• 한국대기환경학회지
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• 제16권4호
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• pp.309-316
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• 2000

Chemical compositions of air pollutants with fine particles (<2.5 ${\mu}{\textrm}{m}$, PB2.5) were evaluated at background site. Kangwha. in Korea during the winter season. The data set was obtained for seventeed days with 24-hour sampling from December 11 to 16, 1996 and from January 9 to 1997. The chemical species have been measured {{{{ {SO }`_{4 } ^{2- } }}}}, {{{{ { NO}`_{3 } ^{- } }}}}, {{{{ { NH}`_{4 } ^{+ } }}}}. OC and EC in the particulate phase, NH3 HNO3, HCl and SO2 in the gas phase using the three stage filter pack method. Mean concentration ($\mu\textrm{g}$/m3) of this study were : 35.42 for PM2.5 8.78 for organic carbon (OC) 7.25 for nss {{{{ {SO }`_{4 } ^{2- } }}}}, 4.94 for {{{{ { NO}`_{3 } ^{- } }}}}, 3.58 for {{{{ { NH}`_{4 } ^{+ } }}}} and 1.48 for elemental carbon (EC) respectively. Contributive rates of major particulate components in PM2.5 were OC (25%) nss- {{{{ {SO }`_{4 } ^{2- } }}}}(20%) ,{{{{ { NO}`_{3 } ^{- } }}}}(14%) {{{{ { NH}`_{4 } ^{+ } }}}}(10%) and EC (4%) respectively and these components could be accounted for 73% of PM2.5 mass. Reactive forms of {{{{ { NH}`_{4 } ^{+ } }}}} were considered as NH4HO3 and NH4{{{{ {SO }`_{4 } ^{2- } }}}} during the sampling periods. {{{{ { NO}`_{3 } ^{- } }}}}/({{{{ { NO}`_{3 } ^{- } }}}} + HNO3) and {{{{ {SO }`_{4 } ^{2- } }}}}/({{{{ {SO }`_{4 } ^{2- } }}}} + SO2) were calculated 0.8 and 0.9 respectively. Most of these compounds might be formed in partiiculate phase in the air. Correlation coefficient between OC and EC was 0.866 which might have the same sources during the sampling periods,.

• 한국대기환경학회지
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• 제30권3호
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• pp.211-222
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• 2014

Pork belly meat is one of the most preferred food items for many Korean people. The odorants released from cooking of pork belly meat were measured by three kinds of cooking methods (Charcoal-grill (C), Electric Pan (E), and Gas burner-pan (G)). A total of 16 target compounds including carbonyl compounds, volatile organic compounds, and poly aromatic hydrocarbon were selected and analyzed for comparative purposes. Their emission concentrations were quantified using HPLC-UV, GC-MS, GC-TOF-MS, etc. The gas samples collected by Charcoal-grill cooking showed generally enhanced concentrations of most target compounds among all three kinds of cooking methods. In Charcoal-grill, concentration of benzene, formaldehyde and pyrene went up to 543, 516, and 402 ppb, respectively. It the results are compared in terms of the sum of odor intensity, the highest value (4.25) was also seen from Charcoal-grill. The results of this study confirm that the significantly reduced emission of harmful pollutants can be attained, it pork belly meat is cooked by the Gas or electric pan instead of Charcoal-grill.

• 한국대기환경학회지
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• 제9권3호
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• pp.207-215
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• 1993

In order to statistically predict $O_3$ levels in Seoul, the study used the TMS (telemeted air monitoring system) data from the Department of Environment, which have monitored at 20 sites in 1989 and 1990. Each data in each site was characterized by 6 major criteria pollutants ($SO_2, TSP, CO, NO_2, THC, and O_3$) and 2 meteorological parameters, such as wind speed and wind direction. To select proper variables and to determine each pollutant's behavior, univariate statistical analyses were extensively studied in the beginning, and then various applied statistical techniques like cluster analysis, regression analysis, and expert system have been intensively examined. For the initial study of high level $O_3$ prediction, the raw data set in each site was separated into 2 group based on 60 ppb $O_3$ level. A hierarchical cluster analysis was applied to classify the group based on 60 ppb $O_3$ into small calsses. Each class in each site has its own pattern. Next, multiple regression for each class was repeatedly applied to determine an $O_3$ prediction submodel and to determine outliers in each class based on a certain level of standardized redisual. Thus, a prediction submodel for each homogeneous class could be obtained. The study was extended to model $O_3$ prediction for both on-time basis and 1-hr after basis. Finally, an expect system was used to build a unified classification rule based on examples of the homogenous classes for all of sites. Thus, a concept of high level $O_3$ prediction model was developed for one of $O_3$ alert systems.

