• Journal of Environmental Health Sciences
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• v.28 no.1
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• pp.51-65
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• 2002

This study was carried out to apply some basic physical and chemical treatment options including Fenton's oxidation, and to evaluate the performances and the characteristics of organic and nitrogen removal using lab-scale biological treatment system such as complete-mixing activated sludge and sequencing batch reactor(SBR) processes for the treatment of leachate from a municipal waste landfill in Gyeongnam province. The results were as follows: Chemical coagulation experiments using aluminium sulfate, ferrous sulfate and ferric chloride resulted in leachate CO $D_{Cr}$ removal of 32%, 23% and 21 % with optimum reaction dose ranges of 10,000～15,000 mg/$\ell$, 1,000 mg/$\ell$ and 500～2,000 mg/$\ell$, respectively. Fenton's oxidation required the optimum conditions including pH 3.5, 6 hours of reaction time, and hydrogen peroxide and ferrous sulfate concentrations of 2,000 ～ 3,000 mg/$\ell$ each with 1:1 weight ratio to remove more than 50% of COD in the leachate containing CO $D_{Cr}$ between 2,000 ～ 3,000 mg/$\ell$. Air-stripping achieved to remove more than 97% of N $H_3$-N in the leachate in spite of requiring high cost of chemicals and extensive stripping time, and, however, zeolite treatment removing 94% of N $H_3$-N showed high selectivity to N $H^{+}$ ion and much faster removal rate than air-stripping. The result from lab-scale experiment using a complete-mixing activated sludge process showed that biological treatability tended to increase more or less as HRT increased or F/M ratio decreased, and, however, COD removal efficiency was very poor by showing only 36% at HRT of 29 days. While COD removal was achieved more during Fenton's oxidation as compared to alum treatment for the landfill leachate, the ratio of BOD/COD after Fenton's oxidation considerably increased, and the consecutive activated sludge process significantly reduced organic strength to remove 50% of CO $D_{Cr}$ and 95% of BO $D_{5}$ . The SBR process was generally more capable of removing organics and nitrogen in the leachate than complete-mixing activated sludge process to achieve 74% removal of influent CO $D_{Cr}$ , 98% of BO $D_{5}$ and especially 99% of N $H_3$-N. However, organic removal rates of the SBR processes pre-treated with air-stripping and with zeolite were not much different with those without pre-treatment, and the SBR process treated with powdered activated carbon showed a little higher rate of CO $D_{Cr}$ removal than the process without any treatment. In conclusion, the biological treatment process using SBR proved to be the most applicable for the treatment of organic contents and nitrogen simultaneously and effectively in the landfill leachate.e.

• Journal of Wetlands Research
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• v.17 no.4
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• pp.348-358
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• 2015

Impacts of climate change are being observed in the globe as well as the Korean peninsula. In the past 100 years, the average temperature of the earth rose about 0.75 degree in celsius, while that of Korean peninsula rose about 1.5 degree in celsius. The fifth Assessment Report of IPCC(Intergovermental Panel on Climate Change) predicts that the water pollution will be aggravated by change of hydrologic extremes such as floods and droughts and increase of water temperature (KMA and MOLIT, 2009). In this study, future runoff was calculated by applying climate change scenario to analyze the future water quality for each targe period (Obs : 2001 ~ 2010, Target I : 2011 ~ 2040, Target II : 2041 ~ 2070, Target III : 2071 ~ 2100) in Hongcheon river basin, Korea. In addition, The future water quality was analyzed by using multiple linear regression analysis and artificial neural networks after flow-duration curve analysis. As the results of future water quality prediction in Hongcheon river basin, we have known that BOD, COD and SS will be increased at the end of 21 century. Therefore, we need consider long-term water and water quality management planning and monitoring for the improvement of water quality in the future. For the prediction of more reliable future water quality, we may need consider various social factors with climate components.

• Korean Journal of Ecology and Environment
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• v.40 no.3
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• pp.468-480
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• 2007

