• Journal of Magnetics
• /
• v.4 no.3
• /
• pp.73-75
• /
• 1999

By appliying an slternate pulsed magnetic field -generated by using a sequential ignition circuit and a magnet exciting circuit- with peak value of about 10 T to the rod type Nd based magnet Nd2Fe12.7Cr1.3B with length of 5 mm and diameter of 3.6 mm, the basic magnetic properties such as saturation magnetization, residual magnetization, coercivity, maximum energy products, magnetic anisotropy and anisotropic field are investigated with obtaining the major and minor J-H loops of the magnet. The increase in coercivity due to eddy currents in ac measurement of coercivity is calculated considering eddy current loss by analyzing a wave of generating magnetic field. The average coercivity calculated for the magnet is about 12.2 kOe, anisotropy magnetic field and anisotropic constant are measured as 60 kOe 2.43 Mj/$m^3$, respectively.

• Journal of the Korean Vacuum Society
• /
• v.4 no.S2
• /
• pp.24-29
• /
• 1995

The magnetic amd magneto-optical(MO)properties of Co-based multilayered(ML)films are known to vary sensitively according to the manufacturing methods and the film microstructures. Co/Pd and Co/Pt ML films with ultrathin layers of Co were prepared by alternating deposition in an ultrahigh-vacuum physical-vapor-deposition system. The individual layer thicknesses of the samples were estimated making use of the angular positions of x-ray diffraction peaks. The magnetic and MO properties were investigated, and correlated systematically to the structural parameters of the films. A Kerr spectrometer was self-manufactured to measure the MO properties such as Kerr rotation angle, ellipticity and reflectivity. The rms surface roughness was also measured using atomic force microscopy. Some of the samples showed good properties for MO medium, such as large perpendicular magnetic anisotropy and Kerr rotation, and perfect squareness of the magnetic hysteresis loop.

• Proceedings of the Korean Magnestics Society Conference
• /
• 2012.05a
• /
• pp.121-122
• /
• 2012

Iron-excess gallium ferrite, $Ga_{0.6}Fe_{1.4}O_3$ (GFO), is known to have room-temperature ferromagnetic phases and potentially exhibit ferroelectricity as well [1]. But, leaky polarization-electric field (PE) hysteresis curves of the GFO thin film are hurdle to prove its spontaneous polarization, in other words, ferroelecticity. One of the reasons that the GFO films have leaky PE hysteresis loop is carrier hopping between $Fe^{2+}$ and $Fe^{3+}$ sites due to oxygen deficiency. We focus on reducing conducting current by substituting divalent cations at $Fe^{2+}$ sites. GFO thin films were grown epitaxially along b-axis normal to $SrRuO_3/SrTiO_3$ (111) substrates by pulsed laser deposition. Current density of the ion-substituted GFO thin films was reduced by $10^3$ or more. Ferroelectric properties of the ion-substituted GFO thin films were measured using macroscopic and microscopic schemes. In particular, local ferroelectric properties of the GFO thin films were exhibited and their remnant polarization and piezoelectric d33 coefficient were obtained.

• Journal of the Korean Chemical Society
• /
• v.61 no.1
• /
• pp.29-33
• /
• 2017

Formation of Au particles in nonstoichiometric $Cu_{2-x}{^I}Cu{_2}^{II}O_{3-{\delta}}$ ($x{\approx}0.20$; ${\delta}{\approx}0.10$) oxide from aniline + hydrochloric acid mixtures and chloroauric acid in the ratios 30 : 1; 60 : 1; 90 : 1 (S1-S3) by volume and 0.01 mol of copper acetate, $Cu(OCOCH_3)_2.H_2O$, in each case is performed by sol-gel growth. Powder x-ray diffraction (XRD) results show Au particles are dispersed in tetragonal nonstoichiometric dicopper (I) dicopper (II) oxides, $Cu_{2-x}{^I}Cu{_2}^{II}O_{3-{\delta}}$ ($x{\approx}0.20$; ${\delta}{\approx}0.10$). Average crystallite sizes of Au particles determined using Scherrer equation are found to be in the approximate ranges ${\sim}85-140{\AA}$, ${\sim}85-150{\AA}$ and ${\sim}80-150{\AA}$ in S1-S3, respectively which indicate the formation of Au nano-micro size particles in $Cu_{2-x}{^I}Cu{_2}^{II}O_{3-{\delta}}$ ($x{\approx}0.20$; ${\delta}{\approx}0.10$) oxides. Hysteresis behaviour at 300 K having low loop areas and magnetic susceptibility values ${\sim}5.835{\times}10^{-6}-9.889{\times}10^{-6}emu/gG$ in S1-S3 show weakly ferromagnetic nature of the samples. Broad and isotropic electron paramagnetic resonance (EPR) lineshapes of S1-S4 at 300, 77 and 8 K having $g_{iso}$-values ${\sim}2.053{\pm}0.008-2.304{\pm}0.008$ show rapid spin-lattice relaxation process in magnetic $Cu^{2+}$ ($3d^9$) sites as well as delocalized electrons in Au ($6s^1$) nano-micro size particles in the $Cu_{2-x}{^I}Cu{_2}^{II}O_{3-{\delta}}$ ($x{\approx}0.20$; ${\delta}{\approx}0.10$) oxides. Broad and weak UV-Vis diffuse reflectance optical absorption band ~725 nm is assigned to $^2B_{1g}{\rightarrow}^2A_{1g}$ transitions, and the weak band ~470 nm is due to $^2B_{1g}{\rightarrow}^2E_g$ transitions from the ground state $^2B_{1g}$(${\mid}d_{x^2-y^2}$>) of $Cu^{2+}$ ($3d^9$) ions in octahedral coordination having tetragonal distortion.

