• Title/Summary/Keyword: Au

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Fabrication of CO2 Gas Sensors Using Graphene Decorated Au Nanoparticles and Their Characteristics (Au 나노입자가 코팅된 그래핀 기반 CO2 가스센서의 제작과 그 특성)

  • Bae, Sang-Jin;Kim, Kang-San;Chung, Gwiy-Sang
    • Journal of Sensor Science and Technology
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    • v.22 no.3
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    • pp.197-201
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    • 2013
  • This paper describes the fabrication and characterization of graphene based carbon dioxide ($CO_2$) gas sensors. Graphene was synthesized by thermal decomposition of SiC. The resistivity $CO_2$ gas sensors were fabricated by pure graphene and graphene decorated Au nanoparticles (NPs). The Au NPs with size of 10 nm were decorated on graphene. Au electrode deposited on the graphene showed Ohmic contact and the sensors resistance changed following to various $CO_2$ concentrations. Resulting in resistance sensor using pure graphene can detect minimum of 100 ppm $CO_2$ concentration at $50^{\circ}C$, whereas Au/graphene can detect minimum 2 ppm $CO_2$ concentration at same at $50^{\circ}C$. Moreover, Au NPs catalyst improved the sensitivity of the graphene based $CO_2$ sensors. The responses of pure graphene and Au/graphene are 0.04% and 0.24%, respectively, at $50^{\circ}C$ with 500 ppm $CO_2$ concentration. The optimum working temperature of $CO_2$ sensors is at $75^{\circ}C$.

Pharmacological properties of the reversible inhibitor of the gastric $H^+/K^+$ ATPase, AU-164

  • Kim, Hyo-Jung;Yum, Eul-Kgun;Choi, Jong-Kwon;Cheon, Hyae-Gyeong
    • Biomolecules & Therapeutics
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    • v.5 no.3
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    • pp.228-232
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    • 1997
  • AU-164 was synthesized as a reversible gastric $H^+/K^+$ ATPase inhibitor, and its effects were tested in various systems. AU-164 inhibited rabbit gastric $H^+/K^+$ ATPase with an $IC_{50}$/ of 9 $\mu$M. On the other hand, AU-164 was a weak inhibitor for dog kidney $Na^+/K^+$ ATPasc, indicating the selectivity for gastric $H^+/K^+$ ATPase. The reversible property of the AU-164-induced inhibition of $H^+/K^+$ ATPase was confirmed by filtering the inhibition mixture through Sephadex G-25M column. In vivo basal acid secretion was also inhibited by AU-164 under the pylorus ligation of Sprague-Dawley rats. In addition, AU-164 protected dose dependently gastric lesion induced by ethanol in rats. The $ED_{50}$ value of 62 mg/kg p.o was estimated. These results suggest that AU-164 is a potent, selective and reversible gastric $H^+/K^+$ ATPase inhibitor, and that AU-164 has a potential use for the clinical therapeutics of peptic ulcer disease.

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Properties of the Dye Sensitized Solar Cell with Localized Surface Plasmon Resonance Inducing Au Nano Thin Films

  • Noh, Yunyoung;Kim, Kwangbae;Choi, Minkyoung;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.26 no.8
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    • pp.417-421
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    • 2016
  • We improve the energy conversion efficiency (ECE) of a dye sensitized solar cell (DSSC) by preparing a working electrode (WE) with localized surface plasmon resonance (LSPR) by inducing Au thin films with thickness of 0.0 to 5.0 nm, deposited via sputtering. Field emission scanning electron microscopy and atomic force microscopy were used to characterize the microstructure of the blocking layer (BL) of the Au thin films. Micro-Raman measurement was employed to confirm the LSPR effect, and a solar simulator and potentiostat were used to evaluate the photovoltaic properties, including the impedance and the I-V of the DSSC of the Au thin films. The results of the microstructural analysis confirmed that nano-sized Au agglomerates were present at certain thicknesses. The photovoltaic results show that the ECE reached a value of 5.34% with a 1-nm thick-Au thin film compared to the value of 5.15 % without the Au thin film. This improvement was a result of the increase in the LSPR of the $TiO_2$ layer that resulted from the Au thin film coating. Our results imply that the ECE of a DSSC may be improved by coating with a proper thickness of Au thin film on the BL.

