• Title/Summary/Keyword: BFO

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PREPARATION AND CHARACTERIZATION OF MULTIFERROIC 0.8 $BiFeO_3$-0.2 $BaTiO_3$ THIN FIMLS BY PULSED LASER DEPOSITION

  • Kim, K.M.;Yang, P.;Zhu, J.S.;Lee, H.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.313-313
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    • 2010
  • $BiFeO_3$ (BFO), when forming a solid solution with $BaTiO_3$ (BTO), shows structural transformations over the entire compositional range, which not only gives a way to increase structural stability and electrical resistivity but also applies a means to have better ferromagnetic ordering. In this respect, we have prepared and studied 0.8 BFO-0.2 BTO thin films on Pt(111)/$TiO_2/SiO_2$/Si substrates by pulsed laser deposition. Various deposition parameters, such as deposition temperature and oxygen pressure, have been optimized to get better quality films. Based on the X-ray diffraction results, thin films were successfully deposited at the temperature of $700^{\circ}C$ and an oxygen partial pressure of 10mTorr and 330mTorr. The dielectric, ferroelectric, and magnetic properties have then been characterized. It was found that the films deposited under lower and higher oxygen pressure corresponded to lower leakage current. Magnetism measurement showed an induced ferromagnetism. The microstructures associated with the magnetic and dielectric properties of this mixed-perovskite solid solutions were observed by transmission electron microscopy, which revealed the existence of complicated ferroelectric domains, suggested that the weak spontaneous magnetization was closely associated with the decrease in the extent of rhombohedral distortion by a partial substitution of $BaTiO_3$ for $BiFeO_3$.

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Structural and Electrical Properties of Bi0.9A0.1Fe0.975Zn0.025O3-δ (A=Eu, Dy) BiFeO3 Thin Films by Chemical Solution Deposition (화학 용액 증착법으로 제조한 Bi0.9A0.1Fe0.975Zn0.025O3-δ (A=Eu, Dy) 박막의 구조와 전기적 특성)

  • Kim, Youn-Jang;Kim, Jin-Won;Chang, Sung-Keun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.4
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    • pp.226-230
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    • 2018
  • Pure $BiFeO_3$ (BFO) and codoped $Bi_{0.9}A_{0.1}Fe_{0.975}Zn_{0.025}O_{3-{\delta}}$ (A=Eu, Dy) thin films were prepared on Pt(111)/Ti/$SiO_2$/Si(100) substrates by chemical solution deposition. The remnant polarizations (2Pr) of the $Bi_{0.9}Eu_{0.1}Fe_{0.975}Zn_{0.025}O_{3-{\delta}}$ (BEFZO) and $Bi_{0.9}Dy_{0.1}Fe_{0.975}Zn_{0.025}O_{3-{\delta}}$ (BDFZO) thin films were about 36 and $26{\mu}C/cm^2$ at the maximum electric fields of 900 and 917 kV/cm, respectively, at 1 kHz. The codoped BEFZO and BDFZO thin films showed improved electrical properties, and leakage current densities of 3.68 and $1.21{\times}10^{-6}A/cm^2$, respectively, which were three orders of magnitude lower than that of the pure BFO film, at 100 kV/cm.

Simultaneously Enhanced Magnetic and Ferroelectric Properties of $Bi_{0.9}Dy_{0.1}Fe_{0.97}Co_{0.03}O_3 $ compound

  • Yu, Yeong-Jun;Hwang, Ji-Seop;Park, Jeong-Su;Lee, Ju-Yeol;Gang, Ji-Hun;Lee, Gwang-Hun;Lee, Bo-Hwa;Kim, Gi-Won;Lee, Yeong-Baek
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.147-147
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    • 2013
  • Multiferroic material $BiFeO_3$ (BFO) is a typical multiferroic material with a room-temperature magnetoelectric coupling in view of high magnetic- and ferroelectric-ordering temperatures (Neel temperature $T_N$ ~ 647 K and Curie temperature TC ~1,103 K). Rare-earth ion substitution at the Bi sites is very interesting, which induces suppressed volatility of the Bi ion and improved ferroelectric properties. At the same time, the Fe-site substitution with magnetic ions is also attracting, since the enhanced ferromagnetism was reported. In this study, BFO, $Bi_{0.9}Dy_{0.1}FeO_3$ (BDFO), $BiFe_{0.97}Co_{0.03}O_3$ (BFCO) and $Bi_{0.9}Dy_{0.1}Fe_{0.97}Co_{0.03}O_3 $ (BDFCO) compounds were prepared by conventional solid-state reaction and wet-mixing method. High-purity $Bi_2O_3$, $Dy_2O_3$, $Fe_2O_3$ and $Co_3O_4$ powders with the stoichiometric proportions were mixed, and calcined at $500^{\circ}C$ for 24 h. The samples were immediately put into an oven, which was heated up to 800oC and sintered in air for 1 h. The crystalline structure of samples was investigated at room temperature by using a Rigaku Miniflex powder diffractometer. The field-dependent magnetization measurements were performed with a vibrating-sample magnetometer. The electric polarization was measured at room temperature by using a standard ferroelectric tester (RT66B, Radiant Technologies). Dy and Co co-doping at the Bi and the Fe sites induce the enhancement of both magnetic and ferroelectric properties of $BiFeO_3$.