• Journal of the Korean Magnetics Society
• /
• v.15 no.2
• /
• pp.72-75
• /
• 2005

The profiles of the second-order higher harmonics during B-H hysteresis loop have been measured as functions of the tensile stress in grain-oriented $3.2{\%}$ Si steels. The observed harmonics profiles have been analyzed in terms of the nonlinear, asymmetric magnetization which reflects the domain reorientation under the field. The field interval of the second-order higher harmonics is related to the nucleation and annihilation fields and a measurement method for the magnetostriction is proposed using the harmonics profiles under tensile stress.

• Journal of Magnetics
• /
• v.16 no.4
• /
• pp.435-439
• /
• 2011

In this work, we prepared Fe-Ni alloy nanopowders by wire electrical explosion in deionized water and ethanol. Particles size and morphology of the as-synthesized nanoparticles prepared in water and ethanol were observed by transmission electron microscopy. In both cases, the as-synthesized nanoparticles were in nearly spherical shape and their size distribution was broad. The particles prepared in the water were in core-shell structure due to the oxidation of Fe element. X-ray diffraction was used to analyze the phase of the nanopowders. It showed that the nanopowders prepared in water had ${\gamma}$-Fe-Ni solid solution and FeO phase. The samples obtained in ethanol were in two phases of Fe-Ni solid solution, ${\gamma}$-Fe-Ni and ${\alpha}$-Fe-Ni. Bulk samples were made from the as-synthesized nanopowders by spark plasma sintering at $1000^{\circ}C$ for 10 min. Structure of the bulk sample was observed by scanning electron microscope. Magnetic properties of the as-synthesized nanopowders and the bulk samples were investigated by vibrating sample magnetometer. The hysteresis loop of the assynthesized nanopowders and the sintered bulk samples revealed a ferromagnetic characteristic.

• Journal of Magnetics
• /
• v.21 no.2
• /
• pp.209-214
• /
• 2016

This paper analyzes the magnetic property according to the machined shape of steel material with non-oriented silicon steel (50PN470/50A470), that is most commonly used in the design of electrical equipment. Toward this end, specimens were produced and divided into Bar-Specimen (Epstein Frame Tester) and Ring-Specimen (Toroidal Ring Tester). The characteristics of the electrical Silicon steel were measured using the instruments solely dedicated to measuring each specimen. The core loss of the Bar-Specimen, which is commonly used, was found to be less than that of the Ring-Specimen. This is a very important design factor in achieving the objectives of improving the product efficiency and predicting the performance of electrical equipment. It serves as a critical point of view in order to reduce the error between design value and product value. A comparative analysis was conducted regarding various characteristics (Hysteresis, B-H characteristic, Iron loss, Minor loop, Coercive force, Residual magnetic flux density, etc.) of the electrical silicon steel considered in the design of the electrical equipment according to the specimen.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2007.06a
• /
• pp.242-242
• /
• 2007

무방향성 규소강판을 lamination core 형태로 제작하여 자기적 특성을 조사 하였다. 그 결과 1차, 2차 권선수가 400turns 시료에서 보자력(Hc)과 포화자속밀도(Bs)는 최대값을 나타내었고, 보자력은 0.05Oe, 포화자속밀도는 1.8T 이었다. 현재 국내에서 생산되고 있는 무방향성 규소강판의 자속밀도값 보다 더 우수한 강을 나타내었으며, 열화특성이 자기적 특성에 미치는 영향을 통해 고효율 무방항성 규소강판 개발의 가능성을 확인하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2006.06a
• /
• pp.245-246
• /
• 2006

방향성 규소강판을 tape-wound core 형태로 제작하여 $N_2$ gas 분위기에서 $760^{\circ}C$ 4 시간동안 열처리후 자기적 특성을 조사 하였다. 그 결과 1차, 2차 권선수가 85 turns 시료에서 보자력(Hc)과 포화자속밀도(Bs)는 최대값을 나타내었고, 보자력은 0.019Oe, 포화자속밀도는 1.92T 이었다. 현재 국내에서 생산되고 있는 방향성 규소강판의 자속밀도값 보다 더 우수한 값을 나타내었으며, 열화특성이 자기적 특성에 미치는 영향을 통해 고효율 방향성 규소강판 개발의 가능성을 확인하였다.

• Journal of the Korean Magnetics Society
• /
• v.18 no.1
• /
• pp.24-27
• /
• 2008

We have prepared $MnFe_2O_4$ nanoparticles with polyol method. The crystallographic and magnetic properties were measured by using X-ray diffraction(XRD), vibrating sample magnetometer(VSM) and $M\"{o}ssbauer$ spectroscopy. The high resolution transmission electron microscope(HRTEM) shows uniform nanoparticle-sizes with $6{\sim}8$ nm. The crystal structure is found to be single-phase cubic spinel with space group of Fd3m. The lattice constant of $MnFe_2O_4$ nanparticles is determined to be $8.418{\pm}0.001{\AA}$. $M\"{o}ssbauer$ spectrum of $MnFe_2O_4$ nanparticles at room temperature(RT) shows a superparamagnetic behavior. In VSM analysis, the diagnosis of the superparamagnetic behavior is also shown in hysteresis loop at RT. $M\"{o}ssbauer$ spectrum at 4.2K shows that the well developed two sextets are with different hyperfine field $H_{hfA}=498$(A-site) and $H_{hfB}=521$(B-site) kOe.