• Journal of the Korean Chemical Society
• /
• v.62 no.5
• /
• pp.372-376
• /
• 2018

A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$ $\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

• Earthquakes and Structures
• /
• v.10 no.1
• /
• pp.1-23
• /
• 2016

Steel plate shear walls (SPSWs) have been shown to be efficient lateral force-resisting systems, which are increasingly used in new and retrofit construction. These structural systems are designed with either stiffened and stocky or unstiffened and slender web plates based on disparate structural and economical considerations. Based on some limited reported studies, on the other hand, employment of low yield point (LYP) steel infill plates with extremely low yield strength, and high ductility as well as elongation properties is found to facilitate the design and improve the structural behavior and seismic performance of the SPSW systems. On this basis, this paper reports system-level investigations on the seismic response assessment of multi-story SPSW frames under the action of earthquake ground motions. The effectiveness of the strip model in representing the behaviors of SPSWs with different buckling and yielding properties is primarily verified. Subsequently, the structural and seismic performances of several code-designed and retrofitted SPSW frames with conventional and LYP steel infill plates are investigated through detailed modal and nonlinear time-history analyses. Evaluation of various seismic response parameters including drift, acceleration, base shear and moment, column axial load, and web-plate ductility demands, demonstrates the capabilities of SPSW systems in improving the seismic performance of structures and reveals various advantages of use of LYP steel material in seismic design and retrofit of SPSW systems, in particular, application of LYP steel infill plates of double thickness in seismic retrofit of conventional steel and code-designed SPSW frames.

• International Journal of High-Rise Buildings
• /
• v.7 no.4
• /
• pp.313-325
• /
• 2018

Concrete-filled steel tubular (CFST) members are commonly used as composite columns in modern construction. However, the current guidelines for members' fire design (EN1994-1-2) have been proved to be unsafe in case the relative slenderness is higher than 0.5. In addition, the simplified design methods of Eurocode 4 are limited to circular and square CFST columns, while in practice columns with rectangular and elliptical hollow sections are being increasingly used because of their architectural aesthetics. In the last years a large experimental research has been carried out at Coimbra University on the topic. They have been tested concrete filled circular, square, rectangular and elliptical hollow columns with restrained thermal elongation. Some parameters such as the slenderness, the type of cross-section geometry as well as the axial and rotational restraint of the surrounding structure to the column have been tested in order to evaluate their influence on the fire resistance of such columns. In this paper it is evaluated the influence of the boundary conditions (pin-ended and semi-rigid end-support conditions) on the behavior of the columns in case of fire. In these tests it could not be seen a marked effect of the tested boundary conditions but it is believed that the increasing of rotational stiffness increases the fire resistance of the columns.

• Journal of the Society of Naval Architects of Korea
• /
• v.29 no.4
• /
• pp.202-213
• /
• 1992

For the analysis and design of ship structures the generalized slope deflection method(GSDM) taking account of axial elongation effect as well as the bending and shearing deformation is developed. Using the span point concept, the existing slope deflection method is easy to transform the variable section to the equivalent uniform one under the bending moment and the shear force, but it is difficult to analyze the web frame with inclined members because the axial deformation effect is not considered. In the present method, the equilibrium conditions including all force components(i.e. axial force, shear force, bending moment) are formulated at the both ends of the variable section beam, such that the usual space frame stiffness equation which can be solved easily by the matrix method is derived. The accuracy and applicability of the present method is demonstrated by analyzing the ship web frame structures.

• The Journal of the Petrological Society of Korea
• /
• v.10 no.2
• /
• pp.82-94
• /
• 2001

The main geological structure of the Ogcheon belt in the Buunnyeong area, Mungyeong, which consists of three stratigraphic sequences, Joseon and Pyeongan Supergroups and Daedong Group, is characterized by the development of ESE-vergence structural unit (Dangok unit) and WNW-vergence structural units (Samsil and Bugongni units) onto an autochthonous unit (Buunnyeong unit). Three phases of deformation are recognized in this area. The lent phase of deformation coourred under the WNW-ESE compression, forming an upright-open fold (Buunnyeong-I fold) with NNE axial trend in the Buunnyeong unit. The second phase of deformation also under the WNW-ESE compression formed the Dangok, Samsil and Bugongni units, resulting in the further closing of the Buunnyeong-I open fold, the elongation of pebbles in the conglomerate rocks of a basal sequence of the Daedong Group, recumbent folds (Buunnyeong-II fold) and drag folds (Dangok fold) with NNE axial trend in the Buunnyeong and Dangok units, respectively. The third phase of deformation formed kink folds with its axis p1unging subvertically. The first and second phases of deformation took place before and after the deposition of the Daedong Group of the Upper Triassic -Lower Jurassic, respectively. These first two deformation events, which occurred under the same WNW-ESE compressional field, produced the regional NNE trend of geological structure in the Joseon and Pyeongan Supergroups of this area.

• Journal of the Korea Concrete Institute
• /
• v.18 no.1 s.91
• /
• pp.91-100
• /
• 2006

This paper presents an analytical model for evaluation of crack widths in structural concrete members. The model is mathematically derived from the actual bond stress-slip relationships between the reinforcement and the surrounding concrete, and the relationships summarized in CEB-FIP Model Code 1990 are employed in this study together with the assumption of a linear slip distribution along the interface at the stabilized cracking stage. With these, the actual strains of the steel and the concrete are integrated respectively along the embedment length between the adjacent cracks so as to obtain the difference in the axial elongation. The model is applied to the test specimens available in literatures, and the predicted values are shown to be in good agreement with the experimentally measured data.

