• 제목/요약/키워드: Atomic structure

검색결과 1,405건 처리시간 0.061초

Crosslinking of Electrospun Poly (VDF-co-HFP) Nanofibrous Membranes by Gamma-ray Irradiation

  • Kim, Yun-Hye;Lim, Youn-Mook;Choi, Jae-Hak;An, Sung-Jun;Park, Jong-Seok;Nho, Young-Chang
    • 방사선산업학회지
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    • 제2권3호
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    • pp.105-110
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    • 2008
  • Poly (VDF-co-HFP)/PEGDMA nanofibrous membranes (NFMs) have been prepared by an electrospinning process. Since electrospun NFMs have a nanoporous structure, they have a potential application for a polymer electrolyte or a separator. Poly (VDF-co-HFP) is a polymer electrolyte binder. In order to improve their mechanical properties, poly (VDF-co-HFP)/PEGDMA NFMs were crosslinked by a gamma-ray irradiation. Then the crosslinked NFMs were characterized through an electrolyte uptake, IR structural analysis, and SEM morphological investigation.

Molecular Weight Control of Chitosan Using Gamma Ray and Electron Beam Irradiation

  • Kim, Hyun Bin;Lee, Young Joo;Oh, Seung Hwan;Kang, Phil Hyun;Jeun, Joon Pyo
    • 방사선산업학회지
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    • 제7권1호
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    • pp.51-54
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    • 2013
  • Chitosan is a useful natural polymer material in many application fields such as biomaterials, water-treatment, agriculture, medication, and food science. However, the poor solubility limits its application. In this study, the effects of radiation on chitosan were investigated using gamma ray and electron beam irradiation. The chemical structure and molecular weight analysis show similar degradation effects of chitosan powder in both gamma ray and electron beam irradiation. However, the radiation irradiated chitosan in $H_2O$ has a lower molecular weight, since the hydroxyl radicals attack the glycosidic bonds. This effect is more clearly shown in the electron beam irradiation results.

Directional Wigner-Ville Distribution and Its Application for Rotating- Machinery Condition Monitoring

  • Kim, Dong-Wan;Ha, Jae-Hong;Shin, Hae-Gon;Lee, Yoon-Hee;Kim, Young-Baik
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(1)
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    • pp.587-593
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    • 1996
  • Vibration analysis is one of the most powerful tools available for the detection and isolation of incipient faults in mechanical systems. The methods of vibration analysis in use today and under continuous study are broad band vibration monitoring, time domain analysis, and frequency domain analysis. In recent years, great interest has been generated concerning the use of time-frequency representation and its application for a machinery diagnostics and condition monitoring system. The objective of the research described in this paper was to develop a new diagnostic tool for the rotating machinery. This paper introduces a new time-frequency representation, Directional Wigner-Ville Distribution, which analyses the time- frequency structure of the rotating machinery vibration.

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Heat transfer characteristics of redan structure in large-scale test facility STELLA-2

  • Yoon, Jung;Lee, Jewhan;Kim, Hyungmo;Lee, Yong-Bum;Eoh, Jaehyuk
    • Nuclear Engineering and Technology
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    • 제53권4호
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    • pp.1109-1118
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    • 2021
  • The construction of STELLA-2 facility is on-going to demonstrate the safety system of PGSFR and to provide comprehensive understanding of transient behavior under DBEs. Considering that most events are single-phase natural circulation flow with slow transient, STELLA-2 was designed with reduced-height of 1/5 length scale. The ratio of volume to surface area in the vessel can relatively increase resulting in excessive heat transfer. Therefore, a steady-state thermal-hydraulic analysis was performed and the effect of design change to reduce the heat transfer through redan was investigated. The heat transfer through single wall redan in STELLA-2 was 3% of the core power, comparable to 1% of the core power in PGSFR. By applying the insulated redan, about 70% of decrease effect was observed. The effect on transient behavior was also evaluated. The conclusion of this study was directly applied to the STELLA-2 design and the modified version is under construction.

Radiative Transfer in Highly Thick Media through Rayleigh and Raman Scattering with Atomic Hydrogen

  • Chang, Seok-Jun
    • 천문학회보
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    • 제46권2호
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    • pp.40.1-40.1
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    • 2021
  • Hydrogen is the most abundant element in the universe, which is, in the cosmological context, attributed to its simplest structure consisting of a proton and an electron. Hydrogen interacts with an electromagnetic wave in astrophysical environments. Rayleigh scattering refers to elastic scattering, where the frequencies of the incident and scattered photons are the same. Rayleigh and resonance scattering is a critical role study Lyman Alpha objects in the early universe. The scattering causes the frequency and spatial diffusion of Lyα. In the case of Raman scattering, the energies of the incident and scattered photons are different. The photons near Lyβ convert to the optical photons near Hα through Raman scattering. The photon scattered by atomic hydrogen can carry both of the properties of the H I region and the emission region. I adopt a Monte Carlo approach to investigate the formation of the various spectral line features through Rayleigh and Raman scattering in highly thick media of atomic hydrogen. In this thesis, I present my works on radiative transfer involving the scattering processes between far UV photon and atomic hydrogen. I introduce scattering processes with atomic hydrogen and the spectral, spatial, and polarized information originating from the scattering.

