• Title/Summary/Keyword: Atmospheric sampling

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수원지역의 대기 중 Pb의 농도 결정 (Determination of Atmospheric Lead in Suwon City)

  • 이태정;김성천;김동술
    • 한국환경과학회지
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    • 제4권5호
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    • pp.535-542
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    • 1995
  • Monitoring of lead concentration in the ambient alt was performed in Kyung Hee University-Suwon Campus over a period of 5 year from November 1989 to September 1994 using a cascade impactor having 9 size stages. Lead level was analyzed by x-ray fluorescence. The lead levels have been extensively examined to identify annual trends, seasonal variations, and size distribution of lead concentration. Even though consumption of leaded gasoline has been decreased, the levels have not significantly changed during the sampling period. Probably other sources like fossil fuel emission and refuse incinerator will be potential contributors. The seasonal variation showed that Pb concentration significantly increased in the winter season and decreased in the summer season. The size distributions of Pb were observed to be unimodal distribution of the 1.1~2.1 $mu extrm{m}$ sixte ranges in the winter and 0.65~1.1 ${\mu}{\textrm}{m}$ in the summer.

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수원지역의 대기 중 Pb의 농도 결정 (Determination of Atmospheric Lead in Suwon City)

  • 이태정;김성천;김동술
    • 한국환경과학회지
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    • 제4권5호
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    • pp.149-149
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    • 1995
  • Monitoring of lead concentration in the ambient alt was performed in Kyung Hee University-Suwon Campus over a period of 5 year from November 1989 to September 1994 using a cascade impactor having 9 size stages. Lead level was analyzed by x-ray fluorescence. The lead levels have been extensively examined to identify annual trends, seasonal variations, and size distribution of lead concentration. Even though consumption of leaded gasoline has been decreased, the levels have not significantly changed during the sampling period. Probably other sources like fossil fuel emission and refuse incinerator will be potential contributors. The seasonal variation showed that Pb concentration significantly increased in the winter season and decreased in the summer season. The size distributions of Pb were observed to be unimodal distribution of the 1.1∼2.1 $mu extrm{m}$ sixte ranges in the winter and 0.65∼1.1 ㎛ in the summer.

ESTIMATION OF RAIN SCAVENGING RATIO FOR PARTICLE BOUND POLYCYCLIC AROMATIC HYDROCARBONS AND POLYCHLORINATED BIPHENYLS

  • Kim, Hyeon-Kook;Shin, Yong-Seung;Lee, Dong-Soo;Song, Byung-Joo;Kim, Jong-Guk
    • Environmental Engineering Research
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    • 제11권1호
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    • pp.33-44
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    • 2006
  • The objective of this study was to develop and assess a method for estimating the rain scavenging ratios (RSRs) of particle-bound PAHs and PCBs using measured scavenging ratio of particulate matters (PM) and routinely available data of physico-chemical properties of PM. Paired atmospheric and rainwater sampling was conducted for a total of 4 rain events. Assuming equilibrium partitioning in rainwater-gas-PM system, an equation was derived for estimating the RSR of particle-bound chemicals as a function of RSR of PM and three equilibrium partition constants (i.e. dimensionless Henry's law constant, gas-particle partition coefficient, and water-particle partition coefficient). For all PAHs, the model significantly under-predicted the RSR while the model prediction for PCBs agreed with observation mostly within a factor of 5. The RSR model for the chemicals is of limited use as its accuracy critically depends on how close the observed partitioning of the chemicals in the gas-PM-rainwater system is to that estimated under the equilibrium assumption.