• Journal of Adhesion and Interface
• /
• v.6 no.2
• /
• pp.13-20
• /
• 2005

Interfacial shear strength (IFSS) of environmentally friendly natural fiber reinforced polymer composites plays a very important role in controlling the overall mechanical performance. The IFSS of various Ramie and Kenaf fibers/epoxy composites was evaluated using the combination of micromechanical test and nondestructive acoustic emission (AE) to find out optimal conditions for desirable final performance. Dynamic contact angle was measured for Ramie and Kenaf fibers and correlated the wettability properties with interfacial adhesion. Mechanical properties of Ramie and Kenaf fibers were investigated using single-fiber tensile test and analyzed statistically by both uni-and bimodal Weibull distributions. An influence of clamping effect on a real elongation for both Ramie and Kenaf fibers were evaluated as well. Two different microfailure modes, axial debonding and fibril fracture coming from fiber bundles and single fiber composites (SFC) were observed under tension and compression.

• Journal of the Korea Concrete Institute
• /
• v.22 no.6
• /
• pp.833-841
• /
• 2010

In this report, the test results of five reinforced concrete beam-column joint subjected to cyclic load are presented. The main purpose of the research is to investigate the influence of the steel pull-out of the beam-column joints to the shear and ductile capacity of the RC beam-column assembles. In addition, the influence of the amount of beam reinforcement to the joint shear and ductile capacity is evaluated. Test results indicate that the yield penetration of steel bar increases as the joint shear strength ratio, $V_{j1}/V_{jby}$ decreases. And the slippage of the steel bars are varied according to the region of the beam-column joints. The pull-out of the steel bars of five specimens was almost the same regardless of the joint shear strength ratio, $V_{j1}/V_{jby}$. Because it was affected by not only the yield penetration of steel bar but also the axial elongation in the plastic hinge.

• Journal of Ocean Engineering and Technology
• /
• v.33 no.3
• /
• pp.259-271
• /
• 2019

It is important to obtain reasonable predictions of the extent of the damage during maritime accidents such as ship collisions and groundings. Many fracture models based on different mechanical backgrounds have been proposed and can be used to estimate the extent of damage involving ductile fracture. The goal of this study was to compare the damage extents provided by some selected fracture models. Instead of performing a new series of material constant calibration tests, the fracture test results for the ship building steel EH36 obtained by Park et al. (2019) were used which included specimens with different geometries such as central hole, pure shear, and notched tensile specimens. The test results were compared with seven ductile fracture surfaces: Johnson-Cook, Cockcroft-Latham-Oh, Bai-Wierzbicki, Modified Mohr-Coulomb, Lou-Huh, Maximum shear stress, and Hosford-Coulomb. The linear damage accumulation law was applied to consider the effect of the loading path on each fracture surface. The Swift-Voce combined constitutive model was used to accurately define the flow stress in a large strain region. The reliability of these simulations was verified by the good agreement between the axial tension force elongation relations captured from the tests and simulations without fracture assignment. The material constants corresponding to each fracture surface were calibrated using an optimization technique with the minimized object function of the residual sum of errors between the simulated and predicted stress triaxiality and load angle parameter values to fracture initiation. The reliabilities of the calibrated material constants of B-W, MMC, L-H, and HC were the best, whereas there was a high residual sum of errors in the case of the MMS, C-L-O, and J-C models. The most accurate fracture predictions for the fracture specimens were made by the B-W, MMC, L-H, and HC models.

• Steel and Composite Structures
• /
• v.47 no.2
• /
• pp.269-287
• /
• 2023

The WGJ420 fire-resistant weathering (FRW) steel is developed and manufactured with standard yield strength of 420 MPa at room temperature, which is expected to significantly enhance the performance of steel structures with excellent fire and corrosion resistances, strong seismic capacity, high strength and ductility, good resilience and robustness. In this paper, the mechanical properties of FRW steel plates and buckling behavior of columns are investigated through tests at elevated temperatures. The stress-strain curves, mechanical properties of FRW steel such as modulus of elasticity, proof strength, tensile strength, as well as corresponding reduction factors are obtained and discussed. The recommended constitutive model based on the Ramberg-Osgood relationship, as well as the relevant formulas for mechanical properties are proposed, which provide fundamental mechanical parameters and references. A total of 12 FRW steel welded I-section columns with different slenderness ratios and buckling load ratios are tested under standard fire to understand the global buckling behavior in-depth. The influences of boundary conditions on the buckling failure modes as well as the critical temperatures are also investigated. In addition, the temperature distributions at different sections/locations of the columns are obtained. It is found that the buckling deformation curve can be divided into four stages: initial expansion stage, stable stage, compression stage and failure stage. The fire test results concluded that the residual buckling capacities of FRW steel columns are substantially higher than the conventional steel columns at elevated temperatures. Furthermore, the numerical results show good agreement with the fire test results in terms of the critical temperature and maximum axial elongation. Finally, the critical temperatures between the numerical results and various code/standard curves (GB 51249, Eurocode 3, AS 4100, BS 5950 and AISC) are compared and verified both in the buckling resistance domain and in the temperature domain. It is demonstrated that the FRW steel columns have sufficient safety redundancy for fire resistance when they are designed according to current codes or standards.