• 대기
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• 제29권5호
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• pp.609-614
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• 2019

Cloud seeding experiment has been proposed as a way to alleviate severe air pollution problem because, if successful, artificially produced precipitation through cloud seeding could scavenge out some portion of air pollutants. As a first step to verify the practicality of such experiment, seedability of the clouds observed in Seoul is assessed by examining statistical characteristics of some relevant meteorological variables. Analyses of 9 years of Korea Meteorological Agency Seoul station data indicate that as PM₁₀ mass concentration increases, cloud amount, liquid water path, and ice water path decrease, but the difference between temperature and dew point temperature tends to increase. Such finding suggests that cloud seeding becomes less feasible as air pollution becomes more severe in the Seoul metropolitan area, at least in a statistical sense. For some individual severe air pollution events, however, seedable clouds may exist and indeed cloud seeding experiments can be successful. Therefore, detailed investigation on cloud seedability for individual severe air pollution events are highly required to make a concrete assessment of cloud seeding as a way to alleviate severe air pollution problem.

• 대기
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• 제23권4호
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• pp.501-511
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• 2013

In this study, we estimate the background concentration of black carbon (BC) mass concentration measured at Gosan Climate Observatory from January 2008 to December 2011 by applying six methods: (1) Mean and Median (2) Trimmed mean method deployed in Interagency Monitoring of Protected Visual Environments (IMPROVE) network program (hereafter, IMPROVE method), (3) Concentration-frequency distribution analysis method, (4) Advanced Global Atmospheric Gases Experiment (AGAGE) method (hereafter, AGAGE method), (5) Kaufman et al. (2001) method (hereafter, Kaufman method), and (6) Airmass sector analysis. The background concentration of BC mass concentrations is estimated to be about 400~900 ng $m^{-3}$, but each method shows a large difference. The estimated background concentration, in general, is arranged in the order of: mean > IMPROVE method > median > Kaufman method > concentration-frequency distribution analysis method > AGAGE method. The background concentration estimated by the airmass sector analysis is found to be about 550 ng $m^{-3}$ which is lower than those estimated by other methods. When we apply the same analytical period (i.e., 4-day and 6-day) to both AGAGE and Kaufman methods, the estimated background concentrations are quite similar. However, further researches on the development of statistical method for estimating background concentration for various gas-phase and particulate pollutants under different environment are needed.

• Asian Journal of Atmospheric Environment
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• 제9권1호
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• pp.78-85
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• 2015

In the past several decades, biofuels have emerged as candidates to help mitigate the issues of global warming, fossil fuel depletion and, in some cases, atmospheric pollution. To date, the only biofuels that have achieved any significant penetration in the global transportation sector are ethanol and biodiesel. The global consumption of biodiesel was rapidly increased from 2005. The goal of this study was to examine the chemical composition on particulate pollutant emissions from a diesel engine operating on several different biodiesels. Tests were performed on non-road diesel engine. Experiments were performed on 5 different fuel blends at 2 different engine loading conditions (50% and 75%). 5 different fuel blends were ultra-low sulfur diesel (ULSD, 100%), soy biodiesel (Blend 20% and Blend 100%) and canola biodiesel (Blend 20% and Blend 100%). The chemical properties of particulate pollutants were characterized using an Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS). Organic matter and nitrate were generally the most abundant aerosol components and exhibited maximum concentration of $1207{\mu}g/m^3$ and $30{\mu}g/m^3$, respectively. On average, the oxidized fragment families ($C_xH_yO_1{^+}$, and $C_xH_yO_z{^+}$) account for ~13% of the three family sum, while ~87% comes from the $C_xH_y{^+}$ family. The two peaks of $C_2H_3O_2$ (m/z 59.01) and $C_3H_7O$ (m/z 59.04) located at approximately m/z 59 could be used to identify atmospheric particulate matter directly to biodiesel exhaust, as distinguished from that created by petroleum diesel in the AMS data.

