• Title/Summary/Keyword: BET study

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Treatment of the Wastewater of High Surfactant Concentration by GAC GAC Adsorption (GAC에 의한 고농도 계면활성제 폐수의 흡착처리)

  • Kim, Hag-Seong;Lee, Jin-Phil;Han, Hoon-Suk
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.1
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    • pp.59-65
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    • 1999
  • For a cosmetic plant wastewater containing surfactants of high concentration, adsorption treatment by granular activated carbon(GAC) having different pore size distribution was studied. Three sorts GACs were used and regenerated afterwards with methanol. Experiments were composed of batch process and column test for both virgin and regenerated GACs. Following conclusions were drawn from the study: Methylene blue activating substance(MBAS) adsorption data from the batch tests for three GACs are described well by BET isotherm and Freundich isotherm. Simulation with the BET isotherm shows that maximum adsorption appears to be affected not only by specific surface area but also by pore size distribution. Maximum adsorption from the BET isotherm for MBAS appears to diminish as the number of reactivation increases. The diminishing ratio of maximum adsorption appears to decrease as the pore size decreases. Recovery ratio of the methanol by vacuum evaporation from the spent methanol ranges from 95% to 97%.

Surface and Adsorption Properties of Activated Carbon Fabric Prepared from Cellulosic Polymer: Mixed Activation Method

  • Bhati, Surendra;Mahur, J.S.;Dixit, Savita;Choubey, O.N.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.569-573
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    • 2013
  • In this study, activated carbon fabric was prepared from a cellulose-based polymer (viscose rayon) via a combination of physical and chemical activation (mixed activation) processes by means of $CO_2$ as a gasifying agent and surface and adsorption properties were evaluated. Experiments were performed to investigate the consequence of activation temperature (750, 800, 850 and $925^{\circ}C$), activation time (15, 30, 45 and 60 minutes) and $CO_2$ flow rate (100, 200, 300 and 400 mL/min) on the surface and adsorption properties of ACF. The nitrogen adsorption isotherm at 77 K was measured and used for the determination of surface area, total pore volume, micropore volume, mesopore volume and pore size distribution using BET, t-plot, DR, BJH and DFT methods, respectively. It was observed that BET surface area and TPV increase with rising activation temperature and time due to the formation of new pores and the alteration of micropores into mesopores. It was also found that activation temperature dominantly affects the surface properties of ACF. The adsorption of iodine and $CCl_4$ onto ACF was investigated and both were found to correlate with surface area.

A Study on Characterization of Surface and Pore for Ag-impregnated Activated Carbon (은이 침착된 활성탄의 표면과 세공특성에 관한 연구)

  • Kim, Jong-Gyu;Oh, Won-Chun;Kim, Myoung-Kun
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.729-733
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    • 1998
  • The surface structure and the pore size distribution of the activated carbon impregnated with silver have been investigated. It has been confirmed that the impregnants had an effect only on the external surface, not on the internal surface and that adsorption isotherms of both impregnated and non-impregnated activated carbons were classified as a typical BET type-I. As the amount of the impregnants increased, the amounts of adsorption, the specific surface area, and the micropore volume decreased and the window blocking was observed. The average pore diameter of the activated carbon impregnated with silver was observed to show the constant values regardless of the amount of the impregnants.

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Hydrogen Production from Ammonia Decomposition over Transition Metal Carbides (전이금속 카바이드를 이용한 암모니아 분해 반응으로부터 수소생산)

  • CHOI, EUI-JI;CHOI, JEONG-GIL
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.1
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    • pp.1-7
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    • 2019
  • The preparation and catalytic activities of various transition metal carbide crystallites (VC, MoC, WC) were examined in this study. In particular, the effect of different kinds of transition metal crystallites were scrutinized on the ammonia decomposition reaction. The experimental results showed that BET surface areas ranged from $8.3m^2/g$ to $36.3m^2/g$ and oxygen uptake values varied from $9.1{\mu}mol/g$ to $25.4{\mu}mol/g$. Amongst prepared transition metal carbide crystallites, tungsten compounds (WC) were observed to be most active for ammonia decomposition reaction. The main reason for these results were considered to be related to the extent of electronegativity between these materials. Most of transition metal carbide crystallites were exceeded by Pt/C crystallite. However, the steady state reactivities for some of transition metal carbide crystallites (WC) were comparable to or even higher than that determined for the Pt/C crystallite.