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Recent Advances in Electron Crystallography

  • Chung, Jeong Min;Lee, Sangmin;Jung, Hyun Suk
    • Applied Microscopy
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    • 제47권3호
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    • pp.160-164
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    • 2017
  • Electron crystallography has been used as the one of powerful tool for studying the structure of biological macromolecules at high resolution which is sufficient to provide details of intramolecular and intermolecular interactions at near-atomic level. Previously it commonly uses two-dimensional crystals that are periodic arrangement of biological molecules, however recent studies reported a novel technical approach to electron crystallography of three-dimensional crystals, called micro electron-diffraction (MicroED) which involves placing the irregular and small sized protein crystals in a transmission electron microscope to determine the atomic structure. In here, we review the advances in electron crystallography techniques with several recent studies. Furthermore, we discuss the future direction of this structural approach.

원자간격 현미경의 캔틸레버의 정량적 특성평가를 위한 계측 시스템 개발 (Development of Measurement System for Quantitative Measurement of Cantilever in Atomic Force Microscopy)

  • 권현규;남기호
    • 한국기계가공학회지
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    • 제6권2호
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    • pp.22-27
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    • 2007
  • In this study, the two methods of stiffness measurement(Spring constant) of cantilever were proposed for quantitative measurement in Atomic Force Microscopy(AFM). As the 1st method for the measurement of stiffness, the probe method, which is used in the measurement of the semiconductor mechanical and electrical properties, was applied to the measurement of the cantilever. Experiments by the probe method were performed finding the resistance value of cantilever. As the results, the resistance was measured differently along with the dimension and the thickness of cantilever that determined the stiffness(spring constant) of the lever. As the 2nd method, the vibration characteristics(Dunkerley expression) is used to obtain the stiffness of the complex structure which is combined by AFM cantilever and the standard cantilever. We measured the resonant frequency from the complex structure using the micro stages and stereo microscope. As the results, we confirmed that the vibration characteristics(Dunkerley expression) is effected the micro complex structure of AFM cantilever.

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Advanced Cryo-Electron Microscopy Technology: High Resolution Structure of Macromolecules

  • Chung, Jeong Min;Jung, Hyun Suk
    • Applied Microscopy
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    • 제46권1호
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    • pp.1-5
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    • 2016
  • Recent cryo-electron microscopy (EM) studies reported the structure of various types of proteins at high resolution which is sufficient to visualize the intermolecular interaction at near atomic level. There are two main factors that cause the advances in cryo-EM; the development of image processing techniques, such as single particle analysis, and the improved electron detection devices. Although the atomic structures of small and asymmetric proteins are not yet to be determined by cryo-EM, this striking improvement implies the bright prospect of the application in biomedical studies. This study reviews the recently published studies reported high resolution structures using improved imaging analysis techniques and electron detectors. Furthermore, we will discuss about the future aspects of cryo-EM application.

Hydrogen isotope exchange behavior of protonated lithium metal compounds

  • Park, Chan Woo;Kim, Sung-Wook;Sihn, Youngho;Yang, Hee-Man;Kim, Ilgook;Lee, Kwang Se;Roh, Changhyun;Yoon, In-Ho
    • Nuclear Engineering and Technology
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    • 제53권8호
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    • pp.2570-2575
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    • 2021
  • The exchange behaviors of hydrogen isotopes between protonated lithium metal compounds and deuterated water or tritiated water were investigated. The various protonated lithium metal compounds were prepared by acid treatment of lithium metal compounds with different crystal structures and metal compositions. The protonated lithium metal compounds could more effectively reduce the deuterium concentration in water compared with the corresponding pristine lithium metal compounds. The H+ in the protonated lithium metal compounds was speculated to be more readily exchangeable with hydrons in the aqueous solution compared with Li+ in the pristine lithium metal compounds, and the exchanged heavier isotopes were speculated to be more stably retained in the crystal structure compared with the light protons. When the tritiated water (157.7 kBq/kg) was reacted with the protonated lithium metal compounds, the protonated lithium manganese nickel cobalt oxide was found to adsorb and retain twice as much tritium (163.9 Bq/g) as the protonated lithium manganese oxide (69.9 Bq/g) and the protonated lithium cobalt oxide (75.1 Bq/g) in the equilibrium state.

구조물과 부계통간의 연계방법에 따른 지진응답 분석 (Analysis of Seismic Response due to the Dynamic Coupling Between a Primary Structure and Secondary System)

  • 정광섭;곽신영;최인길;임승현
    • 한국지진공학회논문집
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    • 제24권2호
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    • pp.87-93
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    • 2020
  • Seismic responses due to the dynamic coupling between a primary structure and secondary system connected to a structure are analyzed in this study. The seismic responses are compared based on dynamic coupling criteria and according to the error level in the natural frequency, with the recent criteria being reliant on the error level in the spectral displacement response. The acceleration responses and relative displacement responses of a primary structure and a secondary system for a coupled model and two different decoupled models of two degrees-of-freedom system are calculated by means of the time integration method. Errors in seismic responses of the uncoupled models are reduced with the recent criteria. As the natural frequency of the secondary system increases, error in the natural frequency decreases, but seismic responses of uncoupled models can be underestimated compared to that of coupled model. Results in this paper can help determine dynamic coupling and predict uncoupled models' response conservatism.