• 제목/요약/키워드: Basic Metals

검색결과 274건 처리시간 0.026초

우리나라 성인의 체내 중금속 3종에 대한 노출수준과 주요 인구사회학적 영향요인에 관한 연구 - 제1~3기 국민환경보건 기초조사(2009-2017) 결과 - (A Study on Heavy Metals Exposure and Major Sociodemographic Influence Factors among Korean Adults - Korean National Environmental Health Survey (2009-2017) -)

  • 주영경;권영민;김성연;최경호;이철우;유승도;유지영
    • 한국환경보건학회지
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    • 제45권5호
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    • pp.541-555
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    • 2019
  • Objectives: The aim of this study is to examine heavy metal exposure levels in the blood and urine of a nationally representative adult population in Korea, and to identify the major influence factors for exposure through linkage analysis using questionnaire data. Methods: Biological samples and questionnaire data were collected from adults aged 18 and over who had participated in the Korean National Environmental Health Survey from 2009 to 2017. Lead, mercury, and cadmium exposure levels were presented with geometric mean and 95th percentiles. Multiple regression analysis was performed to determine the factors affecting heavy metal concentrations. Results: Blood lead levels increased slightly in Cycle 2 compared to Cycle 1, but decreased in Cycle 3. Blood and urinary mercury and urinary cadmium levels decreased over time. The main influence factors included gender, age, and smoking status for blood lead levels; gender, age, and intake of fish at least once a week for blood mercury levels; and age for urinary cadmium levels. Conclusion: The Korean National Environmental Health Survey is an effective tool for confirming over-time changes in exposure to lead, mercury, and cadmium in Korean adults and to identify its influence factors. The results of this study are expected to present basic data for calculating reference values and baseline exposure levels for environmental chemicals in Korean adults.

비산재가 포함된 폐광산 채움재의 위해성 평가 전략 (A Strategy for the Risk Assessment of Abandoned Mine Filler Materials)

  • 지상우;조환주;신희영;이상훈;안지환
    • 자원리싸이클링
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    • 제28권4호
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    • pp.59-64
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    • 2019
  • 본 연구에서는 국내 폐광산에 이용될 채움재의 위해성 평가작업을 위한 전략과 방법론을 개념적 측면에서 제시하였다. 채움재는 석탄발전소 비산재와 고형재로 구성되어 있으며 탄산염 등 위해도가 적은 물질이 대부분을 차지하지만 일부 중금속 성분이 포함되어 있어서 이에 대한 위해성 평가가 요구된다. 위해성 평가는 주로 인체내 발암 및 비발암성 유발 가능성을 정량화하는 것이 목적이며, 본 연구의 경우 국내/외 토양 및 광해 위해성평가 기법을 참조 할 수 있을 것으로 판단된다. 이 때 독성이나 분배계수 등 항목별 주요 은 인자 값은 국내 토양위해성평가 가이드라인에서 제시하는 수치를 주로 이용할 수 있다. 오염도에 대한 정확한 위해 성평가는 현장답사와 실측 등을 통한 노력과 시간이 요구된다. 또한 채움재내 중금속 성분 및 농도가 매우 다양하고 반응이 복잡하여 이를 전부 상세하게 평가한다는 것은 비효율적이다. 따라서, 효과적인 위해성 평가를 위하여 일단 문헌 자료와 채움재 시료특성분석결과를 이용한 예비위해성평가를 먼저 실시하고, 그 이후 상세 위해성 평가에서 예비위해성평가에서 선정된 유의 사항을 중점적으로 다뤄야 할 것으로 생각된다. 이를 위해서는 신뢰성 있는 시료분석기법과 노출경로 및 관련 메커니즘에 대한 충분한 이해가 선행되어야 한다.

