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Preparation of Textured Bi0.5(Na,K)0.5TiO3-BiFeO3 Solid Solutions by Reactive-Templated Grain Growth Process

  • Kato, Kyoko;Kimura, Toshio
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.693-699
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    • 2006
  • Textured $Bi_{0.5}(Na,K)_{0.5}TiO_3-BiFeO_3$ ceramics were prepared by the reactive-templated grain growth process, using platelike $Bi_4Ti_3O_{12}$ particles. The effects of chemical composition in $Bi_{0.5}(Na,K)_{0.5}TiO_3$ on texture development and densification were examined. Textured ceramics were obtained by using $Bi_{0.5}K_{0.5}TiO_3$ as an end member of the solid solution but densification was limited. Dense ceramics were obtained by using $Bi_{0.5}Na_{0.5}TiO_3$ but texture did not develop. Dense, textured ceramics were obtained by using $Bi_{0.5}(Na_{0.5}K_{0.5})_{0.5}TiO_3$.

A study on the type of Bi(肥) and Su(痩) of Body in 'Yellow Emperior's Nei-Ching' (${\ll}$내경(內徑)${\gg}$을 중심(中心) 한 체형(體型)의 비수(肥痩)에 대(對)한 고찰(考察))

  • Chun, Tae Kang;Hong, Won Sik
    • Journal of Korean Medical classics
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    • v.6
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    • pp.176-188
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    • 1993
  • After studing on the type of Bi(肥) and Su(痩) of Body in 'Yellow Emperior's Nei-Ching', I reached the following conclusions; 1. The specific charactor of bi(肥) and su(痩) were explained in table 1. 2. The specific charactor of gi(脂), ko(膏) and youk(肉) were explaned in table 2. 3. Obserbing the type of bi(肥) and su(痩) by the view of YinYang(陰陽), bi(肥) belongs to Yin(陰) and su(痩) belongs to Yang(陽). Also the each of bi(肥) and su(痩) could obserbed by the view of YinYang(陰陽). The type of su(痩) easily becomes to yanghea(陽虛) because chi(氣) easely becomes to exhaust also easely becomes to yinhea(陰虛) because blood(血) easely becomes to exhaust. So the outer of body is cold, the inner of body is hot. The type of bi(肥) easely causes YinYang(陰陽) to exceed because blood(血) easely becomes to black and turbid(血黑以濁), chi(氣) easely becomes to rough and slow(氣澁以遲). So the outer of body is hot, the iner of body is cold 4. Obserbing the type of bi(肥) and su(痩) by the view of viscera, in view of upper and lower(上下觀點) su(痩) is yang(陽) so heart and lung belongs to su(痩) bi(肥) is yin(陰) so liver and kidney belongs In bi(肥). in view of inner and outer(內外觀點) su(痩) is inner(內) so heart 3I1d liver belongs In su(痩) bi(肥) is outer(外) so lung and kidney belongs to bi(肥). 5. Obserbing the type of bi(肥) and su(痩) by the view of body constitution(體質), partially body constitution was divided into gi(脂), ko(膏) and youk(肉), entirely there was OhtaeinLon(五態人論) and four constitutional medicine(四象醫學) I thing that taeyangin(太陽人) and soyangin(少陽人) belong to su(痩), taeyinin(太陰人) and soyinin(少陰人) belong to bi(肥).

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A Study on the effects of CSRR-metamaterial on Microstrip Comb-line Array Antennas (마이크로스트립 콤 어레이 안테나에서 CSRR-메타물질의 영향에 관한 연구)

  • Ki, Hyeon-Cheol
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.17 no.5
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    • pp.187-192
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    • 2017
  • We investigated the effects of the CSRR-metamaterial on microstrip comb-line array antennas. Microstrip comb-line array antennas was designed with 12 radiators, gain of 16.09dBi and bandwidth of 0.24GHz in the 24GHz ISM band. The designed antenna had radiation beam perpendicular to the antenna plane, co-polarization gain of 16.09dBi and cross-polarization gain of -10.86dBi. the CSRR-metamaterial increased largely the impedance bandwidth of the antenna from 0.24GHz to 3.6GHz. however as co-polarization gain became 10.08dBi and cross-polarization gain became 14.1dBi, co-polarization was mixed with cross-polarization. And the antenna gain lowered by 1.99dB. On the investigation of the dependence on the split-direction of the CSRR rings, it showed nearly the same characteristics for up-splitted ring used case and down-splitted ring used case. However in the case of arranging up-splitted ring and down-splitted ring in alternation, co-polarization gain decreased to -1.29dBi and cross-polarization gain increased to 13.9dBi, which meant the wave was transited to cross-polarization majority wave.

