• Journal of the Korean Magnetics Society
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• v.9 no.4
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• pp.173-176
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• 1999

Errors of saturation magnetization and magnetocrystalline anisotropy constant determined by magnetization curve of magnetically aligned unixial power were analyzed. In case of alignment factor ${\Theta}_0=10{\circ}$, magnetic constant errors of $Nd_2Fe_{14}B$ were calculated to be error of $M_S{\risingdotseq}1{\%}\;and\;error\;of\;K_1{\risingdotseq}13\;{\%}$, respectively, and magnetic constant errors of Ba-ferrite were calculated to be error of $M_S{\risingdotseq}1{\%}\;and\;error\;of\;K_1{\risingdotseq}17\;{\%}$. In this method, $M_s$ was found to be determined with high accuracy. High alignment is desirable for high accuracy.

• Advances in nano research
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• v.1 no.4
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• pp.183-192
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• 2013

One-dimensional multiferroic nanostructured composites have drawn increasing interest as they show tremendous potential for multifunctional devices and applications. Herein, we report the synthesis, structural and dielectric characterization of barium titanate ($BaTiO_3$)-bismuth ferrite ($BiFeO_3$) composite fibers that were obtained using a novel sol-gel based electrospinning technique. The microstructure of the fibers was investigated using scanning electron microscopy and transmission electron microscopy. The fibers had an average diameter of 120 nm and were composed of nanoparticles. X-ray diffraction (XRD) study of the composite fibers demonstrated that the fibers are composed of perovskite cubic $BaTiO_3$-$BiFeO_3$ crystallites. The magnetic hysteresis loops of the resultant fibers demonstrated that the fibers were ferromagnetic with magnetic coercivity of 1500 Oe and saturation magnetization of 1.55 emu/g at room temperature (300 K). Additionally, the dielectric response of the composite fibers was characterized as a function of frequency. Their dielectric permittivity was found to be 140 and their dielectric loss was low in the frequency range from 1000 Hz to $10^7$ Hz.

• Journal of Powder Materials
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• v.16 no.6
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• pp.410-415
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• 2009

Hexagonal barium ferrite ($BaFe_{12}O_{19}$) nano-particles have been successfully synthesised using selfassembly method. Diethyleneamine (DEA) surfactant was used to fabricate the micelle structure of Ba-DEA complex under various DEA concentrations. $BaFe_{12}O_{19}$ powders were synthesized with addition Fe ions to Ba-DEA complex and then heat treated at temperature range of 800-1000${\circ}C$. The molar ratio of Ba/DEA and heat-treatment temperature significantly affected the magnetic properties and morphology of $BaFe_{12}O_{19}$ powders. $BaFe_{12}O_{19}$ powders synthesized with Ba/DEA molar ratio of 1 and heat-treated at 1000${\circ}C$ for 1 hour showed the coercive forces (iHc) of 4.84 kOe with average crystal size of about 200 nm.

• Journal of Korea Foundry Society
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• v.9 no.3
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• pp.221-227
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• 1989

The effect of sulfur content and inoculant on solidification microstructure and mechanical properties of gray cast iron have been investigated. The main results obtained are as follows, 1. In the FeSi3Ca1Ba inoculated irons, with the variation of sulfur content, low sulfur levels (${\sim}0.03%$) yield low chill depth, high tensile strength, good wear resistance and type A graphite with a pearlite matrix. High sulfur levels( >0.08%) provide high chill depth, low mechanical proper ties and type D graphite with small amount ferrite. 2. In case of inoculant variation with normal FeSi, FeSi3Ca1Ba, 30CaSi and uninoculation at 0.03%S level, lower chill depth and higher tensile strength was obtained in the order ; 30CaSi, FeSi3Ca1Ba normal FeSi, uninoculation.

• Proceedings of the KIEE Conference
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• 1993.07b
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• pp.1140-1142
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• 1993

It has been prepared by a coprecipitation method for Ferroxplana $Ni_2Y\;(Ba_2Ni_2Fe_{12}O_{22}$ magnetic particles, which is one of the Hexagonal ferrite. The coprecipitates were synthesized by adding aqueous solution of $BaCl_2{\cdot}2H_2O,\;NiCl_2{\cdot}6H_2O\;and\;FeCl_2{\cdot}4H_2O$ (of which the mole ratio is $Ba^{2+}:Ni^{2+}:Fe^{2+}$=1:1:6) to a mixture of NaOH and $Na_2CO_3$ solution. The shape of Ferroxplana $Ni_2Y$ magnetic particles obtained at the calcined temperature 1,100($^{\circ}C$) was hexagonal plate-like, average particle size was 2(${\mu}m$), and aspect ratio was more than 7.

