• Bulletin of the Korean Chemical Society
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• v.34 no.6
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• pp.1800-1808
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• 2013

Dual-responsive amphiphilic block copolymers were synthesized by combining enzymatic ring-opening polymerization (eROP) of ${\varepsilon}$-caprolactone (CL) and ATRP of N,N-dimethylamino-2-ethyl methacrylate (DMAEMA). The obtained block copolymers were characterized by gel permeation chromatography (GPC), $^1H$ NMR and FTIR-IR. The critical micelle concentration (CMC) of copolymer was determined by fluorescence spectra, it can be found that with hydrophilic block (PDMAEMA) increasing, CMC value of the polymer sample increased accordingly, and the CMC value was 0.012 mg/mL, 0.025 mg/mL and 0.037 mg/mL for $PCL_{50}$-b-$PDMAEMA_{68}$, $PCL_{50}$-b-$PDMAEMA_{89}$, $PCL_{50}$-b-$PDMAEMA_{112}$, $PCL_{50}$-b-$PDMAEMA_{89}$ was chosen as drug carrier to study in vitro release profile of anti-cancer drug (taxol). The temperature and pH dependence of the values of hydrodynamic diameter (Dh) of micelles, and self-assembly of the resulting block copolymers in water were evaluated by dynamic light scattering (DLS). The result showed that with the temperature increasing and pH decreasing, the Dh decreased. Drug-loaded nanoparticles were fabricated using paclitaxel as model. Transmission electron microscopy (TEM) and atomic force microscopy (AFM) had been explored to study the morphology of the hollow micelles and the nanoparticles, revealing well-dispersed spheres with the average diameters both around 80 nm. In vitro release kinetics of paclitaxel from the nanoparticles was also investigated in different conditions (pH and temperature, etc.), revealing that the drug release was triggered by temperature changes upon the lower critical solution temperature (LCST) at pH 7.4, and at $37^{\circ}C$ by an increase of pH.

• Polymer(Korea)
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• v.37 no.3
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• pp.332-341
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• 2013

H-shaped amphiphilic pentablock copolymers $(PSt)_2-b-PCL-b-PEO-b-PCL-b-(PSt)_2$ was synthesized via chemoenzymatic method by combining enzyme-catalyzed ring-opening polymerization (eROP) of ${\varepsilon}$-caprolactone (${\varepsilon}$-CL) and atom transfer radical polymerization (ATRP) of styrene. By this process, we obtained copolymers with controlled molecular weight and low polydispersity. The structure and composition of the obtained copolymers were characterized by nuclear magnetic resonance (NMR), gel permeation chromatography (GPC) and infrared spectroscopy analysis (IR). The crystallization behavior of the copolymers was analyzed by differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The crystallization behavior of the H-shaped block copolymers demonstrated a PCL dominate crystallization. The self-assembly behavior of the copolymers was investigated in aqueous media. The hydrodynamic diameters of the copolymer micelles in aqueous solution were measured by dynamic light scattering (DLS). The morphology of the copolymer micelles was observed by atomic force microscopy (AFM) and transmission electron microscopy (TEM). The hydrodynamic diameters of spherical micelles declined gradually with the increase of the hydrophobic chain lengths of the copolymers. The critical micelle concentration (CMC) values were determined from fluorescence emission, and it was found that the CMCs decreased with an increase of PSt hydrophobic block lengths.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.38B no.4
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• pp.279-290
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• 2013

In this paper, we propose a transmission scheme of MAC protocol that enables secure voice communications by exploiting the wide spectrum and low signal strength characteristics of the ultra wide band technology. In addition, it also supports high level of terminal mobility by deploying mobile ad hoc network schemes. While most of existing UWB MAC protocols are operated as a synchronous mode, the proposed scheme operates in an asynchronous mode for supporting high mobility and sends voice packets without RTS/CTS control packets for efficient voice traffic transmission without retransmission. With simulation program, we prove that the proposed scheme satisfies the required voice quality and packet delivery time.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.33 no.8B
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• pp.646-656
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• 2008