Influences of betaine supplementation on growth performance and fecal score in sows and their piglets fed a corn soybean meal-based diet

  • Sureshkumar, Shanmugam;Baek, Dong Heon;Kim, In Ho
    • Korean Journal of Agricultural Science
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    • v.48 no.1
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    • pp.1-9
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    • 2021
  • A total of twenty-four multiparous sows (Landrace × Yorkshire) and their litters were used in this 21-day experimental trial. Based on their body weight, sows were randomly allocated into one of three treatments with eight replicates. The dietary betaine supplementation contained three levels: (i) CON (Basal diet + 0% Bet), (ii) Bet 0.05% (CON + 0.05% Betaine), and (iii) Bet 0.15% (CON + 0.15% Betaine). The supplementation of betaine had no effect (p > 0.05) on body weight and feed intake of lactating sow. Moreover, no significant response was observed on backfat thickness, body condition score, and weaning of the estrus interval with the dietary supplementation of betaine. In addition, the litter weaning weight, litter weight gain, average litter daily gain, and survivability rate at birth showed no significant difference with the dietary betaine supplementation of the sow diet. Fecal scores of the lactating sows and suckling piglets were not affected (p > 0.05) with the dietary betaine supplementation compared with the control diet during the experimental periods. The findings of this study showed that betaine supplementation does not boost growth performance, feed intake, body conditions, and fecal score in lactating sows and suckling piglets fed a corn-soybean meal-based diet.

Spatial-Temporal Distribution Characteristics of Bigeye and Yellowfin Tunas in Kiribati Waters

  • Taanga, Aketa Mature;Cai, Yi-Hui;Lu, Hsueh-Jung;Ni, I-Hsun
    • Proceedings of the KSRS Conference
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    • v.1
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    • pp.174-179
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    • 2006
  • Information on the distribution characteristics of tuna resources in Kiribati EEZ waters in three zones (Zone 1: west Gilbert region, Zone 2: central Phoenix region, and Zone 3: east Line region) as well as their relationship with the ocean environment is critical for sustainable managing the migratory tuna resource and fishing practices in this region. Therefore, this study is designed to investigate the spatial and temporal distribution and concentration of bigeye (BET) and yellowfin tuna (YFT) in Kiribati EEZ waters in relation to sea surface temperature (SST) and thermocline depth so as to better understand the tuna resources management basis in Kiribati waters. The geographic and temporal distribution and concentration were first displayed. Paired t-test was utilized to compare the distribution between the two tuna species based on Catch per Unit Effort (CPUE) derived from the Korean longliners during 1996 to 2004, and also among the three zones of Kiribati EEZ waters. Environmental conditions of the three zones were then compared and correlated with the CPUE of YFT and BET. In addition, the effect of ENSO phenomena on the environmental conditions and the distribution of YFT and BET within the three zones were also examined. The BET was relatively higher in the Zone 3 whereas YFT predominate in the Zone 1 and the Zone 2 due to oceanographic differences among the three zones and the ecological habitats of the two tuna species. It was suggested that El Ni?o/Southern Oscillation (ENSO) phenomena altered the oceanographic conditions of the three zones that in turn change the distribution of the two tuna species. During El Ni?o, the warm phase of ENSO, resulted in having more BET in all the three zones and the opposite observed during La Ni?a (cold phase) replacing by having relatively higher catch rate for YFT, particularly in the Zone 2. Although the results of the study are from short periods (1996 to 2004) in considering oceanographic anomality, these environmental variations should be considered into sustainable fisheries management of tuna fisheries in Kiribati EEZ waters.

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A Study on Dry Film Formation of Clay Solution (점토 혼합액의 건조박막 형성에 관한 연구)

  • 박헌휘
    • Journal of Energy Engineering
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    • v.7 no.2
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    • pp.180-186
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    • 1998
  • In this study, the effect of shear rate on the viscosity variation is examined to understand the flow characteristics of the mixture of bentonite and water. The variation of film thickness according to mixing ratio and viscosity is measured to characterize the film formation. And, the separation of dried film is studied according to film thickness. Specific surface area affecting on adsorption capability is measured using BET method. The viscosity decreases and the film thickness increases as the mixing ratio increases. The separation characteristic of dried film is suitable within a range of 40 to 150 ${\mu}{\textrm}{m}$ in film thickness and 5 to 10% in mixing ratio.

