• Title/Summary/Keyword: BOD/COD removal

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Removal Characteristics of Nitrogen and Phosphorus in swine wastewater by Using Acetic acid on the SBR Process (SBR에서 아세트산을 이용한 양돈폐수의 질소·인 제거 특성)

  • Huh, Mock;Kang, Jin-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.1
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    • pp.84-93
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    • 2004
  • This study was performed : 1) to find the suitable HRT(hydralic retention time), 2) to evaluate the effects of the ratio of mixing/aeration time and injection time of external carbon source, for the removal of organics, nitrogen and phosphorus in swine wastewater by SBR(sequencing batch reactor process), which is one of the biological treatment process. The result of this study were summarized as follows : (1) As the ratio of mixing/aeration time was higher, $NH_4{^+}-N$ removal efficiency was increased and it was increased with increasing injection time of external carbon source because nitrification was affected by denitrification microbes propagation when injection time of external carbon soruce was shorted. T-N removal efficiency was increased with increasing the ratio of mixing/aeration time and injection time of external carbon source. (2) The T-P removal efficiency showed a great difference in each operating condition, and it was increased with increasing the ratio of mixing/aeration time increased and when the injection time of external carbon source was shorted because denitrification was done with effect by denitrification microbes propagation. (3) The highest removal efficiency of organic and nitrogen were obtained by the operating condition of Run 4-1(the ratio of mixing/aeration time : 16.5/5.5, injection time of external carbon source : 15hours) and T-P were obtained by the operation condition of Run 4-2(the ratio of mixing/aeration time : 16.5/5.5, injection time of external carbon source : 3hours), and efficiency(effluent concentration)of $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, T-N and T-P in the treated water was 96.1%, 87.7%, 90.6%, 86.6% and 84.5%, respectively.

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Treatment of Pharmaceutical Wastewaters by Hydrogen Peroxide and Zerovalent Iron

  • Jeon, Byeong-Cheol;Nam, Se-Yong;Kim, Young-Kwon
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.9-14
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    • 2014
  • Fenton reaction with zerovalent iron (ZVI) and $Fe^{2+}$ ions was studied to treat pharmaceutical wastewaters (PhWW) including antibiotics and non-biodegradable organics. Incremental biodegradability was assessed by monitoring biochemical oxygen demand (BOD) changes during Fenton reaction. Original undiluted wastewater samples were used as collected from the pharmaceutical factory. Experiments were carried out to obtain optimal conditions for Fenton reaction under different $H_2O_2$ and ion salts (ZVI and $Fe^{2+}$) concentrations. The optimal ratio and dosage of $H_2O_2$/ZVI were 5 and 25/5 g/L (mass basis), respectively. Also, the optimal ratio and dosage of $H_2O_2/Fe^{2+}$ ions were 5 and 35/7 g/L (mass basis), respectively. Under optimized conditions, the chemical oxygen demand (COD) removal efficiency by ZVI was 23% better than the treatment with $Fe^{2+}$ ion. The reaction time was 45 min for ZVI and shorter than 60 min for $Fe^{2+}$ ion. The COD and total organic carbon (TOC) were decreased, but BOD was increased under the optimal conditions of $H_2O_2$/ZVI = 25/5 g/L, because organic compounds were converted into biodegradable intermediates in the early steps of the reaction. The BOD/TOC ratio was increased, but reverse-wise, the COD/TOC was decreased because of generated intermediates. The biodegradability was increased about 9.8 times (BOD/TOC basis), after treatment with ZVI. The combination of chemical and biological processes seems an interesting combination for treating PhWW.

Evaluation of Treatment Efficiencies of Water Quality for 5 years in Constructed Wetland to Upper Region of Water Source (상수원 상류지역 인공습지의 5년간 수질 정화효율 평가)

  • Park, Jong Seok;Kim, Kang Seok;Kim, Yong Chan;Rhee, Kyoung Hoon
    • Journal of Wetlands Research
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    • v.14 no.4
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    • pp.479-488
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    • 2012
  • This study evaluates treatment efficiencies of pollutants in Boknae bio-park constructed wetlands surrounding Juam Lake for 5 years from January 2006 to December 2010, in order to treat non-point pollutants effectively. The analysis of monthly treatment efficiency of pollutants shows that the scope of BOD is -19.11~37.72%, and of COD is 30.14~27.38%, thus the monthly deviation COD is relatively higher than BOD, and the scope of SS is -54.07~64.82%. Moreover, the analysis of seasonal treatment efficiency of pollutants shows that the treatment efficiency of TN is higher than 36.8% on average for 5 years in the spring and winter, and of TP relatively lower than other pollutants, however, the seasons don't make much difference to the treatment efficiency of TP.

