• Bulletin of the Korean Chemical Society
• /
• v.24 no.10
• /
• pp.1490-1494
• /
• 2003

Noncovalently linked electron donor-acceptor dyad consisting of zinc tetratolylporphyrin and pyridine appended ruthenium trisbipyridine comlex was prepared, via axial coordination of pyridine moiety in ruthenium trisbipyridine complex on zinc tetratolylporphyrin. For the purpose of comparison, axial coordination of pyridine-appended 2,2'-bipyridine on zinc tetratolylporphyrin was also investigated. The Kvalues were detemined based on absorption of fluorescence studies. The fluorescence of zinc teratolylporphrin was efficiently quenched upon axial coordination of pyridine moiety, prbably due to the photoinduced electron transfer from zinc tetrtolylporphyrin to ruthenium trisbipyridine, supported by free enegy estimation.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.12
• /
• pp.4247-4252
• /
• 2011

The porphyrin-incorporated arylether dendrimers ZnP-D1 and ZnP-D4 were investigated to discover the influence of dendritic environments for the axial ligation of pyridine and photoinduced electron transfer by methyl viologen. Absorption and fluorescence spectra of ZnP, ZnP-D1, and ZnP-D4 were measured in dichloromethane with the addition of pyridine or methyl viologen dichloride. Axial ligation of pyridine was confirmed by red-shifted absorption spectrum. The complex formation constants $K_f$ (Table 1) for axial coordination of pyridine on ZnP, ZnP-D1, and ZnP-D4 were estimated to be $4.4{\times}10^3\;M^{-1}$, $3.3{\times}10^3\;M^{-1}$, and $1.7{\times}10^3\;M^{-1}$, respectively. The photoinduced electron transfer to methyl viologen dichloride was confirmed by fluorescence quenching. Stern-Volmer constants Ksv for ZnP, ZnP-D1, and ZnP-D4 were calculated to be $2.6{\times}10^3$, $2.5{\times}10^3$, and $2.1{\times}10^3$, respectively. ZnP-D4 surrounded by 4 aryl ether dendrons shows the smallest $K_f$ and Ksv values, with comparison to ZnP and ZnP-D1.

• 전기의세계
• /
• v.22 no.3
• /
• pp.13-24
• /
• 1973

In this report, as a method to solve the problems on impulse insulation coordination in ribbon core transformer owing to it's BIL stepping up, new design to alter winding distribution of multiple-layer concentric winding to Convex type winding is proposed. The main focus of this method is to settle the weakness of axial direction insulation strength and as a result of theoretical analysis through experiment of model transformers, the following conclusions are obtained; (a) As the electric loadings in a design which increases by strengthenning axial direction insulation endurance in presently avarilable transformers owing to it's BIL stepping up can be restricted in Convex type winding, reasonable design will be suited to the transformer with higher BIL. (b) Convex type winding is a very improved insulation design in respect of insulation coordination because it has shield plate effect to even impulse oscillation. (c) There is a disadvantage to cause leakage flux to increase in Convex type winding, however, the constancy of electric loadings in a design in spite of BIL stepping up restricts the increase of leakage flux to some extent.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.6
• /
• pp.1401-1404
• /
• 2009

• Journal of Power System Engineering
• /
• v.21 no.2
• /
• pp.57-63
• /
• 2017

The large-eddy simulation(LES) was carried out to evaluate the drag and static pressure acting on the blade surface of a small-size axial fan(SSAF) under the condition of unsteady-state, incompressible fluid and three-dimensional coordination. The axial component of drag coefficient increases with the increase of operating load, but the radial components have negligible sizes regardless of operating loads. Otherwise, the static pressures acting on the blade surfaces of SSAF show different distributions around the operating point of D equivalent to the stall. Also, with the increase of operating load, the static pressures acting on the pressure and suction surfaces of blade concentrate at the tips and leading-edges as a whole.

• Journal of the Korean Chemical Society
• /
• v.62 no.5
• /
• pp.372-376
• /
• 2018

A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$ $\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

• Bulletin of the Korean Chemical Society
• /
• v.25 no.5
• /
• pp.673-675
• /
• 2004

The tetranuclear copper(II) cluster compound $[Cu_4OCl_6(C_{14}H_{12}N_2)_4]$ has been synthesized by hydrothermal reaction and studied by X-ray diffraction. The four copper(II) atoms locate four capsheaves of a tetrahedral skeletal structure and a oxygen atom as interstitial atom occupies the center position of the same tetrahedron, and each edge of the Cu-Cu tetrahedron is bridged by one ${\mu}_2$-Cl anion. The copper atom possesses slightly distorted trigonal bipyramidal geometry with three ${\mu}_2$-Cl atoms in equatorial position and the interstitial O atom and one N atom from 3-benzyl-benzimidazole ligand occupying axial position. The Cu-Cu distances are in the range of 3.0986-3.1162 ${\AA}$. The EPR spectrum suggested that the copper(II) ground state $d_{x2-y2}$ and the coordination geometry was trigonal bipyramidal.

• Smart Structures and Systems
• /
• v.30 no.1
• /
• pp.63-74
• /
• 2022

The deformation coordination between a rock/soil mass and an optical sensing cable is an important issue for accurate deformation monitoring. A stress-controlled triaxial apparatus was retrofitted by introducing an optical fiber into the soil specimen. High spatial resolution optical frequency domain reflectometry (OFDR) was used for monitoring the strain distribution along the axial direction of the specimen. The results were compared with those measured by a displacement meter. The strain measured by the optical sensing cable has a good linear relationship with the strain calculated by the displacement meter for different confining pressures, which indicates that distributed optical fiber sensing technology is feasible for soil deformation monitoring. The performance of deformation coordination between the sensing cable and the soil during unloading is higher than that during loading based on the strain transfer coefficients. Three hypothetical strain distributions of the triaxial specimen are proposed, based on which theoretical models of the strain transfer coefficients are established. It appears that the parabolic distribution of specimen strain should be more reasonable by comparison. Nevertheless, the strain transfer coefficients obtained by the theoretical models are higher than the measured coefficients. On this basis, a strain transfer model considering slippage at the interface of the sensing cable and the soil is discussed.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.2
• /
• pp.636-640
• /
• 2012

We modify ZnO nanorods with Zn-porphyrin to obtain the improved characteristics of energy transfer, which is further investigated for the applicability to photovoltaic devices. A nitrogen heterocyclic ligand containing a thiol group is covalently grafted onto the surface of finely structured ZnO nanorods with a length of 50-250 nm and a diameter of 15-20 nm. Zn-porphyrin is then attached to the ligand molecules by the mechanism of metalligand axial coordination. The resulting energy band diagram suggests that the porphyrin-modified ZnO nanorods might provide an efficient pathway for energy transfer upon being applied to photovoltaic devices.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2010.09b
• /
• pp.96-103
• /
• 2010

This paper presents of effect of tunneling on pile group of being operated bridge using Three-dimensional numerical modeling to study the effect of coordination of tunneling location under discontinuous group pile. In order to find idealistic tunneling location that causes settlement, change of stress on the piles and movement of soil at a minimum, a fully coupled 3D finite element model is adopted. The study contains pile settlement, axial force on each piles in the group, axial displacement of piles and soil behaviour caused by tunneling. Based on the result some insights into the pile behavior due to tunneling obtained from numerical analysis were mentioned and discussed.