• 제목/요약/키워드: Atomic structure

검색결과 1,405건 처리시간 0.025초

Characterization of uranium species in molten salt : An application of synchrotron-based XAFS spectroscopy

  • Cho, Young-Hwan;Choi, In-Kyu;Kim, Won-Ho
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 2002년도 추계학술발표회요약집
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    • pp.319.2-319
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    • 2002
  • Synchrotron-based X-ray absorption spectroscopy has been applied to determine the changes in bulk oxidation state of uranium oxides in molten salt. From an analysis of XANES data, one can determine the cahnges in bulk oxidation-state of U compounds in salts(LiCl/KCl). XAFS spectroscpy is a powerful tool for probing the changes in valence state and structure of uranium compounds in colten salt as well as in noncrystalline form and doped in other matrices.

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Atomic Force Microscopy of Asymmetric Membranes from Turtle Erythrocytes

  • Tian, Yongmei;Cai, Mingjun;Xu, Haijiao;Ding, Bohua;Hao, Xian;Jiang, Junguang;Sun, Yingchun;Wang, Hongda
    • Molecules and Cells
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    • 제37권8호
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    • pp.592-597
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    • 2014
  • The cell membrane provides critical cellular functions that rely on its elaborate structure and organization. The structure of turtle membranes is an important part of an ongoing study of erythrocyte membranes. Using a combination of atomic force microscopy and single-molecule force spectroscopy, we characterized the turtle erythrocyte membrane structure with molecular resolution in a quasi-native state. High-resolution images both leaflets of turtle erythrocyte membranes revealed a smooth outer membrane leaflet and a protein covered inner membrane leaflet. This asymmetry was verified by single-molecule force spectroscopy, which detects numerous exposed amino groups of membrane proteins in the inner membrane leaflet but much fewer in the outer leaflet. The asymmetric membrane structure of turtle erythrocytes is consistent with the semi-mosaic model of human, chicken and fish erythrocyte membrane structure, making the semi-mosaic model more widely applicable. From the perspective of biological evolution, this result may support the universality of the semi-mosaic model.

Implementation of a Radiation-hardened I-gate n-MOSFET and Analysis of its TID(Total Ionizing Dose) Effects

  • Lee, Min-Woong;Lee, Nam-Ho;Jeong, Sang-Hun;Kim, Sung-Mi;Cho, Seong-Ik
    • Journal of Electrical Engineering and Technology
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    • 제12권4호
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    • pp.1619-1626
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    • 2017
  • Electronic components that are used in high-level radiation environment require a semiconductor device having a radiation-hardened characteristic. In this paper, we proposed a radiation-hardened I-gate n-MOSFET (n-type Metal Oxide Semiconductors Field Effect Transistors) using a layout modification technique only. The proposed I-gate n-MOSFET structure is modified as an I-shaped gate poly in order to mitigate a radiation-induced leakage current in the standard n-MOSFET structure. For verification of its radiation-hardened characteristic, the M&S (Modeling and Simulation) of the 3D (3-Dimension) structure is performed by TCAD (Technology Computer Aided Design) tool. In addition, we carried out an evaluation test using a $Co^{60}$ gamma-ray source of 10kGy(Si)/h. As a result, we have confirmed the radiation-hardened level up to a total ionizing dose of 20kGy(Si).

Creep-Fatigue Crack Growth Behavior of a Structure with Crack Like Defects at the Welds

  • Lee, Hyeong-Yeon;Kim, Seok-Hoon;Lee, Jae-Han;Kim, Byung-Ho
    • Journal of Mechanical Science and Technology
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    • 제20권12호
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    • pp.2136-2146
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    • 2006
  • A study on a creep-fatigue crack growth behavior has been carried out for a cylindrical structure with weldments by using a structural test and an evaluation according to the assessment procedures. The creep-fatigue crack growth behavior following the creep-fatigue crack initiation has been assessed by using the French A16 procedure and the conservatism for the present structural test has been examined. The structural specimen is a welded cylindrical shell made of 316 L stainless steel (SS) for one half of the cylinder and 304 SS for the other half. In the creep-fatigue test, the hold time under a tensile load which produces the primary nominal stress of 45 MPa was one hour at $600^{\circ}C$ and creep-fatigue loads of 600 cycles were applied. The evaluation results for the creep-fatigue crack propagation were compared with those of the observed images from the structural test. The assessment results for the creep-fatigue crack behavior according to the French Al6 procedure showed that the Al6 is overly conservative for the creep-fatigue crack propagation in the present case with a short hold time of one hour.