A Comparative Study of The Electrical Properties of Arachidic Acid L-B Film in the Al/LB/Al and Au/LB/Au Electrode Structures (Al/LB/Al, Au/LB/AU 전극구조에서 Arachidic Acid L-B막의 전기적 특성에 관한 비교 연구)

  • 오세중;김형석;이창희;김태완;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.11a
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    • pp.112-115
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    • 1993
  • We have studied a property of arachidic acid Langmuir-Blodgett films at room temperature with two different electrodes ; Al/LB/Al and Au/LB/Au. Since a natural oxide layer is formed on top of the Al electrode, the appropriate structure of AL/LB/Al is Al/Al$_2$O$_3$/LB/Al. To obtain a property of Pure LB film, Aua/LB/Au structure was made. In Al/Al$_2$O$_3$/LB/Al structure, a conductivity of 3.7${\times}$10$\^$-14/ S/cm was obtained by using current-voltage(I-V) characteristics. In Au/LB/AU structure, however, I-V curve was not able to be measured because of short current even in 51 layers of the LB film. A status of defects in the film was confirmed by copper decoration method. We have clearly seen a rather big difference of defect in those two above structures.

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Memory characteristics of p-type Si nanowire - Au nanoparticles nano floating gate memory device (P형 실리콘 나노선과 Au 나노입자를 이용한 나노플로팅게이트 메모리소자의 전기적 특성 분석)

  • Yoon, Chang-Joon;Yeom, Dong-Hyuk;Kang, Jeong-Min;Jeong, Dong-Young;Kim, Sang-Sig
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1226-1227
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    • 2008
  • In this study, a single p-type Si nanowire - Au nanoparticles nano floating gate memory (NFGM) device is successfully fabricated and characterized their memory effects by comparison of electrical characteristics of p-type Si nanowire-based field effect transistor (FET) devices with Au nanoparticles embedded in the $Al_2O_3$ gate materials and without the Au nanoparticles. Drain current versus gate voltage ($I_{DS}-V_{GS}$) characteristics of a single p-type Si nanowire - Au nanoparticle NFGM device show counterclockwise hysteresis loops with the threshold voltage shift of ${\Delta}V_{th}$= 3.0 V. However, p-type Si nanowire based top-gate device without Au nanoparticles does not exhibit a threshold voltage shift. This behavior is ascribed to the presence of the Au nanoparticles, and is indicative of the trapping and emission of electrons in the Au nanoparticles.

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Au 전극을 적용한 방사선 영상 검출기의 전기적 특성 평가

  • Song, Yong-Geun;O, Gyeong-Min;Kim, Seong-Heon;Kim, Ji-Na;No, Seong-Jin;Heo, Seung-Uk;Nam, Sang-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.365-365
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    • 2012
  • 본 연구에서는 X-ray 영상을 얻기 위한 검출기 중 직접 검출방식에 쓰이고 있는 광도전체(Photoconductor)의 전극으로 Au를 사용하여 전기적인 특성을 파악하였다. Au는 유기물에 대한 반응이 적고 전기 전도도가 좋은 물질로서 투명전극으로 많이 쓰이고 있는 인듐 주석 산화물(ITO)을 대체할 수 있는 물질로 각광받고 있다. 우선 시편 제작을 위해 투명한 기판(Corning Glass, 0.7t)위에 하부전극으로 Au를 $3cm{\times}3cm$의 크기로 Physical Vapor Deposition(PVD) 방식을 이용하여 증착하였다. 이 때 챔버 내 저진공은 Rotary Pump를 이용하여 $3.9{\times}10-2Torr$ 이하를 유지하고 고진공은 Diffusion Pump를 이용하여 $5.3{\times}10-5Torr$ 이하를 유지하였다. 완성된 하부전극 위에 광도전체인 $HgI_2$를 폴리머 물질에 교반하여 메탈 폴리머 결합을 가진 Paste를 제조하고 이 Paste를 Screen Printing Method를 이용하여 증착 후 건조하였다. 마지막으로 시편위에 상부전극을 하부전극과 같은 조건으로 증착함으로서 시편을 완성한다. 상하부 전극으로 쓰이는 Au의 증착 조건을 변화시키면서 그에 따른 시편의 전기적인 특성 변화를 관찰하였다. 그 결과, Au의 증착온도와 질량에 따라 특성이 변화함을 알 수 있었다. 본 연구의 결과를 통해 디지털 방사선 검출기에서 Au 전극의 적용 가능성을 확인하였으며, 추후 Au 증착 조건의 최적화를 통해 방사선 검출기의 효율 향상을 위한 연구를 하고자 한다.