A Study on the Impact of Incubating Services Between BI Centers and the Firms in the BI (창업보육센터와 입주업체의 비교를 통한 창업보육센터의 효과적 운영전략에 대한 연구)

  • Oh, Chang-Gyu;Chang, Hwal-Sik
    • The Journal of Information Systems
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    • v.16 no.4
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    • pp.269-286
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    • 2007
  • Business Incubators(BI) guide starting-up firms through their growth process and as such constitute a strong instrument to promote innovation and entrepreneurship. This study classified the incubating services into communication, physical facilities, human resources, marketing, financial, legal, technology, and networking services. The research problem was tested with data from 103 BI centers and 561 starting-up firms in BI. The results from the survey are as follows: First, incubating services to important for the BI's performance are networking, communication, human resources, physical facilities, and marketing services. Second, the incubating services to satisfy on the firms in the BI are financial, human resources, marketing, communication, networking, and physical facilities services. Third, there are the differences between BI center and the firms in the BI by each incubating service except communication service. Finally, the results of MSEM(Multi-group Structured Equation Modeling) indicate the communication and networking services are more strongly affected to the performance at the BI centers. Vice versa, the marketing and financial services are more strongly affected to the satisfaction at the firms in the BI centers. Starting-up firms in business incubators showed strong desire to receive better support in such fields as marketing and financial services. BI needs to recognize such demand and provide improved services in such areas. Starting-up firms did not recognize the utility and importance of services in networking with other firms and supporting human resources. BI needs to promote services in such areas. Concerning communication services and physical facility support service, both BI and starting-up firms showed satisfactory levels of services.

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Study on Thermoelectric Properties of Cu Doping of Pulse-Electrodeposited n-type Bi2(Te-Se)3 Thin Films (펄스 전기도금법에 의해 제조된 n형 Bi2(Te-Se)3 박막의 Cu 도핑에 따른 열전특성에 관한 연구)

  • Heo, Na-Ri;Kim, Kwang-Ho;Lim, Jae-Hong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.40-45
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    • 2016
  • Recently, $Bi_2Te_3$-based alloys are the best thermoelectric materials near to room temperature, so it has been researched to achieve increased figure of merit(ZT). Ternary compounds such as Bi-Te-Se and Bi-Sb-Te have higher thermoelectric property than binary compound Bi-Te and Sb-Te, respectively. Compared to DC plating method, pulsed electrodeposition is able to control parameters including average current density, and on/off pulse time etc. Thereby the morphology and properties of the films can be improved. In this study, we electrodeposited n-type ternary Cu-doped $Bi_2(Te-Se)_3$ thin film by modified pulse technique at room temperature. To further enhance thermoelectric properties of $Bi_2(Te-Se)_3$ thin film, we optimized Cu doping concentration in $Bi_2(Te-Se)_3$ thin film and correlated it to electrical and thermoelectric properties. Thus, the crystal, electrical, and thermoelectric properties of electrodeposited $Bi_2(Te-Se)_3$ thin film were characterized the XRD, SEM, EDS, Seebeck measurement, and Hall effect measurement, respectively. As a result, the thermoelectric properties of Cu-doped $Bi_2(Te-Se)_3$ thin films were observed that the Seebeck coefficient is $-101.2{\mu}V/K$ and the power factor is $1412.6{\mu}W/mK^2$ at 10 mg of Cu weight. The power factor of Cu-doped $Bi_2(Te-Se)_3$ thin film is 1.4 times higher than undoped $Bi_2(Te-Se)_3$ thin film.