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Magnetic Properties and Impedance Spectroscopic Studies of Multiferroic Bi1-xNdxFeO3 Materials

  • Thang, Dao Viet;Thao, Du Thi Xuan;Minh, Nguyen Van
    • Journal of Magnetics
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    • v.21 no.1
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    • pp.29-34
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    • 2016
  • Nd-doped $BiFeO_3$ materials were synthesized via a sol-gel method. The crystal structure, magnetic properties, and complex impedance spectroscopy of multiferroic $Bi_{1-x}Nd_xFeO_3$ (BNFO) materials were investigated by X-ray diffraction (XRD), Raman scattering, vibrating sample magnetometer (VSM), and complex impedance spectroscopy. Our results show that the lattice crystal constants (a, c) and the ratio c/a of BNFO materials decreased with increasing Nd concentration. All samples exhibited weak ferromagnetism at room temperature, and the magnetization of samples was enhanced by the presence of $Nd^{3+}$ ions. There was an enhancement in the spontaneous magnetization of BFO with increasing Nd concentration, which is attributable to the collapse of the spin cycloid structure.

A Study on Application of Web-Based Lifestyle Balance Model(LBM) Program for Recovery from Substance Use Disorders(SUD) (물질사용장애(SUD) 회복을 위한 웹-기반 라이프스타일 균형 모델(LBM) 프로그램 적용에 관한 연구)

  • Jang, se-eun;Kim, nami;Kim, kwan-hyeong
    • Proceedings of the Korea Contents Association Conference
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    • 2019.05a
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    • pp.273-274
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    • 2019
  • 최근에는 혁신적인 디지털 기술을 이용한 다양한 응용 프로그램이 의료계에 소개되고 있다. 중독 과학 분야 또한 기술 혁신을 통해 중독 예방 관리 및 치료를 할 수 있는 방법을 적극적으로 모색하고 있다. 중독 회복에 있어 일상적인 환경에서의 적절한 치료개입과 장기적 관리에 대한 중요성은 널리 알려졌으나 낙인, 노출, 비용에 대한 우려로 정신의료서비스의 이용률이 저조했다. 따라서 중독 치료를 통해 전인적 성장을 돕는 자가 관리 체계가 있다면 유용할 것이다. 본 연구는 Davies(2015)의 라이프스타일 균형 모델(LBM)을 바탕으로 영국에서 개발된 웹기반 SUD 회복 프로그램인 Breaking Free Online(BFO)을 소개하고 향후 국내에서 적용 가능한 SUD의 치료적 개입 방향성을 제공하고자 한다.

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Ancillary Service Requirement Assessment Indices for the Load Frequency Control in a Restructured Power System with Redox Flow Batteries

  • Chandrasekar, K.;Paramasivam, B.;Chidambaram, I.A.
    • Journal of Electrical Engineering and Technology
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    • v.11 no.6
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    • pp.1535-1547
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    • 2016
  • This paper proposes various design procedures for computing Power System Ancillary Service Requirement Assessment Indices (PSASRAI) for a Two-Area Thermal Reheat Interconnected Power System (TATRIPS) in a restructured environment. In an interconnected power system, a sudden load perturbation in any area causes the deviation of frequencies of all the areas and also in the tie-line powers. This has to be corrected to ensure the generation and distribution of electric power companies to ensure good quality. A simple Proportional and Integral (PI) controllers have wide usages in controlling the Load Frequency Control (LFC) problems. So the design of the PI controller gains for the restructured power system are obtained using Bacterial Foraging Optimization (BFO) algorithm. From the simulation results, the PSASRAI are calculated based on the settling time and peak over shoot concept of control input deviations of each area for different possible transactions. These Indices are useful for system operator to prepare the power system restoration plans. Moreover, the LFC loop coordinated with Redox Flow Batteries (RFB) has greatly improved the dynamic response and it reduces the control input requirements and to ensure improved PSASRAI, thereby improving the system reliability.