In this paper, we design and verify the MAC chip of the two-stage AWG-based WDM-PON which considers 128 ONUs and 32 wavelengths. Each wavelength with the capacity of 1Gbps is allocated to ONU for downstream transmission but each wavelength for upstream transmission can be shared by four ONUs. Therefore, MAC protocol is required to avoid the collision and use the network resource efficiently among ONUs which are sharing the same wavelength. To design a request/permit-based MAC protocol, we define a unit-chip module called sub-MAC. The WDM-PON with 128 ONUs can be implemented by using 32 sub-MAC modules. The sub-MAC consists of one control unit, one receipt unit and four transmission units. The state transition diagram of the module is described by the internal/external control signals among the functional units. The function of the sub-MAC module is verified through logic simulation using ModelSIM.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.35 no.1B
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• pp.95-105
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• 2010

IEEE 802.15.4 is the one of the protocols for radio communication in a personal area network. Since it aims to provide low cost and low power communication for ubiquitous communication, it requires high level of optimization in implementation. Recently, there have been many studies on the performance evaluation of IEEE 802.15.4 MAC protocol. According to the results of the studies, it is tendency that the transceiver is implemented to SoC type. On the implementation, the specific functions of MAC like CSMA-CA and MAC frame handling is designed to hardwired functions. In this paper, we implemented the protocol with hardwired low MAC (HL-MAC) and its state machine for the optimization from the physical layer and MAC layer. it has the characteristics of the small code size and the enhanced power consumption.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.30 no.9A
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• pp.803-813
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• 2005

This paper explores the throughput performance of CSMA/CA-based DCF protocol over frequency-selective, slow Ricean fading channels with both the $E_{b}/N_{o}$ and BER at the MAC layer in the 802.1 la wireless LAN. By exploring the throughput of DCF protocol with the data rate of 6Mbps, 12 Mbps, 24 Mbps and 54 Mbps, we find the fact that the higher the $E_{b}/N_{o}$ be and the less the BER be, the higher the throughput be.

• Carbon letters
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• v.12 no.2
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• pp.70-80
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• 2011

Two pitches with different average molecular structures were electrospun and compared in terms of the properties of their fibers after oxidative stabilization, carbonization, and activation. The precursor with a higher molecular weight and greater content of aliphatic groups (Pitch A) resulted in better solubility and spinnability compared to that with a lower molecular weight and lower aliphatic group content (Pitch B). The electrical conductivity of the carbon fiber web from Pitch A of 67 S/cm was higher than that from Pitch B of 52 S/cm. The carbon fiber web based on Pitch A was activated more readily with lower activation energy, resulting in a higher specific surface area compared to the carbon fiber based on Pitch B (Pitch A, 2053 $m^2/g$; Pitch B, 1374 $m^2/g$).

• The Journal of Korean Institute of Communications and Information Sciences
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• v.31 no.10B
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• pp.866-871
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• 2006

This paper presents the design of a reservation-based MAC protocol to support multimedia traffic over mobile ad-hoc networks and evaluates its performance. Our MAC protocol is based on a hierarchical approach consisting of two sub-layers. The lower sub-layer of the MAC protocol with reservation provides a fundamental access method using CSMA/CA in order to support asynchronous data traffic over mobile ad-hoc networks. The upper sub-layer supports real-time periodic data by making a slot reservation before transmitting actual data. The proposed protocol has been validated through simulations using ns-2. The results show that the proposed MAC protocol can offer higher throughput and lower delay than standard implementations of the IEEE 802.11.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.25 no.3B
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• pp.456-463
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• 2000

Bidirectional cable TV networks using HFC(Hybrid Fiber Coaxial) networks need MAC (Medium access control) protocols to have efficient access in upstream channels. In this paper, we have studied and evaluated several contention resolution algorithms and mapping of higher layer traffic described in IEEE 802.14 and MCNS (Multimedial Cable Network System) MAC protocols with respect to IP, ABR and CBR traffic types. IEEE 802.14 MAC protocol demonstrates better performance for transmitting ATM cells while the MCNS MAC protocols for the IP traffic.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.34 no.4B
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• pp.360-367
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• 2009

In this paper, we propose a design methodology of IEEE 802.11n MAC which aims to achieve the higher throughput of more than 100Mbps in downlink as measured at the MAC-SAP and present the implementation results of MAC using the proposed design methodology. With our proposed methodology, different from the conventional design flow which has the separate codes for the protocol validation, for the network simulation, and for the system implementation, the unified code can be used for the network simulation and the implementation of software and hardware. Our MAC architecture is partitioned into two parts, Upper-layer MAC and Lower-layer MAC, in order to achieve the high efficiency for the new features of IEEE 802.11n standard. They are implemented in software and hardware respectively. The implemented MAC is tested on ARM based FPGA board.