CCM용융에 대한 유리용융 조건 연구 (The Study on the Power Consumption for Glass Melting by Cold Crucible Melter)

  • 진현주;이규호;장영재;배소영;김태호;정영준;김영석;이강택;류봉기
    • 대한금속재료학회지
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    • 제46권2호
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    • pp.65-68
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    • 2008
  • Generally CCM (cold crucible melting) is not suitable for melting glass. However, in this study we described the quantitative relationship between the basic property of glass and power balance, the power absorption in the melt, the losses in the coil and the cold crucible, for melting glass in CCM. The dependence of power balance on the applied frequency and the electric conductivity has been found. Above 300 kHz, the glass (B) contained alkali ion which has the low resistance $3.0{\Omega}{\cdot}cm$ at $900^{\circ}C$ and $1.36{\Omega}{\cdot}cm$ at $1,100^{\circ}C$ was melted easily and 60% of the overall power was absorbed in the melt and 30% and 10% of the overall power was lost in the cold crucible and coil respectively. Under the same condition, the glass (A) contained non-alkali ion was not melted easily and 50% of the overall power was absorbed in the melt and 40% and 10% of the overall power was lost in the cold crucible and coil respectively. In conclusion, the small absorbed power of the overall power in melt prevented a successful melting as for glass A, and the successful melting depends on the relative size of the absorbed power in melt irrespective of the melting volume. Hence, as typical for direct induction heating method(CCM), the successful melting strongly depended on the chosen working frequency based on electric conductivity of glass, power balance and the control of the critical power which was absorbed in melt.

Seawater ballast tank 환경에서 저합금강의 내식성에 미치는 합금원소의 영향 (Effects of Alloying Elements on Corrosion Resistance of Low Alloyed Steels in a Seawater Ballast Tank Environment)

  • 김동우;김희산
    • 대한금속재료학회지
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    • 제48권6호
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    • pp.523-532
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    • 2010
  • Co-application of organic coating and cathodic protection has not provided enough durability to low-alloyed steels inseawater ballast tank (SBT) environments. An attempt has made to study the effect of alloy elements (Al, Cr, Cu, Mo, Ni, Si, W) on general and localized corrosion resistance of steels as basic research to develop new low-allowed steels resistive to corrosion in SBT environments. For this study, we measured the corrosion rate by the weigh loss method after periodic immersion in synthetic seawater at $60^{\circ}C$, evaluated the localized corrosion resistance by an immersion test in concentrated chloride solution with the critical pH depending on the alloy element (Fe, Cr, Al, Ni), determined the permeability of chloride ion across the rust layer by measuring the membrane potential, and finally, we analyzed the rust layer by EPMA mapping and compared the result with the E-pH diagram calculated in the study. The immersion test of up to 55 days in the synthetic seawater showed that chromium, aluminium, and nickel are beneficial but the other elements are detrimental to corrosion resistance. Among the beneficial elements, chromium and aluminium effectively decreased the corrosion rate of the steels during the initial immersion, while nickel effectively decreased the corrosion rate in a longer than 30-day immersion. The low corrosion rate of Cr- or Al-alloyed steel in the initial period was due to the formation of $Cr_2FeO_4$ or $Al_2FeO_4$, respectively -the predicted oxide in the E-pH diagram- which is known as a more protective oxide than $Fe_3O_4$. The increased corrosion rate of Cr-alloyed steels with alonger than 30-day exposure was due to low localized corrosion resistance, which is explained bythe effect of the alloying element on a critical pH. In the meantime, the low corrosion rate of Ni-alloyed steel with a longer than 30-day exposure wasdue to an Ni enriched layer containing $Fe_2NiO_4$, the predicted oxide in the E-pH diagram. Finally, the measurement of the membrane potential depending on the alloying element showed that a lower permeability of chloride ion does not always result in higher corrosion resistance in seawater.

Determination of Heavy Metal Concentration in Herbal Medicines by GF-AAS and Automated Mercury Analyzer