The urbanization is altering the hydrology, water quality, channel form of waterway and changing the composition of biological communities in the aquatic ecosystem. Recently, towns grew bigger by the drift of large numbers of people and the medium and small leather and dyeing industries around the Pocheon and Youngpyeong streams. The discharges of sewage were increased by them. The UII (urban intensity index) was 85 (st. P-3) and 91 (st. P-6) in the Pocheon stream and about 20 in the Youngpyeong stream. A total 141 taxa of epilithic diatoms which were composed of 2 order, 8 family, 30 genera. Dominant species were Navicula saprophila, N. subminuscula, Nitzschia palea, Gomphonema pseudoaugur in the Pocheon stream and Achnanthes alteragracillima, A. convergens, A. minutissima, N. minima, N. fonticola, N. frustulum and Cymbella minuta var. silesiaca in the Youngpyeong stream. It Showed the different composition of dominant species by the urbanization near two streams. In the relationships between UII and environmental factors such as EC, BOD, COD, TN, TP and DAIpo, UII showed the high relations $(r^2>0.8)$. It was the difference of organic pollution according to urbanization. It therefore, was higher the relative abundance and more the numbers of saprophilous taxa in the Pocheon stream than the Youngpyeong stream. The water quality of two streams by biological indicators(DAIpo) was polysaprobic state(st. P-3, P-4, P-5) in the Pocheon stream and was oligosaprobic (Y-1), mesosaprobic (Y-2, 3) and polysaprobic state (Y-4) in the Youngpyeong stream during the investigation periods.

• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.563-573
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• 2022

This work aimed to develop a new equation for turbidity (Turb) simulation and prediction using statistical methods based on principal component analysis (PCA) and multiple linear regression (MLR). For this purpose, water samples were collected monthly over a five year period from Cheurfa dam, an important reservoir in Northwestern Algeria, and analyzed for 12 parameters, including temperature (T°), pH, electrical conductivity (EC), turbidity (Turb), dissolved oxygen (DO), ammonium (NH₄⁺), nitrate (NO₃^-), nitrite (NO₂^-), phosphate (PO₄^3-), total suspended solids (TSS), biochemical oxygen demand (BOD₅) and chemical oxygen demand (COD). The results revealed a strong mineralization of the water and low dissolved oxygen (DO) content during the summer period. High levels of TSS and Turb were recorded during rainy periods. In addition, water was charged with phosphate (PO₄^3-) in the whole period of study. The PCA results revealed ten factors, three of which were significant (eigenvalues >1) and explained 75.5% of the total variance. The F1 and F2 factors explained 36.5% and 26.7% of the total variance, respectively and indicated anthropogenic pollution of domestic agricultural and industrial origin. The MLR turbidity simulation model exhibited a high coefficient of determination (R² = 92.20%), indicating that 92.20% of the data variability can be explained by the model. TSS, DO, EC, NO₃^-, NO₂^-, and COD were the most significant contributing parameters (p values << 0.05) in turbidity prediction. The present study can help with decision-making on the management and monitoring of the water quality of the dam, which is the primary source of drinking water in this region.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.453-453
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• 2021

도시지역 비점오염원관리, 물순환 회복, 침투 및 증발산량 증가, 열섬현상 저감을 위한 주요한 방안으로 저영향개발(low impact development, LID)과 그린인프라 기법의 적용되고 있다. LID 시설은 소규모 분산형 시설로써 넓은 지역에 많고 다양한 시설들이 적용되어 시설의 개수가 많으며, 수질 및 토양 내 기성제품에 대한 센서들의 가격은 고가로 형성되어 있어 기기의 경제성 및 유지관리 등 적용하는데 제한적이다. 따라서 과거 모니터링 자료를 기반으로 오염물질들과의 상관성 분석을 통하여 계측이 어려운 항목들을 계측가능한 항목들로부터 예측 가능하며, 선정된 항목들에 대한 비용효율적인 센서를 개발하여 실시간 LID 모니터링이 가능한 비용효율적 모니터링을 개발하였다. 공주대학교 천안캠퍼스의 LID 시설들은 2013년에 조성되어 현재까지 시설이 운영되고 있으며, 5년이상의 과거 강우시 모니터링 자료들을 이용하여 오염물질 상관성 분석을 수행가능 하기에 대상지로 선정하였다. 오염물질 상관성 분석은 2013년부터 2017년도에 침투도랑에서 수행된 강우시 모니터링 자료를 활용하여 각 오염물질들의 상관성을 분석을 수행하였다. 침투도랑 내 유입되는 평균 유입수는 TSS 286.1±318.3 mg/L, BOD 22.6±39.5 mg/L, TN 8.96±5.85 mg/L, TP 1.01±1.11 mg/L로 나타났다. 겨울철에 비해 여름철에서의 오염물질의 유입농도가 높은 것으로 분석되었다. 이는 여름철 고온건조로 인한 노면 내 차량의 주행으로 인한 중금속, 폐타이어 등과 장마철 강우 시 유출된 토사로 인하여 유입수의 농도가 높은 것으로 분석되었다. 오염물질 부하량은 TSS와 COD 0.66으로 유의성이 높은 것으로 나왔으며, COD와 TSS, TP, TN 등 유의성이 높은 것으로 분석되었다. Arduino와 Raspberry PI를 활용하여 저비용 센서와 LTE 모뎀통신과 데이터 베이스 연결하여 개발된 프로그램을 통해서 무선으로 LID 시설에 대한 모니터링을 침투화분2와 식생체류지에 조성하였다. 전력공급이 어려운 식생체류지의 경우 태양열(Solar system) 시스템과 보조 전력 배터리를 조성하여 장마철이나 장기적인 악천후로 인한 전력을 생산하지 못할 경우 보조전력배터리에서 전력을 제공하여 지속적인 모니터링이 이루어지도록 설계하였다. 토양함수량, 토양온도와 Conductivity 등 3종류의 센서를 적용하였으며, 프로그램은 현재 2단계를 통한 2차수정을 통하여 프로그램을 구축하였다. 오차, 오작동, 계측값에 대한 검·보정 작업이 필요하다. 또한 대기자료의 구축을 통해 보다 토양과 LID 시설에 대한 영향분석이 필요한 것으로 사료된다.

