• Fire Science and Engineering
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• v.22 no.1
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• pp.99-104
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• 2008

It is important to understand thermal characteristic as a method to estimate the new materials, because spontaneous ignition characterized by causing combustion in the low temperature without ignition source. If can not find out the thermal characteristics of materials, it is frequent that causes of fires could not be found. The danger level of spontaneous ignition material should be estimated and by closely studying its thermal characteristic. However, RPF(Refuse Paper & Plastic Fuel) is a solid matter and getting increasesa year by year because it is an economy profit as alternative energy for limited fossil fuels. Some time RPF occur a fire in the cases of its production process and conservation. Therefore study for thermal stability and critical ignition temperature of RPF was so imperative that the experiment by means of Bombe Calorimeter, TG-DTA, MS80, SIT-II, and Wire Basket Test was implemented. As a result, RPF had a caloric value 26.4-28.3 MJ/kg, and its initial pyrolysis temperature was $192^{\circ}C$ at heating rate 2 K/min. With the result of analysis by MS 80 which is an instrument measuring microscopic calory, pure RPF not containing water has higher caloric value than RPF containing 20% water. Also, SIT-II which is an instrument of insulated auto-ignition was ignited by $118.5^{\circ}C$. This temperature is lower than that of Wire Basket Test. The critical ignition temperature was calculated by Frank-Kamenetskii equation can cause ignition at $80^{\circ}C$ when conserved in the height of 10 m by the standard of infinity slab.

• Journal of the Korean Society of Safety
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• v.29 no.3
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• pp.114-120
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• 2014

The purpose of this study is to conduct the study of the combustion and thermal characteristics through transportation oil for the analysis of fire hazard. Transportation oil breaks down into fuels such as diesel for civilian demands, gasoline, DF1(diesel for military), high sulfur diesel(for marine), kerosene and JP1(for aviation), and lubricants like brake fluid, power steering oil, engine oil, and automatic and manual transmission oil. The experiments of flash point, ignition point, flame duration time, heat release rate were carried out using TAG closed cup flash point tester(AFP761), Cleveland open cup auto flash point analyzer(AFP762), KRS-RG-9000 and Dual cone calorimeter. As a result, the fuel's ignition points were lower than lubricants, especially that of gasoline was not conducted as it has below zero one. Gasoline has the highest ignition point of about $600^{\circ}C$, while the other fuels showed $400{\sim}465^{\circ}C$. For flame duration time, lubricants had over 300 seconds, but fuels had less than 300 seconds except high sulfur diesel(350 seconds). Total heat release rate ranged $287{\sim}462kW/m^2$ for lubricants and gasoline showed the highest total heat release rate, $652kW/m^2$.

• Journal of the Korean Ceramic Society
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• v.38 no.4
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• pp.307-307
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• 2001

Combustion process with citrate was used to produce the LiMn$_2$O$_4$powder. Precursors are pre-ignited in open air followed by post-heating in the range from $600^{\circ}C$ to 80$0^{\circ}C$ for 4h. With varying the molar ratio (R) of ethylene glycol (EG) to citric acid (CA) from 0 to 4, the effect of EG content on powder characteristics is evaluated. Vacuum drying promote the auto-ignition at room temperature. With small addition of EG metal ion was selectively segregated with organic substances and undesired lithium evaporation occurred during post-heating. LiMn$_2$O$_4$phase which is produced by combustion reaction was decomposed back to Mn$_3$O$_4$because the reaction temperature was higher than 95$0^{\circ}C$. With increasing EG content, the homogeneity of LiMn$_2$O$_4$powder increased and specific surface area increased. And lithium evaporation during vacuum drying and/or ignition also increased.

• International Journal of Automotive Technology
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• v.8 no.3
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• pp.275-281
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• 2007

GTL (Gas To Liquid) has the potential to be used in diesel engines as a clean alternative fuel due to advantages in emission reduction, particularly soot reduction. Since the physical properties of GTL fuel differ from those of diesel fuel to some extent, studying how this difference in characteristics of GTL and diesel fuels affects spray and combustion in diesel engines is important. In this study, visual investigation of sprays and flames from GTL and diesel fuels in a vessel simulating diesel combustion was implemented. The effects of various parameters and conditions, such as injection pressure, chamber temperature and pilot injection on liquid-phase fuel length and auto-ignition delay were investigated. It was determined that GTL has a somewhat shorter liquid-phase fuel length, which explains why there is less contact between the fuel liquid-phase and flame for GTL fuel compared to diesel fuel.