  • Kim, Sang-A;Kim, Young-Jun
    • 한국식품위생안전성학회지
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    • 제36권4호
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    • pp.281-288
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    • 2021
  • GF-AAS와 수은분석기를 이용하여 납, 비소, 카드뮴 및 수은의 회수율로 정확도를 측정한 결과 92.67-102.56% 범위에서 측정되었고, 정밀도를 측정한 결과 0.21-6.00 RSD%의 재현성을 보였으며, CODEX guideline에서 규정하는 범위에 적합하였다. 또한, FAPAS QC material을 검증결과, 회수율은 96.7-102.0%, 재현성은 0.33-4.93 RSD%로 우수한 결과를 나타냈다. 한약재 430건의 평균 Pb 함량은 254.9 ㎍/kg(N.D.-2,515.2)이었고, 평균 As 함량은 171.0 ㎍/kg (N.D.-2,465.2)이었으며, 평균 Cd 함량은 99.2 ㎍/kg (N.D.-797.1), 평균 Hg 함량은 6.0 ㎍/kg (N.D.-83.6)이었다. 분석 결과 우리나라에 유통되는 한약재 20종은 식품의약품안전처에서 규정하는 한약재의 중금속 함량에 대한 허용기준 이내의 결과로 모두 안전한 수준의 한약재로 나타났다. 이를 토대로 한약 규격품 제조업소를 품질관리의 기준으로 하여 유통되기 직전의 가공 포장 과정에서의 한약재 중 납, 비소, 카드뮴 및 수은의 함량을 조사하여 한약재 내 중금속 함량 실태를 파악하고, 국민에게 안전하고 우수한 한약재를 공급하기 위한 기초자료로 활용할 수 있을 것으로 사료된다.

Dual Energy CT를 이용한 금속물질 인공물 감소방법 : Dual Energy와 MAR알고리즘의 임상적 응용 (A Study of the Metal Artifact Reduction using Dual Energy CT : Clinical Applications of Dual Energy and MAR Algorithm)

  • 박기석;최우전;김동현
    • 한국방사선학회논문지
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    • 제15권3호
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    • pp.273-279
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    • 2021
  • 전산화단층촬영 검사 시 인체 내에 삽입되어 있는 금속물질은 금속주위에 있는 인체조직이나 뼈와 큰 밀도차이가 있어 인공물을 발생시킨다. 이 실험을 통해 Single source Dual energy CT에서 Dual energy검사 및 MAR 알고리즘의 특성을 비교분석하여 임상적으로 적용방법에 대한 기초자료를 제시하려 한다. MAR 알고리즘을 적용하거나 Dual Energy를 이용하여 검사하였을 때 금속 인공물이 감소하였는데 MAR알고리즘을 적용한 영상은 세부적인 부분을 왜곡시키는 단점이 있다. Dual Energy로 검사한 영상은 MAR알고리즘을 적용한 영상보다 세부적인 부분까지 구현해 낼 수 있다는 장점이 있으나 재구성에 소요되는 시간이 길며 피폭선량이 MAR알고리즘을 적용한 영상보다 약 4배 가량 높았다. 수술 후 Follow up 및 금속물질의 위치를 파악하기 위해서는 MAR알고리즘을 적용하여 영상을 획득하는 것이 검사적 측면에서 유용하며 미세 병변 확인 및 수술계획을 세우거나 진단적인 측면에서 검사를 시행하였을 때는 Dual Energy로 검사하는 것이 더 유용하다.

돼지에서 생체 분해 금속성 전달체를 활용한 구제역 백신의 적용 연구 (Application of biodegradable metal based drug delivery carrier on Foot and Mouth Disease vaccination in pigs)

  • 조아라;오상익;최창용;정영훈;도윤정;김수희;추현욱;구종수;정우진;조성윤;류재규
    • 한국동물위생학회지
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    • 제43권3호
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    • pp.129-137
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    • 2020
  • In this study, we applied biodegradable drug delivery carries (BDDC) for food-and-mouth (FMD) vaccination. After FMD vaccination using BDDC, we estimated the percentage inhibition (PI) of antibody, decomposed patterns, and histopathologic features of BDDC. PI of antibody was higher than 50 at two weeks after injection and sustained positive PI until 10 weeks after injection. BBDC injection group showed significantly an increased pattern of blood monocyte at two and three weeks after injection. According to the Micro CT, micro-cracks were observed at two weeks after injection and the morphology of BDDC was lost at four weeks after injection. For histopathological examination, acute inflammation with neutrophil infiltration and micro-metallic residues were observed around BDDC until four weeks after injection and inflammatory responses gradually decreased at 10 weeks. Based on our experiment, BDDC is considered as an alternative way to vaccine injection for veterinary applications. Our study can be used as basic data for the drug delivery system using biodegradable metals in the future.