Evaluation of the Water Purification Efficiency of Waste LCD Glass Media by Using Foaming Technology (발포기술을 이용한 폐 LCD유리 여재의 수질정화능력 평가)

  • Ahn, Tae-Woong;Choi, I-Song;Oh, Jong-Min
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.4
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    • pp.369-376
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    • 2010
  • The purpose of this study is to reprocess Waste-LCD(Liquid Crystal Display), to widely increase specific surface-area by foaming agent in the process of reprocessing and to use as a substrate of water treatment which is increased the ability of biological treatment, as well as to control non-point source pollutants produced by surface run off during rainfall with using this substrate, and to improve water quality of public watershed as developing substrate for water treatment to be able to purify second treated water which is exhausted at the wastewater treatment plant. The average removal efficiency of Waste-LCD that using the foaming technology was SS 71.2%, BOD 55.7%, COD 58.4%, T-N 29.5% and T-P was 50.3%. Almost Media, early stage showed low removal efficiency of SS and BOD. However, it became high when the microorganism adhered the Media. The variation of SS removal efficiency was high by inflow concentration of SS. The reason for the Media 4 showed high SS removal efficiency is that it has wide specific surface-area, and also it has a pore. All in all, it shows floating matter treatment ability not only inside but it also works outside of the substrate.

Natural Treatment of Wastewater from Industrial Complex in Rural Area by Subsurface Flow Wetland System (인공습지에 의한 농공단지 폐수처리)

  • Yoon, Chun-Gyeong;Lim, Yoong-Ho;Kim, Hyung-Joong
    • Korean Journal of Environmental Agriculture
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    • v.16 no.2
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    • pp.170-174
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    • 1997
  • Constructed wetland system was studied to treat wastewater from industrial complex in rural area. Pilot plant at the Baeksuk Nongkong Danzi in Chunahn-City was used for field study. For the DO, the effluent concentration was higher than the influent concentration and it implies that natural reaeration supplies enough oxygen to the system. For the SS, the effluent concentration was consistently lower than the water quality standard even though the influent concentration varied significantly, which showed that SS was removed by the system effectively which is consist of soil and plants. For the BOD and COD, the average removal rate of them were 56% and 43%, respectively, therefore, the effluent concentration could not meet water quality standards when influent concentration was high. The removal rate of BOD and COD can be improved by supplemental treatment in addition to this system if necessary. For the T-N and T-P, the influent concentration of them were lower than the water quality standards than no further treatment was needed. Overall, the result showed that constructed wetland system is a feasible alternative for the treatment of wastewater from industrial complex in rural area. For actual application of this system, further study on design factors including loading rate, removal mechanism, and temperature effects is required to meet water quality standard consistently. Compared to existing systems, this system is quite competitive because it requires low capital cost, almost no energy and maintenance, and therefore, very cost effective.

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The wastewater treatment system with high performance based on electrochemical interface reaction using dimensionally stable anode with simple manufacturing (전기화학 계면반응에 기초한 DSA 전극을 사용한 고성능 폐수처리 시스템)

  • Na, Young Soo;Lee, Man Sung;Kim, Kyoungho
    • Journal of Adhesion and Interface
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    • v.19 no.3
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    • pp.101-105
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    • 2018
  • With the rapidly growing of the population and industrization of cities, the clean and affordable water resources have gained immense interest because of remaining about 780 million people still lack access to it. However, present wastewater treatment systems have been faced with various issues, such as low processing efficiency, high operational costs and the requirement of a large area for manufacturing. It is therefore urgently required to develop an inexpensive and efficient wastewater treatment system. As the one of these efforts, we suggested and successfully demonstrated the wastewater treatment system using and electrochemical method via a dimensionally stable anode (DSA) based on rutile type $RuO_2$. Our system achieved biochemical oxygen demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC) removal efficiently at the respective rates of 52.0%, 77.8%, and 65.6% from household wastewater. In addition, we were able to remove BOD, COD, total nitrogen (TN), and total phosphorus (TP) from animal husbandry wastewater at rates of 92.9%, 75.6%, 35.1%, and 100%, respectively, thereby achieving dramatic reductions. Considering the excellent removal efficiency and the small size of this device, electrochemical wastewater treatment using a DSA coated in rutile $RuO_2$ presents a promising option for the treatment of both household and animal husbandry wastewater.

A study on the Treatment of Slaughterhouse Wastewater using Curtain Biological Film Contact Process. (커어튼형 생물막 접촉공법에 의한 도축장 폐수 처리에 관한 연구)

  • 이태호;은종극
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.14-19
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    • 2000
  • This study was carried out to get efficient of nutrient removal and wastage sludge production minimized effects on the treatment of slaughterhouse wastewater using aerobic curtain biological film contact process. As a results of biofilm attachment experiment aggravation of water quality due to excessive biofilm showed after every 15 days of operating times. The concentration of BOD and COD in the influent were 2500~3000mg/L and 1700~2100mg/L , respectively. The average BOD and CoD were 9mg/L and 17mg/L , respectively. The result of this experiment was wastage sludge did not almost generated and the removal efficiency of nutrients were kept equilibrium.

