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http://dx.doi.org/10.3740/MRSK.2007.17.10.548

Preparation of BaTiO3 Thick Film by an Interfacial Polymerization Method  

Iwasaki, Mitsunobu (Department of Applied Chemistry, School of Science & Engineering, Kinki University)
Park, Won-Kyu (Department of Material Engineering, Graduate School of Paichai University)
Publication Information
Korean Journal of Materials Research / v.17, no.10, 2007 , pp. 548-554 More about this Journal
Abstract
[ $BaTiO_3$ ] thick film by an interfacial polymerization method was prepared at the liquid/liquid interface between benzyl alcohol saturated solution with the basic catalyst [diethyl amine ($NHEt_2$) or triethylamine ($NEt_3$)], and the water dissolved with $TiO_2$ and $Ba(CH_3COO)_2$. The film thickness increased gradually with an increase in diethyl amine($NHEt_2$) or triethylamine($NEt_3$) volume and the reaction time. The homogeneity of $BaTiO_3$ thick film after sintered at $600^{\circ}C$ was confirmed by EPMA analysis, which showed that both of Ba and Ti element were homogeneously distributed on the surface as well as in the perpendicular direction of the film. The thickness of $BaTiO_3$ film obtained by this process was $8.75\;{\mu}m$.
Keywords
$BaTiO_3$ thick film; Polymerization method; Liquid/liquid interface; Basic catalyst;
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