• Title/Summary/Keyword: Average grain size

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Vertical Distribution of Persistent Heavy metals in Core Sediments from Upo Wetland (자연습지 우포늪 퇴적물의 연도별 잔류성 중금속 축적도)

  • Lee, Chan Won;Boo, Min Ho;Jeon, Hong Pyo;Lim, Kyung Won;Kim, Ki Ho
    • Journal of Wetlands Research
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    • v.10 no.3
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    • pp.27-35
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    • 2008
  • Sediment cores were obtained from Upo and Mokpo in Upo Wetland and core samples were divided by depth into 20 ~ 21 subsamples. The heavy metal concentrations of Fe, Mn, Zn, AS, Cu, Cd, Ni, Pb, and Cr in the sediments of each depth were determined by ICP-MS. The texture of sediemnts from Upo Wetland appeared to be clayey silt with average grain size of $7.52{\sim}11.15{\mu}m$ for physical properties. It was found to have a clear tendency of depth profile with respect to TOC and ignition loss. Organics were stabilized in the range of 0.5 ~ 0.7 % TOC and 8 ~ 9 % ignition loss in 30 years, whereas, the surficial sediments have the highest concentrations of about 3.0 % of TOC and 13 ~ 15 % ignition loss. Those are much higher than the values of the main stream, the Nakdong River, which reflects the deposit of biodegradable organics from plants and other lifes. The vertical distribution of heavy metals in two sediment cores was investigated to elucidate historical trends of heavy metals deposited into Upo wetland. The depth profile concentrations of each heavy metal were compared and discussed with the Concensus-Based Sediment Quality Guidelines for freshwater ecosystems. All the Cd data for the vertical distribution in the sediments were detected above PEC value for Cd, which predict harmful effects on sediment-dwelling organisms expected to occur frequently. The concentrations of Zn, Cu, and Cr in all sediment samples for depth profile were detected below the TEC values, which provided a basis predicting the absence of toxicity by Zn, Cu, and Cr.

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The Effect of Die Upset and Heat Treatment on the Magnetic Properties of Mechanically Ground Nd-Fe-B Alloys (기계적 분쇄한 Nd-Fe-B 합금의 다이업셋과 열처리가 자기적 특성에 미치는 영향)

  • 정원용;박정덕;곽창섭;양현수
    • Journal of the Korean Magnetics Society
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    • v.4 no.3
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    • pp.233-238
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    • 1994
  • The effect of die upset and heat treatment on the magnetic properties of mechanically ground $Nd_{16}Fe_{78}B_{6}$ alloys has been studied. Although stripe domain patterns parallel to the compression direction were observed after die upset, it was found that crystallographic c-axes of a specimen were not completely aligned along the compression direction' which resulted in the decrease of Br. The average grain size of a die-upset specimen annealed for 5 hours at $1000^{\circ}C$ was about $20\mu\textrm{m}$, resulting in reduced values of Br and $_{i}H_{c}$. The maximum magnetic properties (Br=7.8 kG and $(_{i}H_{c}=14\;kOe) were obtained from the magnet die-upset at $750^{\circ}C$ using the alloy powder ground for 13 hours.

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IRAS OBSERVATIONS OF DARK GLOBULES