Thermoelectric Characteristics of the Electroplated Bi-Te Films and Photoresist Process for Fabrication of Micro Thermoelectric Devices (전기도금 공정으로 제조한 Bi-Te 박막의 열전특성 및 미세열전소자 형성용 포토레지스트 공정)

  • Lee, Kwang-Yong;Oh, Tae-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.2 s.43
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    • pp.9-15
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    • 2007
  • Thermoelectric properties of the electrodeposited Bi-Te films and photoresist process have been investigated to apply for thermoelectric thin film devices. After plating in Bi-Te solutions of 20 mM concentration, which were prepared by dissolving $Bi_2O_3$ and $TeO_2$ into 1M $HNO_3$, thermoelectric properties of the films were characterized with variation of the Te/(Bi+Te) ratio in a plating solution. With increasing the Te/(Bi+Te) ratio in the plating solution from 0.5 to 0.65, Seebeck coefficient of Bi-Te films changed from $-59{\mu}V/K$ to $-48{\mu}V/K$ and electrical resistivity was lowered from $1m{\Omega}-cm$ to $0.8m{\Omega}-cm$ due to the increase in the electron concentration. Maximum power factor of $3.5{\times}10^{-4}W/K^2-m$ was obtained for the Bi-Te film with the $Bi_2Te_3$ stoichiometric composition. Using multilayer overhang process, the photoresist pattern to form thermoelectric legs of 30 m depth and 100m diameter was successfully fabricated fur micro thermoelectric device applications.

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Effect of the Structure of MoO3/bismuth molybdate Binary Phase Catalysts on the Selective Oxidation of Propylene (MoO3/bismuth molybdate 혼합 2상 촉매의 구조에 따른 프로필렌 선택산화반응 특성)

  • Cha, T.B.;Choi, M.J.;Park, D.W.;Chung, J.S.
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.53-63
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    • 1992
  • M/BM -series catalysts, $MoO_3$ supported on ${\alpha}-Bi_2Mo_3O_{12}$ were also prepared by impregnation method. BM/M-series catalysts, ${\alpha}-Bi_2Mo_3O_{12}$ supported on $MoO_3$ were also prepared by coprecipitation. Structure and catalytic properties of the two phase catalysts were studied by means of using nitrogen adsorption, X-ray diffraction, and scanning electron microscopy. The reaction test for the selective oxidation of propylene to acrolein over Bi-molybdate catalysts was studied using a fixed-bed reactor system. In M/BM-series catalysts, $MoO_3$ was dispersed on ${\alpha}-Bi_2Mo_3O_{12}$, and the crystal structure of ${\alpha}-Bi_2Mo_3O_{12}$ remains unchanged by the presence of excess $MoO_3$. However the surface morphology and bulk structure of BM/M-series catalysts were altered probably because the precipitated $Bi(OH)_3$ reacted with $MoO_3$ during the calcination to form ${\alpha}-Bi_2Mo_3O_{12}$ phase. The results of propylene oxidation on both series catalysts showed that the reaction took place over the surface of ${\alpha}-Bi_2Mo_3O_{12}$ particle and the role of excess $MoO_3$ was to supply oxygen to ${\alpha}-Bi_2Mo_3O_{12}$. These increasing effects on activity were also observed in the mechanical mixtures of ${\alpha}-Bi_2Mo_3O_{12}$ and $MoO_3$.

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Thermoelectric properties of Bi2Te2.7Se0.3 grown by traveling heater method (Traveling heater method에 의해 성장된 Bi2Te2.7Se0.3의 열전특성)

