• 제목/요약/키워드: Atomic parameters

검색결과 838건 처리시간 0.023초

AlGaAs합금의 Al 도핑농도에 대한 효과 (Effect on Al Concentration of AlGaAs Ternary Alloy)

  • 강병섭
    • 반도체디스플레이기술학회지
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    • 제20권4호
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    • pp.125-129
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    • 2021
  • We investigated the electronic property and atomic structure for chalcopyrite (CH) AlxGa1-xAs semiconductor by using first-principles FPLMTO method. The CH-AlxGa1-xAs exhibits a p-type semiconductor with a direct band-gap. For low Al concentration unoccupied hole-carriers are induced, but for high Al concentration it is formed a localized bonding or anti-bonding state below Fermi level. The hybridization of Al(3s)-Ga(4s, or 4p) is larger than that of Al(3s)-As(4s, or 4p). And the Al film on As-terminated surface, Al/AsGa(001), is more energetically favorable one than that on Ga-terminated (001) surface. Consequently, the band-gap of CH-AlxGa1-xAs system increases exponentially with increasing Al concentration. The change of lattice parameter is shown two different configurations with increasing Al concentration. The calculated lattice parameters for CH-AlxGa1-xAs system are compared to the experimental ones of zinc-blend GaAs and AlAs.

Temperature-dependent axial mechanical properties of Zircaloy-4 with various hydrogen amounts and hydride orientations

  • Bang, Shinhyo;Kim, Ho-a;Noh, Jae-soo;Kim, Donguk;Keum, Kyunghwan;Lee, Youho
    • Nuclear Engineering and Technology
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    • 제54권5호
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    • pp.1579-1587
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    • 2022
  • The effects of hydride amount (20-850 wppm), orientation (circumferential and radial), and temperature (room temperature, 100 ℃, 200 ℃) on the axial mechanical properties of Zircaloy-4 cladding were comprehensively examined. The fraction of radial hydride fraction in the cladding was quantified using PROPHET, an in-house radial hydride fraction analysis code. Uniaxial tensile tests (UTTs) were conducted at various temperatures to obtain the axial mechanical properties. Hydride orientation has a limited effect on the axial mechanical behavior of hydrided Zircaloy-4 cladding. Ultimate tensile stress (UTS) and associated uniform elongation demonstrated limited sensitivity to hydride content under UTT. Statistical uncertainty of UTS was found small, supporting the deterministic approach for the load-failure analysis of hydrided Zircaloy-4 cladding. These properties notably decrease with increasing temperature in the tested range. The dependence of yield strength on hydrogen content differed from temperature to temperature. The ductility-related parameters, such as total elongation, strain energy density (SED), and offset strain decrease with increasing hydride contents. The abrupt loss of ductility in UTT was found at ~700 wppm. Demonstrating a strong correlation between total elongation and offset strain, SED can be used as a comprehensive measure of ductility of hydrided zirconium alloy.

Implementation of waste silicate glass into composition of ordinary cement for radiation shielding applications

  • Eid, Mohanad S.;Bondouk, I.I.;Saleh, Hosam M.;Omar, Khaled M.;Sayyed, M.I.;El-Khatib, Ahmed M.;Elsafi, Mohamed
    • Nuclear Engineering and Technology
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    • 제54권4호
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    • pp.1456-1463
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    • 2022
  • The aim of this work is to study the radiation shielding properties of cement samples with waste glass incortated into its composition. The mass attenuation coefficient (MAC) of the samples were experimentally determined to evaluate their radiation shielding ability. The experimental coefficient was evaluated using NaI detector for gamma energies between 59.53 keV and 1408.01 keV using different radioactive point sources Am-241, Eu-152, Co-60, and Cs-137, and the gamma transmission parameters half-value layer, mean free path, and transmission factor were calculated. The theoretical coefficient of the composites was determined using Geant4 and XCOM software. The results were also compared against Geant4 and XCOM simulations by calculating the relative deviation between the values to determine the accuracy of the results. In addition the mechanical properties (including Compressive and porosity) as well as the thermogravimetric analysis were tested for the present samples. Overall, it was concluded that the cement sample with 50% waste glass has the greatest shielding potential for radiation shielding applications and is a useful way to reuse waste glass.