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Adsorption of Cu(II) Ions onto Myristica Fragrans Shell-based Activated Carbon: Isotherm, Kinetic and Thermodynamic Studies

  • Syahiddin, D.S.;Muslim, A.
    • Journal of the Korean Chemical Society
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    • v.62 no.2
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    • pp.79-86
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    • 2018
  • This study reported the adsorption of Cu(II) ions onto activated carbon prepared from Myristica Fragrans shell (MFS AC) over independent variables of contact time, activating chemical (NaOH) concentration, initial adsorbate concentration, initial pH of adsorbate solution and adsorption temperature. The MFS AC structure, morphology and total surface area were characterized by FTIR, SEM and BET techniques, respectively. The Cu(II) ions adsorption on the MFS AC (activated using 0.5 M NaOH) fitted best to Freundlich adsorption isotherm (FAI), and the FAI constant obtained was 0.845 L/g at $30^{\circ}C$ and pH 4.5. It followed the pseudo first order of adsorption kinetic (PFOAK) model, and the PFOAK based adsorption capacity was 107.65 mg/g. Thermodynamic study confirmed the Cu(II) ions adsorption should be exothermic and non-spontaneous process, physical adsorption should be taken place. The total surface area and pore volume based on BET analysis was $99.85m^2/g$ and 0.086 cc/g, respectively.

Modulation of Bee Venom on Th1/Th2 Cell Lineage Development (봉독 추출액이 helper T cell 분화에 미치는 영향)

  • Ko Eun Jung;Nam Sang Soo;Hong Moo Chang;Shin Min Kyu;Bae Hyun Su
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.18 no.5
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    • pp.1347-1355
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    • 2004
  • In this study, the immunological effect of a traditional Korea herbal acupuncture, that has been widely used for the treatment of various immunological disorders including inflammation in Korea, was examined in vitro and in vivo. In our previous study demonstrated that BV increased the expression of IFN-γ mRNA, that plays pivotal role in T cell response. This study was designated to evaluate the effect of BV on helper T cell development by monitoring Th1/Th2 specific cytokine secretion patterns in artificially induced Th1/Th2 polarized condition and in vivo. The results demonstrated that BV didn't have mitogenic effects on the unstimulated CD4+ T cell, but increased the CD4+ T cell proliferation upon activation with anti-CD3/CD28 antibody. The Th1 cells were over-populated dramatically in Th1 driven condition with BV treatment, while the Th2 cells were increased slightly in Th2 skewed condition. Furthermore, under Th1-skewed conditions, the level of IFN-γ was considerably increased with BV treatment. Besides, the expression of T-bet, a transcription factor that plays pivotal role in Th1 lineage programming, was increased with BV treatment. The expressions of IFN-γ and T-bet were also significantly increased in vivo. The results that Th1 specific cytokine secretion were considerably increased and Th2 specific cytokine secretion were not significantly changed in vitro and in vivo indicated that BV enhances Th1 lineage development, Therefore, these results suggest that BV might be desirable agent for correction of Th1 dominant pathological disorders.

Effect of Storage Times on Sperm Function, Sperm Chromatin Structure Assay (SCSA) and Correlations Between Fertility and SCSA in Boars (액상 정액의 보존 기간이 정자 기능 및 정자염색질 구조 분석에 미치는 영향과 인공수정 분만율과의 상관관계)

  • 유재원;이주형;김인철;이일주;강 권;민동수;윤희진;윤종택;방명걸;류범용;정영채;김창근
    • Journal of Animal Science and Technology
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    • v.48 no.6
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    • pp.785-796
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    • 2006
  • This study was designed to evaluate the changes in sperm motility, viability, HOST(hypo-osmotic swelling test), IVP(in vitro penetration), SCSA(sperm chromatin structure assay) during storage of liquid semen collected from boars with different farrowing rates using AI, and to find the relationship between boar fertility through AI and sperm diagnostic parameters during semen storage. The results of HOST were significantly decreased according to the increasing of in semen storage days and the results of IVP were significantly decreased at 3 days of semen storage (P<0.05). The %Red was significantly different among the >80%, 70󰠏80% and <70% farrowing rate group at semen storage day 6(P<0.05). The correlation coefficients between the %Red and farrowing rate were increased according to the semen storage. In conclusion, these results suggest that the sperm parameters evaluated in these studies may be useful indicators to predict the fertility of AI and evaluate the semen quality in boars.