  • Lee, H.M.;Hong, S.S.;Kwon, S.M.
    • Journal of The Korean Astronomical Society
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    • v.24 no.1
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    • pp.55-70
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    • 1991
  • Infrared emission maps are constructed at 12.5, 25, 60, and $100{\mu}m$ for dark globules B5, B34, B133, B134, B361, L134 and L1523 by using Infrared Astronomical Satellite data base. These clouds are selected on the basis of their appearance in Palomar print as dark obscuring objects with angular sizes in the range of 3 to 30 arcminutes. The short wavelength(12.5 and $25{\mu}m$) maps show the embedded infrared sources. We found many such sources only in B5, B361 and B34 regions, Diffuse component at 12.5 and $25{\mu}m$, possibly arising from the stochastically heated very small dust grains(a < $0.01{\mu}m$) by interstellar radiation field, is found in B361 and L1523 regions. Such emission is characterized by the limb brightening, and it is confirmed in L1523 and in B361. Infrared emissions at the long wavelengths(60 and $100{\mu}m$) are due to colder dusts with temperature less than 20 K. The distribution of color index determined by the ratio 60 to $100{\mu}m$ intensities shows monotonic decrease of dust temperature toward the center. The black body temperature determined from these ratios is found to lie between 16 and 23 K. Such temperature is possible for small(i.e., $a\;{\lesssim}\;0.01{\mu}m$) graphite grains if the grains are mainly heated by interstellar radiation field. Thus IRAS 100 and $60{\mu}m$ emissions are arising mainly from small grains in the colud. The distribution of such dust grains implied from the emissivity distributions at 100 and $60{\mu}m$ resembles that of isothermal sphere. This contrasts to earlier findings of much steeper distribution of dusts contributing visible extinction. These dust grains are mainly larger ones(i.e., $a{\simeq}0.1{\mu}m$). Therefore we conclude that the average grain size increase, toward the cloud center.

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A study on copper thin film growth by chemical vapor deposition onto silicon substrates (실리콘 기판 위에 화학적 방법으로 증착된 구리 박막의 특성 연구)

  • 조남인;박동일;김창교;김용석
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.318-326
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    • 1996
  • This study is to investigate a chemical vapor deposition technique of copper film which is expected to be more useful as metallizations of microcircuit fabrication. An experimental equipment was designed and set-up for this study, and a Cu-precursor used that is a metal-organic compound, named (hfac)Cu(I)VTMS ; (hevaflouoroacetylacetonate trimethyvinylsilane copper). Base pressure of the experimental system is in $10^{-6}$ Torr, and the chamber pressure and the substrate temperature can be controlled in the system. Before the deposition of copper thin film, tungsten or titanium nitride film was deposited onto the silicon wafer. Helium has been used as carrier gas to control the deposition rate. As a result, deposition rate was measured as $1,800\;{\AA}/min$ at $220^{\circ}C$ which is higher than the results of previous studies, and the average surface roughness was measured as about $200\;{\AA}$. A deposition selectivity was observed between W or TiN and $SiO_{2}$ substrates below $250^{\circ}C$, and optimum results are observed at $180^{\circ}C$ of substrate temperature and 0.8 Torr of chamber pressure.

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Electrical Characteristics of ZnO-Pr6O11-CoO-Cr2O3-Y2O3 -Based Varistor Ceramics (ZnO-Pr6O11-CoO-Cr2O3-Y2O3계 바리스터 세라믹스의 전기적 특성)

  • 남춘우;김향숙
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.664-670
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    • 2002
  • The electrical characteristics of $ZnO-Pr_6O_{11}-CoO-Cr_2O_3-Y_2O_3$(ZPCCY)-based varistors were investigated with $Y_2O_3$ content in the range of 0.0~4.0 mol%. As $Y_2O_3$ content is increased, the average grain size was markedly decreased in the range of 18.6~3.2 $\mu m$ and the density of the ceramic was decreased in the range of 5.53 ~3.74 $g/\textrm{cm}^3$. While, the varistor voltage was increased in the range of 39.4~748.1 V/mm and the nonlinear exponent was in the range of 4.5~51.2 with increasing $Y_2O_3$ content. The addition of $Y_2O_3$ greatly enhanced the nonlinear properties of varistors, compared with the varistor without $Y_2O_3$. In particular, the varistors with $Y_2O_3$content of 0.5 mol% exhibited the highest nonlinearity, in which the nonlinear exponent is 51.2 and the leakage current is 1.3 $\mu A$. The donor concentration and the density of interface states were decreased in the range of (4.19~0.14) $\times$10$^{18}$ /㎤ and (5.38~1.15)${\times}10^{18}/\textrm{cm}^3$, respectively, with increasing $Y_2O_3$ content.