Design of Multipurpose Phantom for External Audit on Radiotherapy

  • Lim, Sangwook
    • 한국의학물리학회지:의학물리
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    • 제32권4호
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    • pp.122-129
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    • 2021
  • Purpose: This study aimed to design a multipurpose dose verification phantom for external audits to secure safe and optimal radiation therapy. Methods: In this study, we used International Atomic Energy Agency (IAEA) LiF powder thermoluminescence dosimeter (TLD), which is generally used in the therapeutic radiation dose assurance project. The newly designed multipurpose phantom (MPP) consists of a container filled with water, a TLD holder, and two water-pressing covers. The size of the phantom was designed to be sufficient (30×30×30 cm3). The water container was filled with water and pressed with the cover for normal incidence to be fixed. The surface of the MPP was devised to maintain the same distance from the source at all times, even in the case of oblique incidence regardless of the water level. The MPP was irradiated with 6, 10, and 15 MV photon beams from Varian Linear Accelerator and measured by a 1.25 cm3 ionization chamber to get the correction factors. Monte Carlo (MC) simulation was also used to compare the measurements. Results: The result obtained by MC had a relatively high uncertainty of 1% at the dosimetry point, but it showed a correction factor value of 1.3% at the 5 cm point. The energy dependence was large at 6 MV and small at 15 MV. Various dosimetric parameters for external audits can be performed within an hour. Conclusions: The results allow an objective comparison of the quality assurance (QA) of individual hospitals. Therefore, this can be employed for external audits or QA systems in radiation therapy institutions.

Spectroscopic Characterization of Aqueous and Colloidal Am(III)-CO3 Complexes for Monitoring Species Evolution

  • Hee-Kyung Kim
    • 방사성폐기물학회지
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    • 제20권4호
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    • pp.371-382
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    • 2022
  • Carbonates are inorganic ligands that are abundant in natural groundwater. They strongly influence radionuclide mobility by forming strong complexes, thereby increasing solubility and reducing soil absorption rates. We characterized the spectroscopic properties of Am(III)-carbonate species using UV-Vis absorption and time-resolved laser-induced fluorescence spectroscopy. The deconvoluted absorption spectra of aqueous Am(CO3)2- and Am(CO3)33- species were identified at red-shifted positions with lower molar absorption coefficients compared to the absorption spectrum of aqua Am3+. The luminescence spectrum of Am(CO3)33- was red-shifted from 688 nm for Am3+ to 695 nm with enhanced intensity and an extended lifetime. Colloidal Am(III)-carbonate compounds exhibited absorption at approximately 506 nm but had non-luminescent properties. Slow formation of colloidal particles was monitored based on the absorption spectral changes over the sample aging time. The experimental results showed that the solubility of Am(III) in carbonate solutions was higher than the predicted values from the thermodynamic constants in OECD-NEA reviews. These results emphasize the importance of kinetic parameters as well as thermodynamic constants to predict radionuclide migration. The identified spectroscopic properties of Am(III)-carbonate species enable monitoring time-dependent species evolution in addition to determining the thermodynamics of Am(III) in carbonate systems.

THE EFFECT OF THE HIGH DENSITY PLASMA ON THE DIAMOND-LIKE CARBON FILMS

  • Kim, H.;D.H. Jung;Park, B.;K. C. Yoo;Lee, J. J.;J. H. Joo
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2003년도 추계학술발표회초록집
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    • pp.54-54
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    • 2003
  • DLC films were deposited on Si(100) substrates by inductively coupled plasma (ICP) assisted chemical vapor deposition (CVD). A mixture of acetylene (C$_2$H$_2$) and argon (Ar) gases was used as the precursor and plasma source, respectively. The structure of the films was characterized by the Raman spectroscopy. Results from the Raman spectroscopy analysis indicated that the property change of the DLC films is due to the sp$^3$ and sp$^2$ ratio in the films under various conditions such as ICP power, working pressure and RF substrate bias. The hydrogen content in the DLC films was determined by an electron recoil detector (ERB). The roughness of the films was measured by atomic force microscope (Am). A microhardness tester was used for the hardness and elastic modulus measurement. The DLC film showed a maximum hardness of 37㎬. In this work, the relationship between deposition parameters and mechanical properties were discussed.

