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Electrical Characteristics of ZnO-Pr6O11-CoO-Cr2O3-Y2O3 -Based Varistor Ceramics

ZnO-Pr6O11-CoO-Cr2O3-Y2O3계 바리스터 세라믹스의 전기적 특성

  • 남춘우 (동의대학교 전기공학과) ;
  • 김향숙 (동의대학교 전기공학과)
  • Published : 2002.08.01

Abstract

The electrical characteristics of $ZnO-Pr_6O_{11}-CoO-Cr_2O_3-Y_2O_3$(ZPCCY)-based varistors were investigated with $Y_2O_3$ content in the range of 0.0~4.0 mol%. As $Y_2O_3$ content is increased, the average grain size was markedly decreased in the range of 18.6~3.2 $\mu m$ and the density of the ceramic was decreased in the range of 5.53 ~3.74 $g/\textrm{cm}^3$. While, the varistor voltage was increased in the range of 39.4~748.1 V/mm and the nonlinear exponent was in the range of 4.5~51.2 with increasing $Y_2O_3$ content. The addition of $Y_2O_3$ greatly enhanced the nonlinear properties of varistors, compared with the varistor without $Y_2O_3$. In particular, the varistors with $Y_2O_3$content of 0.5 mol% exhibited the highest nonlinearity, in which the nonlinear exponent is 51.2 and the leakage current is 1.3 $\mu A$. The donor concentration and the density of interface states were decreased in the range of (4.19~0.14) $\times$10$^{18}$ /㎤ and (5.38~1.15)${\times}10^{18}/\textrm{cm}^3$, respectively, with increasing $Y_2O_3$ content.

Keywords

References

  1. 半導? セラミ クスと その應用 こュ-ケラスシ-リズ編集委員會
  2. 電氣學會技術報告 no.474 酸化亞鉛避雷器の特性と評價試驗法 電氣學會
  3. J. Amer. Ceram. Soc. v.75 no.6 Phase indentification and electrical properties in ZnO-glass varistors Y.S. Lee;T. Y. Tseng https://doi.org/10.1111/j.1151-2916.1992.tb04236.x
  4. J. Amer. Ceram. Soc. v.76 no.8 Compositional effects on the liquid-phase sintering of praseodymium oxides-based zinc oxides varistors A.B. Alles;R. Puskas;G. Callahan;V. L. Burdick https://doi.org/10.1111/j.1151-2916.1993.tb08339.x
  5. J. Amer. Ceram. Soc. v.79 no.9 Microstructure and crystal phases of prasodymium in zinc oxide varistor ceramics Y.-S. Lee;K. -S. Liao;T. -Y. Tseng https://doi.org/10.1111/j.1151-2916.1996.tb08986.x
  6. 전기전자재료학회논문지 v.11 no.10 Y₂O₃첨가에 따른 ZnO:Pr 바리스터의 미세구조 및 전기적 특성에 관한연구 남춘우;정순철;이외천
  7. 전기전자재료학회논문지 v.11 no.10 이트리아가 첨가된 프라세오디뮴계 산화아연 바리스터의 안정성에 관한 연구 남춘우;박춘현
  8. 전기전자재료학회논문지 v.13 no.9 ZPCCE계 바리스터의 미세구조와 전기적 성질 및 안정성 남춘우;윤한수;류정선
  9. 전기전자재료학회논문지 v.14 no.5 Zn-Pr-Co-Cr-Er 산화물계 바리스터의 전기적 성질 남춘우;류정선
  10. J. Mater. Sci. Lett. v.19 no.4 Microstructure and varistor properties of ZnO-Pr6O11-CoO-Nd₂O₃ based ceramics C.-W. Nahm;C.-H. Park;H. -S. Yoo https://doi.org/10.1023/A:1006781823837
  11. J. Mater. Sci. Lett. v.19 no.9 Highly stable nonohmic characteristics of ZnO-Pr6O11-CoO₃-Dy₂O₃based varistors C.-W. Nahm;C. -H. Park;H. -S. Yoon https://doi.org/10.1023/A:1006739421559
  12. J. Mater. Sci. v.35 no.12 Microstructure, electrical properties, and degradation behavior of praseodymium-based doped with Y₂O₃ C.-W. Nahm;C. -H. Park https://doi.org/10.1023/A:1004749214640
  13. J. Mater. Sci. Lett. v.20 no.5 The nonlinear properties and d.c degradation characteristic of ZPCCE based varistors C. -W. Nahm;H. -S. Yoon;J. -S. Ryu https://doi.org/10.1023/A:1010969506901
  14. J. Mater. Sci. v.36 no.7 Effect of Er₂O₃ addition on the microstructure, electrical properties, and stability of Pr6O11-based ZnO ceramic varistors C. -W. Nahm;C.-H. Park https://doi.org/10.1023/A:1017552020433
  15. J. Appl. Phys. v.50 no.6 Capacitance vs. voltage characteristics of ZnO varistors K. Mukae;K. Tsuda;I. Nagasawa https://doi.org/10.1063/1.326411
  16. Semiconductor Ceramics: Grain Boundary Effects L. Hozer
  17. J. Amer. Ceram. Soc. v.55 no.97-12 Lineal intercept technique for measuring grain size in two-phase polycrystalline ceramics J.C. Wurst;J. A. Nelson https://doi.org/10.1111/j.1151-2916.1972.tb11224.x
  18. J. Amer. Ceram. Soc. v.73 no.7 Application of zinc oxide varistor T.K. Gupta https://doi.org/10.1111/j.1151-2916.1990.tb05232.x
  19. J. Appl. Phys. v.54 no.7 Intrinsic defects ZnO varistor G.D. Mahan https://doi.org/10.1063/1.332607
  20. J. Mater. Sci. v.20 A grain boundary defect model for instability/stability of a ZnO varitor T.K. Gupta;W.G. Carlson https://doi.org/10.1007/BF01113755