• Journal of the Korean Magnetics Society
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• v.22 no.1
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• pp.19-22
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• 2012

$Ba_2Mg_{0.5}Co_{1.5}(Fe_{0.99}In_{0.01})_{12}O_{22}$ was prepared by the conventional solid-state reaction method, and studied by x-ray diffractometer, vibrating sample magnetometer, and Mossbauer spectrometer. The crystal structure was determined to be a single-phased rhombohedral with space group R-3m. Magnetization value were $M_s$ = 28.6 emu/g at 295 K. The hysteresis loops indicate that all the samples are ferrimagnetic behaviors. Mossbauer spectra of $Ba_2Mg_{0.5}Co_{1.5}(Fe_{0.99}In_{0.01})_{12}O_{22}$ have been 6-sextet taken at various temperatures ranging from 4.2 to 620 K. Based on the isomer shift (${\delta}$) values of all samples, the charge states were found to be $Fe^{3+}$ state at all temperatures, the Curie temperature was determined to be 630 K by the ZVC curve.

• Journal of the Korean Ceramic Society
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• v.29 no.3
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• pp.195-201
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• 1992

It had been studied the structure and the magnetic properties of singel phase Co2Y(Ba2Co2Fe12O22) powder, one of the hexagonal ferrite. The material was successfully prepared by a commercially applicable coprecipitation method. Adding asqueous solution of BaCl2, CoCl2 and FeCl2(Ba2+:Co2+:Fe2+=1:1:6 in mole ratio) to a mixture of NaOH and hydrogen peroxide solution, coprecipitate was formed with rapid oxidation of ferrous to ferric ion. The coprecipitate transformed to single phase Co2Y powder at heat treatment temperatures as low as 900$^{\circ}C$. The shape of Co2Y particles obtained at 900$^{\circ}C$ was hexagonal plate-like (diameter∼$\mu\textrm{m}$, aspect ratio>10). The structure of the Co2Y was refined by a Rietveld analysis of the measured X-ray diffractogram. The lattice parameters are ao=5.8602${\AA}$ and co=43.512${\AA}$. Co2Y is a soft magnetic material with saturation magnetization 30 emu/g and coecivity 170 . A standard X-ray diffraction pattern for Co2Y is proposed as well.

• Journal of Magnetics
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• v.17 no.1
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• pp.1-5
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• 2012

The coercivity of a single 27 nm-spherical barium ferrite (S-BaFe) particle was simulated using three models: 1) Gibbs free energy (GFE), 2) Landau-Lifshitz-Gilbert (LLG), and 3) Stoner-Wohlfarth (S-W). Spherically and hexagonally shaped particles were used in the GFE and LLG simulations to investigate coercivity with the different shape anisotropies. The effect of shape was not included in the S-W model. It was found that the models using a spherical shape resulted in a coercivity higher than the models using the hexagonal shape with both shapes having the same diameter. The coercivity estimated with the S-W model was approximately the same as that for the spherical-shape models, which indicates that spherical shape has no significant effect on the particle's coercivity at nanoscale.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.34 no.5
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• pp.386-392
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• 2021

Multiferroics exhibiting the coexistence and a possible coupling of ferromagnetic and ferroelectric order are attracting widespread interest in terms of academic interests and possible applications. However, room-temperature single-phase multiferroics with soft ferromagnetic and displacive ferroelectric properties are still rare owing to the contradiction in the origin of ferromagnetism and ferroelectricity. In this study, we demonstrated that sizable ferromagnetic properties are induced in the ferroelectric bismuth ferrite-barium titanate system simply by introducing Co ions into the A-site. It is noted that all modified compositions exhibit well-saturated magnetic hysteresis loops at room temperature. Especially, 70Bi_0.95Co_0.05FeO₃-30Ba_0.95Co_0.05TiO₃ manifests noticeable ferroelectric and ferromagnetic properties; the spontaneous polarization and the saturation magnetization are 42 µC/cm² and 3.6 emu/g, respectively. We expect that our methodology will be widely used in the development of perovskite-structured multiferroic oxides.

• Korean Journal of Materials Research
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• v.7 no.6
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• pp.536-544
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• 1997

본연구는 45 BaO-20B$_{2}$O$_{3}$-35Fe$_{2}$o$_{3}$(wt%)의 조성의 유리에 핵형성제로서 TiO$_{2}$또는 ZrO$_{2}$를 첨가한 조성에서는 barium ferrite(BaFe$_{12}$O$_{19}$)가 결정화되었다. TiO$_{2}$를 9wt%첨가한 조성에 대하여 활성화에너지와 진동수는 각각 235.45kJ/mol, 진동수 6.89x$10^{17}$S$^{-1}$이었으며, Avrami지수는 1$\leq$n $\leq$로서 일방향의 결정성장으로 나타났다. 또한, ZrO$_{2}$9wt% 첨가 조성에서는, 활성화에너지와 진동수는 각각 173.86kJ/mol, 2.65x$10^{14}$S$^{-1}$이었으며, Avrami지수는 2$\leq$n$\leq$3로서 이방향의 결정성장을 나타내었다.내었다.