Effect of Nb Doping on the Dielectric and Strain Properties of Lead-free 0.94(Bi1/2Na1/2)TiO3-0.06BaTiO3 Ceramics

  • Han, Hyoung-Su;Hong, In-Ki;Kong, Young-Min;Lee, Jae-Shin;Jo, Wook
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.145-149
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    • 2016
  • $(Bi_{1/2}Na_{1/2})_{0.94}Ba_{0.06}(Ti_{1-x}Nb_x)O_3$ (BNBTxNb) ceramics were investigated in terms of the crystal structure as well as the ferroelectric, dielectric, and piezoelectric properties. While little change was observed in the microstructure except for a slight decrease in the average grain size, a significant change was noticed in the temperature dependence of dielectric and piezoelectric properties. It was shown that the property changes are closely related to the downward shift in the position of the ferroelectric-to-relaxor transition temperature with increasing amount of Nb doping. A special emphasis is put on the fact that Nb doping is so effective at decreasing the ferroelectric-to-relaxor transition temperature that even at no more than 2 at.% Nb addition, the transition temperature was already brought down slightly below room temperature, resulting in the birth of a large strain at 0.46 %, equivalent to $S_{max}/E_{max}=767pm/V$.

Structural and Electrical Properties of (Na0.465K0.465Bi0.07)(Nb0.93Ti0.07)O3-0.08MnO2 Ceramics with Variation of Sintering Temperature (소결온도에 따른 (Na0.465K0.465Bi0.07)(Nb0.93Ti0.07)O3-0.08MnO2 세라믹스의 구조적, 전기적 특성)

  • Lee, Tae-Ho;Yeo, Jin-Ho;Lee, Sung-Gap
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.7
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    • pp.506-510
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    • 2012
  • In this study, lead-free $(Na_{0.465}K_{0.465}Bi_{0.07})(Nb_{0.93}Ti_{0.07})O_3-0.08MnO_2$ ceramics were fabricated by conventional mixed oxide method. Structural and electrical properties of lead-free $(Na_{0.465}K_{0.465}Bi_{0.07})(Nb_{0.93}Ti_{0.07})O_3-0.08MnO_2$ ceramics with the variation of sintering temperature were investigated. As results of x-ray diffraction analysis, all specimens showed a typical polycrystalline perovskite structure without presence of the second phase. Sintered density increased with an increases of sintering temperature and the specimen sintered at $1,020^{\circ}C$ showed the maximum value of 4.5 $g/cm^3$. The average grain size of the $(Na_{0.465}K_{0.465}Bi_{0.07})(Nb_{0.93}Ti_{0.07})O_3-0.08MnO_2$ specimen sintered at $1,020^{\circ}C$ is about 0.83 ${\mu}m$. Electromechanical coupling factor, relative dielectric constant and dielectric loss of $(Na_{0.465}K_{0.465}Bi_{0.07})(Nb_{0.93}Ti_{0.07})O_3-0.08MnO_2$ specimens sintered at $1,020^{\circ}C$ were 0.252, 741 and 0.043% respectively.

Analysis of agricultural characteristics and qualities of CIMMYT resources in seeding time

  • Kang, Chon-Sik;Yoon, Young-Mi;Cheong, Young-Keun;Son, Jae-Han;Park, Jong-Chul;Kim, Yang-Kil;Park, Jong-Ho;Song, Tae-Hwa;Park, Tae-Il;Kim, Kyong-Ho;Kim, Bo-Kyeong
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.258-258
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    • 2017
  • We received 73 wheat resources from CIMMYT for analysis of agricultural characteristics and qualities of them. We sowed 73 lines and 4 Korean varieties in fall and spring to compare differences of wheat traits between fall and spring seeding. The heading and maturity date of fall seeding lines has coming faster average 18 days than spring seeding lines. Fall seeding lines have more number of spike per $m^2$ and grain number of spike. Spike and awn length of spring seeding lines were shorter than fall seeding lines and stem length was variable to varieties in both condition. Protein contents of five of 73 lines, Jokyoung and Jopoom varieties decreased but the others increased. The sedimentation values of 34 lines include Jokyoung and falling number (F/N) of 44 lines include two varieties, Keumkang and Jokyoung, decreased but the others increased, respectively. Particle size was presented that most spring seeding lines were bigger. However, when it sowed in fall, the lightness (L) of wheat flour was lighter. Consequently, we confirmed when it was sowed in spring, agricultural traits and qualities of wheat got weak.