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Water Quality Improvement of Stagnant Water using an Upflow Activated Carbon Biofilm Process and Microbial Community Analysis (상향류 활성탄 생물막 공정을 이용한 정체 수역 수질 개선 및 공정 내 미생물 군집 해석)

  • Oh, Yu-Mi;Lee, Jae-Ho;Park, Jeung-Jin;Choi, Gi-Choong;Park, Tae-Joo;Lee, Tae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.1
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    • pp.23-32
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    • 2010
  • The capacity of natural purification was limited by the interruption of natural flow and the problems such as eutrophication were occurred by nutritive salts accumulation in stagnant stream. Moreover, the inflow of non-point sources causes non-degradable materials to increase in stagnant stream. In this study, an upflow biological activated carbon (BAC) biofilm process comprised of anoxic, aerobic 1, and aerobic 2 reactors were introduced for treatment of stagnant stream and SS, $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, TN, and TP were monitored in the upflow BAC biofilm reactors with continuous cycling. In order to simulate stagnant stream, the lake water of amusement park and golf course were stored as influent in a tank of $2m^3$ and hydraulic retention time (HRT) was changed into 6, 4, and 2 hours. At HRT 4hr and the lake water of amusement park as influent, the removal efficiencies of SS, $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, TN, and TP showed the best water quality improvement and were 69.8, 83.0, 91.3, 74.1, 74.7, and 88.9%, respectively. At HRT 4hr and the lake water of golf course as influent, the removal efficiencies of SS, $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, TN and TP were 78.5, 78.0, 80.2, 74.9, 55.6 and 97.5%, respectively. As the results of polymerase chain reaction - denaturing gel gradient electrophoresis (PCR-DGGE), microbial community was different depending on influent type. Fluorescence in situ hybridization (FISH) showed that nitrifying bacteria was dominant at HRT 4 hr. The biomass amount and microbial activities by INT-DHA test were not decrease even at lower HRT condition. In this study, the upflow BAC biofilm process would be considered to the water quality improvement of stagnant stream.

A study on enhancement of nitrogen removal efficiency on low concentration influent sewage (단계유입과 내부순환을 이용한 저농도 하수의 질소처리효율 향상을 위한 연구)

  • Choo, Tai-Ho;Kim, Tae-Ki;Ok, Chi-Youl
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.675-680
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    • 2010
  • This study was investigated to complement nitrogen removal of low concentration influent municipal sewage. The following are the results of the effect of Internal Recircularion and Step Feed rates on Treatment efficiency at a BOD low concentration influent municipal sewage. Up to 90.0% of BOD, 87.8% of COD, 71.0% of T-N, 75.3% of T-P were removed on average at a low concentration influent. Whereas BOD and T-P were removed without any relations to Step Feed rates, T-N was influenced. Nitrogen removal efficiencies in 80% of Step Feed rates was 65%, which was caused by the lack of Carbon Source for denitrification. Nitrogen removal efficiency in 40% of Step Feed rates was 58%, which means it was not removed but dischared. Consequently, the efficiency was 73%, 80%, and 78% in 70%, 60% and 50% of Step Feed rates, which was concluded as the best range of Step Feed rates. Nitrogen removal efficiency increased under the condition of Internal Recircularion. At over 150% of Internal Recircularion rate, the efficiencies were not affected any more. It is believed that lots of Recircularion caused inflow of DO to anoxic tank. Therefore, the most appropriate Internal Recircularion rate can be concluded as 50~150%.

A Study on Performance Evaluation for the Bio-retention Non-point Source Pollution Treatment System (생물 저류 방법 적용을 통한 비점오염원 처리시설의 성능평가에 관한 연구)

  • Lee, Jang-Soo;Park, Yeon-Soo;Cho, Wook-Sang
    • Clean Technology
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    • v.19 no.3
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    • pp.295-299
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    • 2013
  • This study was purposed and performed to evaluate removal efficiency of non-point source pollution in the process and system based on bio-retention design criteria regulated by EPA. Basic Column Reactors (BCR) were prepared for optimal determinations of inflow rate of first rainfall runoff and composition and ratio of soil layers. Removal efficiencies of non-point source pollution from synthetic runoff and real first rainfall runoff, directly sampled from motor way and parking lot, were analyzed, respectively. Removal efficiency of SS, BOD, COD, T-N, and T-P were all shown to be more than 80%.