한국 가정용 가구디자인의 시대적 경향분석에 관한 연구 (80년대 이후 중심으로) (A Study on the Historical Trend Analysis of Korean Home Furniture Design (Focused on After 1980s))

  • 인미애
    • 한국가구학회지
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    • 제16권1호
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    • pp.53-69
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    • 2005
  • This research has a significant meaning to observe and understand the historical condition of a furniture industry and the characteristics of Korean home furniture's formation, ability, skill and materials from 1980s when there were an economic growth and a historical development of Korean home furniture occurred to present days. During 1980s, there was an automatic system available and has enforced and settled the standards on its quality and price in a furniture industry. Also, there was a big trend of black furniture as well as an entrance of corporation and high glossy furniture due to technical cooperation from Europe. In 1990s, there was an entrance of furniture which various techniques was applied due to a high development of the materials and skills, and also various sizes of height and weight and enlargement of acceptance function using highly-technological hardware. After 2000 and now, pro-environmental products is embossed in the Korean home furniture where they added a public issue which is the concept of well being, and A.I and sub material has been pro-environment. There also was a natural unity between nature and technology because of increased usage of trees with its natural patterns, metals, and glasses. For the future development of home furniture design, This problem should be promptly recognized that current home furniture designs are now on the verge of being lack of originality and are just following the market demand and recent trend as it is. Then, there should be a development of its specialized, detailed, unique design as well as a development of advanced materials, production management, distribution, and so on, and carrying out a diversified research continuously. There also should be a systematic education, which is necessary for training specialists to lead the Korean home furniture design industry as well as preparing a basic level for the future without a negligence.

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수소화물발생 유도결합플라즈마 원자방출분광법에 의한 머리카락 시료 중 미량의 Se와 Bi의 분석에 관한 연구 (A study on the Determination of Trace Se and Bi in the Scalp Hair by Hydride Generation- Inductively Coupled Plasma Atomic Emission Spectrometry)

  • 최범석;이동기
    • 분석과학
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    • 제9권1호
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    • pp.26-34
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    • 1996
  • 수소화물 발생장치를 사용한 유도결합플라즈마 원자방출분광법(ICP-AES)으로 머리카락 시료 중에 함유된 미량의 Se와 Bi의 분석에 관해 연구하였다. 기체상태의 수소화물 측정시 ICP의 최적 측정조건은 시료운반기체의 유속은 0.6~0.8L/min, 관측위치는 유도코일로부터 6mm 높이였다. 수소화물 생성효율이 최대를 나타내는 염산농도는 $NaBH_4$와 NaOH를 각각 2.5% 사용할 때 1.5M 이상일 때였으며, 2.5% $NaBH_4$와 0.1% $NaBH_4$를 사용할 때는 약 O.5M 이상일 때였다. 분석과정에서 Cu와 Ni 같은 전이금속으로부터의 심한 방해영향이 관찰되었고, lanthanum hydroxide로 Se와 Bi를 공침시켜 방해영향을 제거하였다.

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도시공원의 생태기능 향상을 위한 토양 이화학적 특성 기준에 대한 연구 (Study on Soil Physico-Chemical Properties Criteria for Improving Ecosystem Services in Urban Parks)

  • 공민재;권태근;김창현;김남춘;신유경;안난희;이상민;손진관
    • 한국환경과학회지
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    • 제29권4호
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    • pp.325-337
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    • 2020
  • The purpose of this study was to analyze the soil environment of urban neighborhood parks and to use them as basic data for evaluating the ecological functions of urban parks such as groundwater regeneration, flood control, microclimate regulation, adsorption and purification. The landscape design criteria were generally evaluated as advanced, and further monitoring and studies are needed to evaluate the various ecological functions. It is also necessary to improve the phosphoric acid and nitrogen contents, which tended to be low. In addition, continuous monitoring is needed to assess the proper soil environment according to the biological species, and to evaluate the ecological functions. The results of this study can be used to evaluate the groundwater recharge of urban parks. In particular, when the land of the neighboring park is used for various purposes, the level of access of the user may be increased. Therefore, factors that may adversely affect the user's health, such as heavy metals and organic matters, should be selected and selected as management criteria. In addition, follow-up studies considering fertilization standards suitable for trees and growth of introduced vegetation, etc. are needed urgently to improve the soil environment.