대기압의 변화에 따른 휘발성 오염물질의 토양에서 대기로의 거동

  • 최지원;;황경엽
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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    • pp.114-116
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    • 2005
  • Natural attenuation has been actively studied and often selected as final clean-up process in remediation of contaminated ground-water and soil for the last decade. Accordingly, understanding of natural processes affecting the fate and transport of contaminants in the subsurface becomes important for a success of implementation of the natural remediation strategy, Contaminant advection and diffusion processes in the unsaturated zone are naturally related to environmental changes in the atmosphere. The atmospheric pressure changes affecting the transport of contaminants in the subsurface are investigated in this study. Moisture content, trichloroethylene (TCE) concentration, temperature, and pressure variations in the subsurface were measured for the July, August, November, and December 2001 at Picatinny Arsenal, New Jersey. These data were used for a one-phase flow and one-component transport model in simulating the soil-gas flow and accordingly the TCE transport in the subsurface in accordance with the atmosphere pressure variations at the surface. The soil-gas velocities during the sampling periods varied with a magnitude of $10^{-6}\;to\;10^{-7}\;m\;s^{-1}$ at land surface. The TCE advection fluxes at land surface were several orders of magnitude smaller than the TCE diffusion fluxes. A sensitivy analysis indicated that advection fluxes were more sensitive to changes in geo-environmental conditions compared to diffusion fluxes. Of all the parameters investigated in this study, moisture content has the most significant effect on TCE advection and diffusion fluxes.

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UNCERTAINTY AND SENSITIVITY STUDIES WITH THE PROBABILISTIC ACCIDENT CONSEQUENCE ASSESSMENT CODE OSCAAR

  • HOMMA TOSHIMITSU;TOMITA KENICHI;HATO SHINJI
    • Nuclear Engineering and Technology
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    • 제37권3호
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    • pp.245-258
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    • 2005
  • This paper addresses two types of uncertainty: stochastic uncertainty and subjective uncertainty in probabilistic accident consequence assessments. The off-site consequence assessment code OSCAAR has been applied to uncertainty and sensitivity analyses on the individual risks of early fatality and latent cancer fatality in the population outside the plant boundary due to a severe accident. A new stratified meteorological sampling scheme was successfully implemented into the trajectory model for atmospheric dispersion and the statistical variability of the probability distributions of the consequence was examined. A total of 65 uncertain input parameters was considered and 128 runs of OSCAAR with 144 meteorological sequences were performed in the parameter uncertainty analysis. The study provided the range of uncertainty for the expected values of individual risks of early and latent cancer fatality close to the site. In the sensitivity analyses, the correlation/regression measures were useful for identifying those input parameters whose uncertainty makes an important contribution to the overall uncertainty for the consequence. This could provide valuable insights into areas for further research aiming at reducing the uncertainties.

광화학측정망에서 측정한 휘발성유기화합물의 정도관리 방법 (Quality Assurance and Quality Control method for Volatile Organic Compounds measured in the Photochemical Assessment Monitoring Station)

  • 신혜정;김종춘;김용표
    • 한국입자에어로졸학회지
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    • 제7권1호
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    • pp.31-44
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    • 2011
  • The hourly volatile organic compounds(VOCs) concentrations between 2005 and 2008 at Bulgwang photochemical assessment monitoring station were investigated to establish a method for quality assurance and quality control(QA/QC) procedure. Systematic error, erratic error, and random error, which was manifested by outlier and highly fluctuated data, were checked and removed. About 17.3% of the raw data were excluded according to the proposed QA/QC procedure. After QA/QC, relative standard deviation for representing 15 species concentrations decreased from 94.7-548.0% to 63.4-125.8%, implying the QA/QC procedure is proper. For further evaluation about the adequacy of QA/QC procedure, principal components analysis(PCA) was carried out. When the data after QA/QC procedure was used for PCA, the extracted principal components were different from the result from the raw data and could logically explain the major emission sources(gasoline vapor, vehicle exhaust, and solvent usage). The QA/QC procedure based on the concept of errors is inferred to proper to be applied on VOCs. However, an additional QA/QC step considering the relationship between species in the atmosphere needs to be further considered.