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Distribution of Methyl Mercury in Sediments from Kyeonggi Bay, Namyang Bay, Chinhae Bay, and Lake Shihwa, Korea

  • Lee, Kyu-Tae;Kannan, Kurunthachalam;Shim, Won-Joon;Koh, Chul-Hwan
    • Journal of the korean society of oceanography
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    • v.33 no.4
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    • pp.178-184
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    • 1998
  • To elucidate contamination levels and distribution of methyl mercury (Me-Hg) in Korean coastal areas, 126 sediment samples were collected from Kyeonggi Bay, Namyang Bay, Chinhae Bay, and Lake Shihwa during 1995-1996, and the Me-Hg concentrations were determined by cold vapor atomic fluorescence spectrometry (CVAFS). Contamination levels of Me-Hg in sediments from Kyeonggi Bay, Namyang Bay, Chinhae Bay, and Lake Shihwa were 274 ${\pm}$ 990, 108 ${\pm}$ 24, 294 ${\pm}$ 342, and 1080 ${\pm}$ 760 pg/g, respectively. Concentrations of Me-Hg in sediments were significantly correlated with total organic carbon and sulfur contents, but were independent of mud contents and mean grain size. The highest concentration of Me-Hg (7100 pg/g) was observed at Incheon North Harbor (Site Kl9) in Kyeonggi Bay. This Me-Hg concentration was one or two orders of magnitude higher than those in other Kyeonggi Bay sediments were. The average concentration of Me-Hg in sediments from Lake Shihwa was higher than in those from other study areas. The three peaks of Me-Hg concentrations were observed on three sites (55, 56,and 510) in Lake Shihwa and gradually decreased in distance-dependent manner around these sites. High concentrations of Me-Hg at surface and 10-cm sediment depth in Chinhae Bay maybe due to higher rates of methylation process by active sulfate-reducing bacteria or higher concentrations of total mercury available to sulfate-reducing bacteria.

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Electrical Properties of Co- and Cu-Doped Nickel Manganite System Thick Films for Infrared Detectors

  • Lee, Dong-Jin;Lee, Sung-Gap;Kim, Kyeong-Min;Kwon, Min-Su
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.5
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    • pp.261-264
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    • 2017
  • $Ni_{0.79}Co_{0.15-x}Cu_xMn_{2.06}O_4$ ($0{\leq}x{\leq}0.09$) thick films were fabricated using the conventional solid-state reaction method and screen-printing method. Structural and electrical properties of specimens based on the amount of Cu were observed in order to investigate their applicability in the infrared detector. All specimens showed a single spinel phase with a homogeneous cubic structure. As the amount of Cu increased, the average grain size increased and was found to be approximately $5.01{\mu}m$ for the $Ni_{0.79}Co_{0.06}Cu_{0.09}Mn_{2.06}O_4$ specimen. The thickness of all specimens was approximately $55{\sim}56{\mu}m$. As Cu content increased, the resistivity and TCR properties at room temperature decreased, and these values for the $Ni_{0.79}Co_{0.06}Cu_{0.09}Mn_{2.06}O_4$ specimen were $502{\Omega}-cm$ and $-3.32%/^{\circ}C$, respectively. The responsivity and noise properties decreased with an increase in Cu content, with the specimen with a Cu content of x=0.09 showing 0.0183 V/W and $5.21{\times}10^{-5}V$, respectively.