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Simulation Procedure for Estimating the Reliability of a System with Repairable Units+

  • S. Y. Baek;T.J. Lim;J. S. Hong;C. H. Lie;Park, Chang K.
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(2)
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    • pp.691-698
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    • 1996
  • This paper propose a procedure to estimate the system lifetime distribution using simulation method in a parametric framework and also develop the criterion for terminating the simulation. We assume that a system is composed of many components whose lifetime and repair time distributions are general, and repair of each component is imperfect or not. General simulation algorithms can not be adopted for this case, due to the dependency of successive operating times and the discontinuity in base line intensity function of failure process. Then we propose algorithms for generating failure times subject to imperfect repair. We develop the event time tracking logic for identifying the system failure time, and also develop the criterion for terminating the simulation. Our procedure is composed of two phases. The first phase of the procedure is to generate the system failure times from the inputs. The second phase is to estimate the lifetime distribution of the system. The best model is selected by a fully automated procedure among well-known parametric families, and the required parameters are estimated. We give examples to show the accuracy of our procedure and the effect of repair effect of components to system MTTF(Mean Time To Failure).

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Effect of mitigation strategies in the severe accident uncertainty analysis of the OPR1000 short-term station blackout accident

  • Wonjun Choi;Kwang-Il Ahn;Sung Joong Kim
    • Nuclear Engineering and Technology
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    • 제54권12호
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    • pp.4534-4550
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    • 2022
  • Integrated severe accident codes should be capable of simulating not only specific physical phenomena but also entire plant behaviors, and in a sufficiently fast time. However, significant uncertainty may exist owing to the numerous parametric models and interactions among the various phenomena. The primary objectives of this study are to present best-practice uncertainty and sensitivity analysis results regarding the evolutions of severe accidents (SAs) and fission product source terms and to determine the effects of mitigation measures on them, as expected during a short-term station blackout (STSBO) of a reference pressurized water reactor (optimized power reactor (OPR)1000). Three reference scenarios related to the STSBO accident are considered: one base and two mitigation scenarios, and the impacts of dedicated severe accident mitigation (SAM) actions on the results of interest are analyzed (such as flammable gas generation). The uncertainties are quantified based on a random set of Monte Carlo samples per case scenario. The relative importance values of the uncertain input parameters to the results of interest are quantitatively evaluated through a relevant sensitivity/importance analysis.

A multi-criteria decision-making process for selecting decontamination methods for radioactively contaminated metal components

  • Inhye Hahm ;Daehyun Kim;Ho jin Ryu;Sungyeol Choi
    • Nuclear Engineering and Technology
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    • 제55권1호
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    • pp.52-62
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    • 2023
  • Various decontamination technologies have been developed for removing contaminated areas in industries. Although it is important to consider parameters such as safety, cost, and time when selecting the decontamination technology, till date their comparative study is missing. Furthermore, different decontamination technologies influence the decontamination effects in different ways. Therefore, this study compares different decontamination techniques for the steam generator using a multicriteria decision-making method. A steam generator is a large device comprising both low- and very low-level waste (LLW, VLLW) and reflects the difference in weights of the standards according to the classification of the waste. For LLW and VLLW decontaminations, chemical oxidizing reduction decontamination (CORD) and decontamination grit blasting were used as the preferred techniques, respectively, considering the purpose of decontamination differs based on the initial state of waste. An expert survey revealed that safety in LLW and waste minimization in VLLW exhibited high preference. This evaluation method can be applied not only to the comparison between each process, but also to the creation of process scenarios. Therefore, determining the decontamination approach using logical decision-making methods may improve the safety and economic feasibility of each step in the decommissioning process and ensure a public acceptance.

Development of a muon detector based on a plastic scintillator and WLS fibers to be used for muon tomography system

  • Chanwoo Park;Kyu Bom Kim;Min Kyu Baek;In-soo Kang;Seongyeon Lee;Yoon Soo Chung;Heejun Chung;Yong Hyun Chung
    • Nuclear Engineering and Technology
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    • 제55권3호
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    • pp.1009-1014
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    • 2023
  • Muon tomography is a useful method for monitoring special nuclear materials (SNMs) such as spent nuclear fuel inside dry cask storage. Multiple Coulomb scattering of muons can be used to provide information about the 3-dimensional structure and atomic number(Z) of the inner materials. Tomography using muons is less affected by the shielding material and less harmful to health than other measurement methods. We developed a muon detector for muon tomography, which consists of a plastic scintillator, 64 long wavelength-shifting (WLS) fibers attached to the top of the plastic scintillator, and silicon photomultipliers (SiPMs) connected to both ends of each WLS fiber. The muon detector can acquire X and Y positions simultaneously using a position determination algorithm. The design parameters of the muon detector were optimized using DETECT2000 and Geant4 simulations, and a muon detector prototype was built based on the results. Spatial resolution measurement was performed using simulations and experiments to evaluate the feasibility of the muon detector. The experimental results were in good agreement with the simulation results. The muon detector has been confirmed for use in a muon tomography system.