieving the target of 95%. The hydrogen sulfide treatment efficiency of the prototype was 100% for the first and 99.9% for the second, which achieved 95%, which was the target of the project. As a result, ammonia was removed by the reaction of ammonia and hydrogen sulfide.

A Study on the Efficiency of Dye Sensitized Solar Cell Employing TiO2 Photoelectrode Synthesized Using Basic Catalyst (염기성 촉매제를 이용한 염료감응 태양전지의 효율에 관한 연구)

  • Ki, Hyun-Chul;Jung, Haeng-Yun;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.10
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    • pp.736-740
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    • 2013
  • In this study, the influence of electrochemical properties by mixing Tetrabutylammonium hydroxide (TBAOH) and ammonium hydroxide (NH4OH) electrode on the dssc. The titanias were prepared using a sol-gel method by mixing Tetrabutylammonium hydroxide and Ammonium hydroxide. The $TiO_2$ nanopowder prepared by sol-gel methode, and to improve the distributed properties of $TiO_2$ nanopowder, the TBAOH and NH4OH was added. The I-V values of cells show that the Tetrabutylammonium has 6.51% efficiency.

Preparation of BaTiO3 Thick Film by an Interfacial Polymerization Method

  • Iwasaki, Mitsunobu;Park, Won-Kyu
    • Korean Journal of Materials Research
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    • v.17 no.10
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    • pp.548-554
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    • 2007
  • [ $BaTiO_3$ ] thick film by an interfacial polymerization method was prepared at the liquid/liquid interface between benzyl alcohol saturated solution with the basic catalyst [diethyl amine ($NHEt_2$) or triethylamine ($NEt_3$)], and the water dissolved with $TiO_2$ and $Ba(CH_3COO)_2$. The film thickness increased gradually with an increase in diethyl amine($NHEt_2$) or triethylamine($NEt_3$) volume and the reaction time. The homogeneity of $BaTiO_3$ thick film after sintered at $600^{\circ}C$ was confirmed by EPMA analysis, which showed that both of Ba and Ti element were homogeneously distributed on the surface as well as in the perpendicular direction of the film. The thickness of $BaTiO_3$ film obtained by this process was $8.75\;{\mu}m$.