위해성 이차 PAHs 성분 측정 및 관리 방안 (Measurement and Control of Hazardous PAHs Reaction Products)

  • 이지이;홍지형;정창훈;김용표
    • 한국입자에어로졸학회지
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    • 제9권2호
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    • pp.111-125
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    • 2013
  • Among the hazardous air pollutions(HAPs), characteristics of secondary organic aerosols are not well understood. In this study, the current state for the measurement and analysis of representative secondary PAHs such as oxy-PAHs and nitro-PAHs are presented with the discussion of their toxicity. Also, further research directions for the secondary PAHs are suggested. It was found that the chemical reaction mechanisms and products of PAHs in the air are poorly identified and their toxicities are not well studied. Moreover ambient concentrations of those secondary PAHs are not well documented. Sampling methodologies of those secondary PAHs are similar with PAHs but the analytical protocols for those secondary PAHs are more complicated than PAHs. Future management directions are suggested along with future research directions.

AC 전기장내 하전 액체 입자의 응집에 관한 실험적 연구 (Experimental Study on Electrical Agglomeration of Liquid Particles in an Alternating Electric Field)

  • 지준호;황정호;배귀남;김용진
    • 대한기계학회논문집B
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    • 제25권3호
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    • pp.442-450
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    • 2001
  • Experiments were carried out on agglomeration of bipolarly charged particles in an alternating current electric field. Laboratory-scale setup was built and experiments were conducted at atmospheric condition. DOS(Di-octyl Sebacate) particles with 100% purity were generated by an atomizer. The particles were branched into two, each of which passed through a wire-to-plate type charging section where a positive or a negative DC high voltage was applied and was charged positively or negatively. These bipolarly charged particles together passed through an agglomeration section where an $\pm$20kV AC power was applied between two plates. The resident time in the agglomeration section was adjusted as l sec. Particle sampling was made by a cascade impactor (MOUDI). The effect of agglomeration system on the reduction ratio of particles below l ㎛ was 42∼45%. Effect of AC frequency on the particle size distribution was found insignificant.

몬테칼로 방법을 사용할 사고후 영향 평가모델 (An Off-Site Consequence Modeling for Accident Using Monte Carlo Method)

  • Chang Sun Kang;Sae Yul Lee
    • Nuclear Engineering and Technology
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    • 제16권3호
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    • pp.136-140
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    • 1984
  • 원자력발전소 사고 후 그 위험도를 평가하는 새로운 방법으로 몬테칼로 방법을 제시한다. 본 연구에서는 발전소 주위의 주민에게 주는 방사선의 영향을 평가하기 위하여 공기중의 확산계산에 부지에서 측정한 기상조건을 직접 사용하고 있다. 사고가 일어나는 순간에서의 화산조건은 주어진 기상자료로부터 분석된 pdf에 의하여 결정되고 그이후의 조건(풍향, 풍속, 안정도)은 마르코프 조건을 만족시킨다고 가정하였다. 예제로써 KNU-1의 냉각재 상실사고를 분석한 절과 50마일내의 주민이 받는 선량은 50퍼센트 신뢰도를 갖고 200 man-Sv이다.

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Deep Hydrochemical Investigations Using a Borehole Drilled in Granite in Wonju, South Korea

  • Kim, Eungyeong;Cho, Su Bin;Kihm, You Hong;Hyun, Sung Pil
    • 방사성폐기물학회지
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    • 제19권4호
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    • pp.517-532
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    • 2021
  • Safe geological disposal of spent nuclear fuel (SNF) requires knowledge of the deep hydrochemical characteristics of the repository site. Here, we conducted a set of deep hydrochemical investigations using a 750-m borehole drilled in a model granite system in Wonju, South Korea. A closed investigation system consisting of a double-packer, Waterra pump, flow cell, and water-quality measurement unit was used for in situ water quality measurements and subsequent groundwater sampling. We managed the drilling water labeled with a fluorescein dye using a recycling system that reuses the water discharged from the borehole. We selected the test depths based on the dye concentrations, outflow water quality parameters, borehole logging, and visual inspection of the rock cores. The groundwater pumped up to the surface flowed into the flow cell, where the in situ water quality parameters were measured, and it was then collected for further laboratory measurements. Atmospheric contact was minimized during the entire process. Before hydrochemical measurements and sample collection, pumping was performed to purge the remnant drilling water. This study on a model borehole can serve as a reference for the future development of deep hydrochemical investigation procedures and techniques for siting processes of SNF repositories.