A Multi-Dimensional Thermal-Hydraulic System Analysis Code, MARS 1.3.1

  • Jeong, Jae-Jun;Ha, Kwi-Seok;Chung, Bub-Dong;Lee, Won-Jae
    • Nuclear Engineering and Technology
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    • 제31권3호
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    • pp.344-363
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    • 1999
  • A multi-dimensional thermal-hydraulic system analysis code, MARS 1.3.1, has been developed in order to have the realistic analysis capability of two-phase thermal-hydraulic transients for pressurized water reactor (PWR) plants. As the backbones for the MARS code, the RELAP5/MOD3.2.1.2 and COBRA-TF codes were adopted in order to take advantages of the very general, versatile features of RELAP5 and the realistic three-dimensional hydrodynamic module of COBRA-TF. In the MARS code, all the functional modules of the two codes were unified into a single code first. Then, the source codes were converted into the standard Fortran 90, and then they were restructured using a modular data structure based on "derived type variables" and a new "dynamic memory allocation" scheme. In addition, the Windows features were implemented to improve user friendliness. This paper presents the developmental work of the MARS version 1.3.1 including the hydrodynamic model unification, the heat structure coupling, the code restructuring and modernization, and their verifications.their verifications.

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Ultrasonic ranging technique for obstacle monitoring above reactor core in prototype generation IV sodium-cooled fast reactor

  • Kim, Hoe-Woong;Joo, Young-Sang;Park, Sang-Jin;Kim, Sung-Kyun
    • Nuclear Engineering and Technology
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    • 제52권4호
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    • pp.776-783
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    • 2020
  • As the refueling of a sodium-cooled fast reactor is conducted by rotating part of the reactor head without opening it, the monitoring of existing obstacles that can disturb the rotation of the reactor head is one of the most important issues. This paper deals with the ultrasonic ranging technique that directly monitors the existence of possible obstacles located in a lateral gap between the upper internal structure and the reactor core in a prototype generation IV sodium-cooled fast reactor (PGSFR). A 10 m long plate-type ultrasonic waveguide sensor, whose feasibility has been successfully demonstrated through preliminary tests, was employed for the ultrasonic ranging technique. The design of the sensor's wave radiating section was modified to improve the radiation performance, and the radiated field was investigated through beam profile measurements. A test facility simulating the lower part of the upper internal structure and the upper part of the reactor core with the same shapes and sizes as those in the PGSFR was newly constructed. Several under-water performance tests were then carried out at room temperature to investigate the applicability of the developed ranging technique using the plate-type ultrasonic waveguide sensor with the actual geometry of the PGSFR's internal structures.

Synthesis of Metal and Ceramic Magnetic Nanoparticles by Levitational Gas Condensation (LGC)

  • Uhm, Y.R.;Lee, H.M.;Lee, G.J.;Rhee, C.K.
    • Journal of Magnetics
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    • 제14권2호
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    • pp.75-79
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    • 2009
  • Nickel (Ni) and ferrite ($Fe_3O_4$, $NiFe_2O_4$) nanoparticles were synthesized by LGC using both wire feeding (WF) and micron powder feeding (MPF) systems. Phase evolution and magnetic properties were then investigated. The Ni nanopowder included magnetic-ordered phases. The LGC synthesis yielded spherical particles with large coercivity while the abnormal initial magnetization curve for Ni indicated a non-collinear magnetic structure between the core and surface layer of the particles. Since the XRD pattern cannot actually distinguish between magnetite ($Fe_3O_4$) and maghemite (${\gamma}-Fe_2O_3$) as they have a spinel type structure, the phase of the iron oxide in the samples was unveiled by $M{\ddot{o}}ssbauer$ spectroscopy. The synthesized Ni-ferrite consisted of single domain particles, including an unusual ionic state. The synthesized nanopowder bore an active surface due to the defects that affected abnormal magnetic properties.

Sorption of I and Se onto Green Rusts with Different Interlayer Anions, GR(CO32-) AND GR(Cl-)

  • Min, J.H.;Baik, M.H.;Lee, J.K.;Jeong, J.T.
    • Journal of Nuclear Fuel Cycle and Waste Technology
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    • 제1권1호
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    • pp.57-63
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    • 2013
  • Natural green rust (GR) can retard the migration of anions through geological media because it has a Layer Double Hydroxyl (LDH) structure with a positive charge. In this study, the sorption behaviors of anions such as selenite ($Se(IV)O{_3}^{2-}$), selenate ($Se(VI)O{_4}^{2-}$), and iodide ($I^-$) onto green rusts with different structures, i.e., GR($Cl^-$) and GR($CO{_3}^{2-}$), were investigated by conducting batch sorption experiments in an anoxic condition. Experimental results showed that selenite was mostly sorbed onto GR($CO{_3}^{2-}$) and then partly reduced to metal selenium, Se(0). However, little selenate and iodide was sorbed onto GR($CO{_3}^{2-}$) while some iodide was sorbed onto GR($Cl^-$). It is presumed from the experimental results that the major sorption mechanism of $SeO{_3}^{2-}$ and $I^-$ onto green rusts is the anion exchange reaction with the anions existing in the interlayer of the rusts. Green rust, therefore, can play an important role in the retardation of anions migrating through deep geological environments owing to its LDH structure with a high anion exchange capacity.