  • Roh, Im-Jun;Hyun, Dow-Bin;Kim, Jin-Sang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.4
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    • pp.135-139
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    • 2015
  • $Bi_2Te_3-Bi_2Se_3$ alloy which is typical n-type thermoelectric material were grown by traveling heater method (THM) technique. We investigate the effect of the composition of $100-x(Bi_2Te_3)-x(Bi_2Se_3)$ and doping of n-type dopants such as $SbI_3$ and $CdCl_2$. Maximum figure of merit of $Bi_2Te_3-Bi_2Se_3$ alloy was observed with $CdCl_2$ 0.1 wt% (Z: $2.73{\times}10^{-3}/K$) and $SbI_3$ 0.05 wt% (Z: $2.29{\times}10^{-3}/K$). Deviation along the length of $Bi_2Te_3-Bi_2Se_3$ ingot grown by THM method is low, which indicates that the ingot is very homogenized. Also we observed the close relationship of between anisotropy ratio and dopant in the $90(Bi_2Te_3)-10(Bi_2Se_3)$ alloys. And we confirmed the fact that anisotropy ratio exerts thermoelectric performance in $Bi_2Te_3$ based n-type thermoelectric material.

Microwave Dielectric Properties in Bi-Substituted BaO.$Nd_{2}O_{3}$.$4TiO_{2}$ (Bi 가 치환된 BaO.$Nd_{2}O_{3}$.$4TiO_{2}$ 세라믹스의 마이트로파 유전특성)

  • Cheon, Jae-Il;Kim, Jeong-SeoG
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.659-663
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    • 1998
  • The effect of Bi-substitution in $BaO.(Nd_{1-x}Bi_x)_2O_3.4TiO_2$ ceramic was studied on the formation of crystal phases, microstructure, and microwave dielectric properties. $BaO.(Nd_{1-x}Bi_x)_2O_3.4TiO_2$, solid solution (0$\leq$x$\leq$0.2) were formed by Bi-substitution into the Nd site of $BaO.(Nd_{1-x}Bi_x)_2O_3.4TiO_2$ ceramics. Average grain size increased with Bi-substitution. Dielectric constant(${\varepsilon}_r$) increased from 84 to U8, and the temperature coefficient of resonant frequency(${\tau}_f$) decreased from 44 ppm/$^{\circ}C$ to -30 ppm/$^{\circ}C$ when Bi contents increased up to x=0.2 in $BaO.(Nd_{1-x}Bi_x)_2O_3.4TiO_2$ solid solutions. $BaO.(Nd_{1-x}Bi_x)_2O_3.4TiO_2$ solid solutions with x=0.04~0.08 showed the most superior microwave dielectric properties, those are ${\varepsilon}_r$= 89-92, Q . f = 5855~6091 GHz, and (${\tau}_f$)= -7.5-7.5 ppm/$^{\circ}C$.

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Crystallization behavior and thermoelectric properties of p-type $(Bi_{1-X}Sb_X)_2Te_3$ thin films prepared by magnerron sputtering (마그네트론 스퍼터링법으로 제조한 P형 $(Bi_{1-X}Sb_X)_2Te_3$ 박막의 결정성과 열전특성)

  • 연대중;오태성
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.353-359
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    • 2000
  • $(Bi_{0.15}Sb_{0.85})_2Te_3$ and $(Bi_{1-x}Sb_x)_2Te_3$ thermoelectric thin films were prepared by magnetron sputtering process, and their thermoelectric characteristics were investigated with variation of the sputtering condition and the $Sb_2Te_3$ content. The $(Bi_{0.15}Sb_{0.85})_2Te_3$ film, deposited by DC sputtering at $300^{\circ}C$ with rotating the Corning glass substrate at 10 rpm, was fully crystallized to $(Bi,Sb)_2Te_3$ phase with c-axis preferred orientation. This $(Bi_{0.15}Sb_{0.85})_2Te_3$ film exhibited the Seebeck coefficient of 185 $\mu$V/K which was higher than the values of other $(Bi_{0.15}Sb_{0.85})_2Te_3$ films fabricated with different sputtering conditions. With increasing the $Sb_2Te_3$ content, the Seebeck coefficient and electrical resistivity of p-type $(Bi_{1-x}Sb_x)_2Te_3$ (0.77$\leq$x$\leq$1.0) film were lowered. Among p-type $(Bi_{1-x}Sb_x)_2Te_3$ films, a maximum power factor of $0.79{\times}10^{-3}W/K^2-m$ was obtained at (Bi_{0.05}Sb_{0.95})_2Te_3$ composition..

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