• 한국환경보건학회지
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• 제30권3호
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• pp.293-299
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• 2004

Traffic represents one of the largest sources of primary air pollutants in urban area. As a consequence, numerous abatement strategies are being pursued to decrease the ambient concentration of pollutants. A characteristics of most of the these strategies is a requirement for accurate data on both the quantity and spatial distribution of emissions to air in the form of an atmospheric emission inventory database. In the case of traffic pollution, such an inventory must be compiled using activity statistics and emission factors for vehicle types. The majority of inventories are compiled using passive data from either surveys or transportation models and by their very nature tend to be out-of-date by the time they are compiled. The study of current trends is towards integrating urban traffic control systems and assessments of the environmental effects of motor vehicles. In this study, a model of vehicle emission calculation by using real-time traffic data was studied. Traffic data, which are required on a street-by-street basis, is obtained from induction loops of traffic control system. It is possible that characteristics of hourly air pollutants emission rates is obtained from hourly traffic volume and speed. An emission rates model is allocated with a high resolution space by using geographic information system (GIS). Vehicle emission model was developed with a high resolution spatial, gridded and hourly emission rates.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2003년도 춘계학술대회 논문집
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• pp.411-412
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• 2003

일반적으로 공단지역의 경우 대기 중으로 배출된 다량의 대기오염물질이 대기정체 조건 하에 국지적으로 축적되어 고농도 현상이 나타나게 된다. 하지만 국지순환이 뚜렷이 나타나는 지역의 경우 대기오염물질의 지역적 수송현상을 경험하게 되며 풍하측 고농도현상이 빈번히 나타나게 된다. 이러한 대기오염물질 수송현상은 연안에 인접한 공단지역에서 보다 뚜렷이 나타나는데, 이것은 육풍 효과에 의해 바다로 밀려간 기괴내의 대기오염물질이 수면의 낮은 침적에 의해 (Entwistle et al, 1997) 일정 농도로 유지되고 다시 해풍에 의해 기괴가 내륙으로 수송되기 때문이다. (중략)

• 한국환경과학회지
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• 제4권2호
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• pp.159-168
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• 1995

To predict reasonably the movement and the concentration of the pollutants in the coastal area. A simulation model should be prepared considering detail topography with land-sea and the urban effects, and the resolution near the source. The explicit method can not be applied due to the instability of the numerical calculation in high horizontal-grid resolution, while the ADI scheme satisfied with the high horizontal grid resolution and can be used in the fine mesh system which shows the detail topography, atmospheric flow The ADI method which studied the high horizontal grid resolution was excellent. The two dimensional model used in the study using ADI method is proved as a reasonable model to predict the wind field in any small scale area including mountainous coastal urban area.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제4권4호
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• pp.263-271
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• 2000

To investigate the distribution of air pollutants dispersion in the horizontal wind fields, a chaff release experiment was carried out by an airplane. The temporal and spatial variations of a chaff plume from an elevated point source using the WSR-88D(NEXRAD) radar. The observed profiles of radar reflectivity were compared with the Gaussian diffusion model at slightly unstable atmospheric condition. The present study shows that the distributions of radar reflectivity from chaffs and their concentration by the model are in general agreement with time variation. The dispersion coefficients in downwind($\sigma$(sub)x) and crosswind($\sigma$(sub)y) spread data exceeded what has generally been found at Pasquill and Brigg\`s estimates. As a result, it was clearly shown that horizontal and vertical diffusion coefficients are more accurately determined as compared with theoretical coefficients. At longer diffusion distances(than 10km), a radar observation provided the determination of maximum range and diffusion height more qualitatively, too.