• Journal of the Korean Society of Combustion
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• v.15 no.4
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• pp.1-8
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• 2010

Mild combustion is considered as a promising combustion technology for energy saving and low emission of combustion product gases. In this paper, the controllability of reaction region in mild combustion is examined by using co-axial air nozzle. For this purpose, numerical approach is carried out. Propane is considered for fuel and air is considered for oxidizer and the temperature of air is assumed 900K slightly higher than auto ignition temperature of propane. But unlike main air, the atmospheric condition of co-axial air is considered. Various cases are conducted to verify the characteristics of Co-Axial air burner configuration. The use of coaxial air can affect reaction region. These modification help the mixing between fuel and oxidizer. Then, reaction region is reduced compare to normal burner configuration. The enhancement of main air momentum also affects on temperature uniformity and reaction region. The eddy dissipation concept turbulence/chemistry interaction model is used with two step of global chemical reaction model.

• Journal of ILASS-Korea
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• v.13 no.2
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• pp.91-98
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• 2008

In the present study, in order to understand the overall spray combustion characteristics of DME fuel as well as to identify the distinctive differences of DME combustion processes against the conventional hydrocarbon liquid fuels, the sequence of the comparative analysis have been systematically made for DME and n-heptane liquid fuels. To realistically represent the physical processes involved in the spray combustion, this studyemploys the hybrid breakup model, the stochastic droplet tracking model, collision model, high-pressure evaporation model, and transient flamelet model with detailed chemistry. Based on numerical results, the detailed discussions are made in terms of the autoignition, spray combustion processes, flame structure, and turbulence-chemistry interaction in the n-heptane and DME fueled spray combustion processes.

• Fire Science and Engineering
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• v.27 no.2
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• pp.11-17
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• 2013

For the safe handling of n-undecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-undecane were calculated. The lower flash points of n-undecane by using closed-cup tester were measured $59^{\circ}C$ and $67^{\circ}C$. The lower flash points of n-undecane by using open cup tester were measured $67^{\circ}C$ and $72^{\circ}C$, respectively. The fire point of n-undecane by using Cleveland open cup tester was measured $74^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-undecane. The experimental AIT of n-undecane was $198^{\circ}C$. The estimated lower and upper explosion limit by using measured lower flash point $59^{\circ}C$ and upper flash point $83^{\circ}C$ for n-undecane were 0.65 Vol.% and 2.12 Vol.%.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.1
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• pp.155-164
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• 1996

Dual-fuel engines are being researched with emphasis on the possible types of natural gas supply systems. Hence, a three-dimensional combustion model by using finite volume method was developed to provide a fundamental understanding of the auto-ignition of pilot distillate and subsequent burning of natural gas, when the natural gas as well as the distillate was directly injected into a quiescent diesel engine like combustion bomb tests and the numerical results were investigated for the mixed combustion phenomena. With high-pressure natural gas injection, it was found that the gaseous fuel injection characteristics had to be well harmonised with that of the pilot distillate. For better combustion efficiency, however, further researches are required for the optimisation of injection system in the existence of air motion.

• Journal of the Korean Institute of Gas
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• v.14 no.4
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• pp.24-30
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• 2010

An accurate information of the autoignition temperature(AIT) is important in developing appropriate prevention and control measures in industrial fire. This study measured the AITs of trichlorosliane and dichlosilane(DCS)-trichlorosliane(TCS) mixtures by using ASTM E659-78 apparatus. The experiment AITs of trichlorosliane, TCS(90wt%)-DCS(10wt%) and the TCS(70wt%)-DCS(30wt%) were $225^{\circ}C,\;250^{\circ}C\;and\;236^{\circ}C$, respectively.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.371-374
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• 2011

High-resolution numerical study is carried out to investigate the flame stability of the turbulent supersonic combustion in a Dual-Combustion Ramjet (DCR). The auto-ignition in a shear layer between hydrogen/carbon-monoxide syngas and air was studied at elevated enthalpy condition. Comparison of a constant area combustor and a combustor with a small divergence angle shows that the supersonic combustion has a characteristics of the lifted flame and its stability is influenced significantly by the compressibility.