Epitaxial Growth of $BiFeO_3-Ba(Cu_{1/3}Nb_{2/3})O_3$ Thin Films Deposited by Pulsed Laser Deposition

  • Baek, Chang-U;Lee, Jong-Pil;Seong, Gil-Dong;Jeong, Jong-Hun;Ryu, Jeong-Ho;Yun, Un-Ha;Park, Dong-Su;Jeong, Dae-Yong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.30.1-30.1
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    • 2011
  • Multiferroic thin films with composition $0.9BiFeO_3-0.1Ba(Cu_{1/3}Nb_{2/3})O_3$ were epitaxially grown by pulsed laser deposition on $SrRuO_3(001)/SrTiO_3$ (000) substrate $0.9BiFeO_3-0.1Ba(Cu_{1/3}Nb_{2/3})O_3$, which is assumed to be morphotropic phase boundary (MPB), that showed superior dielectric, ferroelectric and magnetic properties in our study on polycrystalline films. The structures of epitaxially grown films were characterized by means of XRD. From P-E measurements, samples exhibited typical ferroelectric hysteresis loops and large remnant polarization, whose value is much larger than those of pure BFO film. The enhancement of dielectric, ferroelectric, magnetic properties was attributed to the structural distortion induced by the BCN addition and the high physical stress effect.

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Enhanced Sintering Behavior and Electrical Properties of Single Phase BiFeO3 Prepared by Attrition Milling and Conventional Sintering

  • Jeon, Nari;Moon, Kyoung-Seok;Rout, Dibyranjan;Kang, Suk-Joong L.
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.485-492
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    • 2012
  • Dense and single phase $BiFeO_3$ (BFO) ceramics were prepared using attrition milled calcined (coarse) powders of an average particle size of ${\approx}3{\mu}m$ by conventional sintering process. A relative density of ${\approx}96%$ with average grain size $7.3{\mu}m$ was obtained when the powder compacts were sintered at $850^{\circ}C$ even for a shorter duration of 10 min. In contrast, densification barely occurred at $800^{\circ}C$ for up to 12 h rather the microstruce showed the growth of abnormal grains. The grain growth behavior at different temperatures is discussed in terms of nonlinear growth rates with respect to the driving force. The sample sintered at $850^{\circ}C$ for 12 h showed enhanced electrical properties with leakage current density of $4{\times}10^{-7}A/cm^2$ at 1 kV/cm, remnant polarization $2P_r$ of $8{\mu}C/cm^2$ at 20 kV/cm, and minimal dissipation factor (tan ${\delta}$) of ~0.025 at $10^6$ Hz. These values are comparable to the previously reported values obtained using unconventional sintering techniques such as spark plasma sintering and rapid liquid phase sintering.

Microstructures and Magnetic Properties of Multiferroic BiFeO3 Thin Films Deposited by RF Magnetron Sputtering Method (RF 마그네트론 스퍼터링법으로 증착된 Multiferroic BiFeO3 박막의 미세구조 및 자기적 특성)

  • Song, Jong-Han;Nam, Joong-Hee;Kang, Dae-Sik;Cho, Jung-Ho;Kim, Byung-Ik;Choi, Duck-Kyun;Chun, Myoung-Pyo
    • Journal of the Korean Magnetics Society
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    • v.20 no.6
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    • pp.222-227
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    • 2010
  • $BiFeO_3$ (BFO) thin films were deposited on Pt/Ti/$SiO_2$/Si(100) substrates by RF magnetron sputtering method at room temperature. The influence of the flow rate of $O_2$ gas on the preparation of $BiFeO_3$ thin films was studied. XRD results indicate that the $BiFeO_3$ thin films were crystallized to the perovskite structure with the presence of small amount of impurity phases. The flow rate of $O_2$ gas has great affect on the microstructures and magnetic properties of $BiFeO_3$ thin films. As flow rate of $O_2$ gas increased, roughness and grain size of the thin films increased. $BiFeO_3$ thin films exhibited weak ferromagnetic behavior at room temperature. The PFM images revealed correlation between the surface morphology and the piezoresponse, indicating that the piezoelectric coefficient is related to microstructure.