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Enhancing photoluminescence of Au - TiO2 nanoparticles using Drude model

  • Dang, Diem Thi-Xuan;Vu, Thi Hanh Thu
    • Journal of IKEEE
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    • v.21 no.3
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    • pp.288-296
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    • 2017
  • The enhancement of photoluminescence of Au-$TiO_2$ nanoparticles by surface plasmon resonance has been studied extensively by experiment in recent years. For the purpose of optimizing the photoluminescence property of Au-$TiO_2$ nanoparticles, the manufacturing parameters related to the Au nanoparticles and $TiO_2$ nanoparticles need to be considered. In this paper, Drude model and Maier's effective volume method are used to analyze the variation of the metal nanoparticle radius, separation between metal nanoparticle and dielectric molecule, and total absorption cross-section with original radiative efficiency on the photoluminescence property of Au-$TiO_2$ nanoparticles. The results show that to obtain the optimized enhancement factor for photoluminescence process, the size of Au nanoparticle is about 13 - 20 nm, the separation between Au nanoparticle and $TiO_2$ molecule is about 5 -15 nm, the total absorption cross-section of $TiO_2$ molecules is about $1-100nm^2$ and the original radiative efficiency of $TiO_2$ molecule is weak about 0.001- 0.1. With these fabrication parameters, the photoluminescence property of Au-$TiO_2$ nanoparticles can be enhanced several thousand times compared to traditional $TiO_2$ nanoparticles.

Effect of Au Additive on The Bi Site in The Bi2-δAuδSr2CaCu2O8+δ (x=0~0.15) Superconductors (Bi2-δAuδSr2CaCu2O8+δ(x = 0~0.15) 산화물고온초전도체의 Bi 위치에 Au 혼합효과)

  • 이민수;최봉수;이정화;송기영;정성혜;홍병유
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.4
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    • pp.308-313
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    • 2002
  • Samples with the norminal composition, $Bi_{2-x}Au_xSr_2CaCu_2O_{8+\delta}$ (x = 0, 0.05. 0.1, 0.15) were prepared by the solid-state reaction method. The superconducting properties, x-ray powder diffraction patterns, critical temperature and microstructure of surface were measured the samples. x-ray patterns show the single phase(2212) nature of the samples. But, the peaks of 2201 at $2\theta=30^{\circ}$ and Au peak at $2\theta=38.31^{\circ}$ are observed in the Au additive samples. The grain sire are enlarged with the increase of x. As the result of enlargement the grain size, the onset and offset critical temperature($T_c^{on}$,$T_c^{zero}$) increased with increase of x.

The Electrical and Radiation Detection Properties of $Au/Cd_{1-x}Zn_x/Te(x=20%)/Au$ Structure ($Au/Cd_{1-x}Zn_x/Te(x=20%)/Au$ 구조의 전기적 특성 및 방사선 탐지 특성)

  • 최명진;왕진석
    • Electrical & Electronic Materials
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    • v.10 no.1
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    • pp.39-44
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    • 1997
  • Bulk type radiation detector of Au/Cd$_{1-x}$ Zn$_{x}$Te(x=20%)/Au structure using Cd$_{1-x}$ Zn$_{x}$Te(x=20%) wafer(3x4xl mm$^{3}$) grown by high pressure Bridgman method has been developed. We etched wafer surfaces with 2% Br-methanol solution and coated gold thin film on the surfaces by electroless deposition method for 5 min. in 49/o HAuCI$_{3}$ 4H20 solution. Initial etch rates of Cd, Zn and Te were 46%, 12% and 42% respectively. After etched, the surface of wafer was slightly revealed to Te rich condition. The leakage current was increased with etch time, but it didn't exceed 3nA at 50volt. The thickness of Au film was about 100nm by Rutherford Backscattering Spectroscopy(RBS). The resolution were 6.7% for 22.1 keV photon from 109 $^{109}$ Cd and 8.2% for 59.5 keV photon from $^{241}$ Am. The radiation detector such as Au/Cd$_{1-x}$ Zn$_{x}$Te(x=20%)/Au structure was more effective to monitor the low energy gamma radiation.iation.

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Anti-Ulcer Activity of Newly Synthesized Acylquinoline Derivatives

  • Cheon, Hyae-Gyeong;Kim, Hyun-Jung;Mo, Hye-Kyoung;Shin, En-Joo;Lee, Yeon-Hee
    • Archives of Pharmacal Research
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    • v.22 no.2
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    • pp.137-142
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    • 1999
  • Anti-ulcer activity of newly synthesized acylquinoline derivatives was investigated. For the in vitro screening, the effects of compounds on gastric $H^{+}/K^{+}$ ATPase isolated from hog and rabbit were examined. Among them, AU-090, AU-091, AU-254, AU-413 and AU-466 exhibited good in vitro activity on both enzymes. To correlate the in vitro activity with in vivo action, the effects of the compounds on the basal gastric acid secretion were studied. Some derivatives showed considerable anti-secretory activities, and AU-413 was selected for further studies. AU-413 protected gastric damage induced by either ethanol or NaOH dose dependently when given orally. $ED_{50}$ values of 12 mg/kg, p.o. (ethanol) and 41 mg/kg, p.o. (NaOH) were obtained. In addition, histamine-stimulated gastric secretion was reduced upon AU-413 administration. Taken together, newly synthesized acylquinoline derivatives, especially AU-413, is worthy of further investigation to be developed as an anti-ulcer agent.

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