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Quality Assurance and Quality Control method for Volatile Organic Compounds measured in the Photochemical Assessment Monitoring Station  

Shin, Hye-Jung (Department of Environmental Science and Engineering, Ewha Womans University)
Kim, Jong-Choon (Atmospheric Research Division, National Institute of Environmental Research)
Kim, Yong-Pyo (Department of Environmental Science and Engineering, Ewha Womans University)
Publication Information
Particle and aerosol research / v.7, no.1, 2011 , pp. 31-44 More about this Journal
Abstract
The hourly volatile organic compounds(VOCs) concentrations between 2005 and 2008 at Bulgwang photochemical assessment monitoring station were investigated to establish a method for quality assurance and quality control(QA/QC) procedure. Systematic error, erratic error, and random error, which was manifested by outlier and highly fluctuated data, were checked and removed. About 17.3% of the raw data were excluded according to the proposed QA/QC procedure. After QA/QC, relative standard deviation for representing 15 species concentrations decreased from 94.7-548.0% to 63.4-125.8%, implying the QA/QC procedure is proper. For further evaluation about the adequacy of QA/QC procedure, principal components analysis(PCA) was carried out. When the data after QA/QC procedure was used for PCA, the extracted principal components were different from the result from the raw data and could logically explain the major emission sources(gasoline vapor, vehicle exhaust, and solvent usage). The QA/QC procedure based on the concept of errors is inferred to proper to be applied on VOCs. However, an additional QA/QC step considering the relationship between species in the atmosphere needs to be further considered.
Keywords
Volatile organic compounds; Quality assurance and quality control; Sampling and analysis error; Statistical error analysis;
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