• Korean Journal of Environmental Biology
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• v.28 no.2
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• pp.69-78
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• 2010

The distributions of planktonic and periphytic algae were studied from April 2003 to February 2004 at Gwangju Stream. A total of 274 species, belongs to 8 classes, 19 orders, 6 suborders, 35 families, 4 subfamilies, 79 genera, was identified as algal flora of Gwangju Stream. The most diverse phytoplankton flora was observed at Bangrim bridge and Yangdong market sites with 137 species, and followed by Yuchon bridge site (118 species). The richness of phytoplankton fluctuated throughout the studied period from all the sampled sites. The precipitation was a major factor affected the richness of phytoplankton. The diatoms predominated the phytoplankton of Gwangju Stream with 57.7~77.0% of total phytoplankton. The maximum cells of phytoplankton was observed at Yuchon bridge site with 23,792 cells $mL^{-1}$ in August 2003, and minimum at Jeungsimsa site with 82 cells $mL^{-1}$ in April 2003. The periphyton of Gwangju Stream was predominated by the diatoms. In February 2004, all the periphyton of Yuchon bridge site were diatoms. Other sites also showed the predominance of diatoms throughout the studied period. The standing crops of phytoplankton were highly correlated with chlorophyll-a concentration with R=0.795. TN and TP also showed high relationships with phytoplankton standing crops in Yangdong market site with R=0.796 and R=0.760, respectively. The rains of 7-days ago showed high relationships with phytoplankton standing crop at Dongsan tower site with R=0.810. However, other climatic factors showed no clear relationships with phytoplankton cells.

• Korean Journal of Ecology and Environment
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• v.39 no.1 s.115
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• pp.1-12
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• 2006

Distributions of water temperature and DO profiles were investigated in Andong Reservoir from 1992 to 2004. Thermal stratification began to form from May of every year. Increasing water temperature of epilimnion, temperature difference between epilimnion and hypolimnion increased until August. Lower oxygen layer was formed at metalimnion from June or July of every year and there were 2 layers depending on each year. The two lower oxygen layers were affected by rainfall and inflow between July and September when thermal stratification was formed. The metalimnetic oxygen minima strongly formed at 2 layers, upper and lower part, when the average rainfall and inflow were ${\geqq}$ 170 mm, ${\geqq}$ 50 $m^3\;sec^{-1}$, respectively. It formed weakly when they were > 400 mm and > 200 $m^3\;sec^{-1}$ for one month. The upper part of low oxygen layers formed on the interface of epilimnion and metalimnion showed larger decreasing rate of DO than temperature and it disappeared around November. The lower part of those farmed on interface of metalimnion and hypolimnion existed until December and disappeared in January, this layer showed larger decreasing rate of temperature than DO. DO increased between the upper and lower part of the low oxygen layers. DO on hypolimnion increased under metalimnion and dramatically decreased near the bottom of the reservoir. Temperature of the inflow during rainy season was similar to that of the reservoir's metalimnion, DO was similar or higher and BOD, COD and SS increased. Density layer caused by turbidity was formed in metalimnion, and turbidity increased under the upper part (oxygen increasing layer) of metalimnetic DO minima layers reaching the maximum at the direct upper part of the lower DO minima layer. The upper part of DO minima layers formed on the interface of epilimnion and metalimnion is related to organic activity on the surface, and the lower part of those was considered to be the result of turbid water inflow to metalimnion during rainy season.

• Korean Journal of Ecology and Environment
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• v.36 no.3 s.104
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• pp.356-368
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• 2003

Water quality of effluent from wastewater treatment plants (WWTPS) was reviewed to examine the feasibility of agricultural reuse using USEPA and WHO guidelines. It might meet the guidelines for BOD and SS, however, the most critical microbiological concentration was too high and further treatment is required. The pilot study of three treatments were performed to reduce microbiological concentrations. The UV irradiation was proved to be very effective in disinfection of secondary level effluent, and about 30 mW ${\cdot}$ s/$cm^2$ of dose was suggested to meet the even most stringent USEPA guidelines. Slow sand filter demonstrated effective removal of bacteria, and effluent concentration of total coliform (TC), fecal coliform (FC), and E. coli. dropped from about 10,000/100 mL to 300, 200, and 150 MPN/100 mL, respectively, showing over 95% removal. These level of bacterial concentration sufficiently meet the WHO guidelines ($10^3\;{\sim}\;10^5$ FC/100 mL), and could meet the more stringent USEPA guidelines (200 FC/100 mL) if properly applied. Slow sand filter also provided about 50% removal of SS, turbidity, and BOD in addition to bacterial removal. The removal efficiency of pond system was relatively poor, but still showed over 85% removal and effluent concentration of TC, FC, and E. coli was all below 10,000/100 mL. The pond system alone could meet the WHO guidelines, but hardly meet the USEPA guidelines and further treatment might be necessary. Overall, three methods evaluated in the study treat the effluent to meet the WHO microbiological guidelines for agricultural reuse. The UV disinfection and slow sand filter might also could the USEPA guidelines, while the pond system can hardly meet the USEPA guidelines if applied alone. The WHO and USEPA guidelines were made based on data from upland field agricultural system and may not be directly applicable to the paddy field agricultural system. Therefore, national standards for agricultural reuse of reclaimed water should be made considering domestic agricultural systems as well as international guidelines. Also, further investigation is recommended to develop optimum and feasible treatment measures for agricultural reuse of effluent from WWTPs.

• Korean Journal of Ecology and Environment
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• v.41 no.3
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• pp.283-293
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• 2008

The objectives of the study were firstly to provide fundamental data for establishment of total maximum daily load (TMDL) management in Ulsan City, and secondly to make practical application of stream health assessment with tolerance range by each species when physiochemical and fish investigations were carried out together. A total of 44 sites in Taehwa River, Hoiya River, Dong Stream, and Cheongryang Stream were selected to monitor water qualities seasonally and fish investigation was performed in August 2006. Among the parameters of water quality, biological oxygen demand (BOD) and dissolved oxygen (DO) related to respiration, total nitrogen (T-N) and total phosphorus (T-P) related to nutrient and eutrophication, and total suspended solids (TSS) and $NH_4$-N were compared with vertical box plot by 8 dominant species. According to the fish investigation, 12 families 33 species were found including endangered species (Pungitius kaibarae) and introduced species (Lepomis macrochirus, Micropterus salmoides), and appearance rate of Korean endemic species was greater in Taehwa River (29.2%) than others. As the results of tolerance range by species, Zacco koreanus, Rhynchocypris oxycephalus, Iksookimia longicorpa, and Squalidus gracilis majimae had limited low range by water quality parameters indicating preference of good water quality. Whereas, Carassius auratus and Pseudorasbora parva were found downstream and urban-streams which were exposed from frequent inflow of pollutants. It concludes that the results help distinguishing sensitive, intermediate, and tolerant species when we evaluate stream health assessment with fish, and further making practical application for conservation and restoration of aquatic ecosystem.

• Korean Journal of Ecology and Environment
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• v.39 no.2 s.116
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• pp.187-197
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• 2006

A mathematical modeling program called Hydrological Simulation Program-FORTRAN (HSPF) developed by the United States Environmental Protection Agency(EPA) was applied to the Yongdam Watershed to examine its applicability for loading estimates in watershed scale. It was run under BASINS (Better Assessment Science for Integrating point and Nonpoint Sources) program, and the model was validated using monitoring data of 2002 ${\sim}$ 2003. The model efficiency of runoff was high in comparison between simulated and observed data, while it was relatively low in the water quality parameters. But its reliability and performance were within the expectation considering complexity of the watershed and pollutant sources and land uses intermixed in the watershed. The estimated pollutant load from Yongdam watershed for BOD, T-N and T-P was 1,290,804 kg $yr{-1}$, 3,753,750 kg $yr{-1}$ and 77,404 kg $yr{-1}$,respectively. Non-point source (NPS) contribution was high showing BOD 57.2%, T-N 92.0% and T-P 60.2% of the total annual loading in the study area. The NPS loading during the monsoon rainy season (June to September) was about 55 ${\sim}$ 72% of total NPS loading, and runoff volume was also in a similar rate (69%). However, water quality was not necessarily high during the rainy season, and showed a decreasing trend with increasing water flow. Overall, the BASINS/HSPF was applied to the Yongdam watershed successfully without difficulty, and it was found that the model could be used conveniently to assess watershed characteristics and to estimate pollutant loading in watershed scale.