• Journal of Korean Society for Atmospheric Environment
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• v.25 no.6
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• pp.523-538
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• 2009

Recently, there has been a keen demand for real-time automatic monitoring of VOCs not only in Korea but other developed countries. We carried out this study to evaluate and to optimize the performance of a continuous automatic monitoring system for hazardous VOCs (HVOCs) in the ambient atmosphere, using an on-line GC system. The online system normally consisted of a Nafion dryer prior to a cold trap of an automatic thermal desorption apparatus and a GC system equipped with two detectors, i.e. PID and ECD. Preliminary tests conducted to check out any contamination of the system revealed an evidence of significant artifact formation of benzene, and it was found that the Nafion dryer (even brand new one) is the source of the benzene artifact. Thus, all the subsequent experiments in this study was carried out inevitably by removing the Nafion dryer. The on-line GC method was investigated with a variety of QC/QA performance criteria such as repeatability, linearity, lower detection limits, and accuracy. In order to find out the best operating condition for the on-line GC system, three different types (in terms of adsorption strength) of cold trap combinations were tested, i.e. (i) Tenax-TA and Carbopack-B combination (weak and hydrophobic); (ii) Tenax-TA, Carbopack-X and Carboxen-1000 combination (strong and hydrophilic); and (iii) Tenax-TA and Carbopack-X combination (medium and hydrophobic/hydrophilic). The USEPA TO-17 manual method was selected as a reference method to evaluate the performance of the on-line method. A series of experiments revealed that the system performance was superior to others when a cold trap packed with hydrophilic adsorbents (Tenax-TA/Carbopack-X/Carboxen-1000 combination) was used and operated at $25^{\circ}C$. However, the system with a cold trap packed with a combination of Tenax-TA and Carbopack-X is more recommended for field applications since the carboxen-1000 adsorbent is too sensitive to water vapor, and hence the performance of the system might be very unstable to humid samples or during rainy days. Furthermore, the precision and accuracy criteria of the Tenax-TA/ Carbopack-X combination were generally compatible with the triple adsorbents cold trap. The continuous automatic monitoring method is, thus, considered very useful to real-time monitoring to understand the variations of VOCs concentrations in ambient air, as it adopts much simpler procedures in sampling, analysis, and data integration steps than manual monitoring methods. However, it should be noted that there is a high possibility of benzene artifacts formation through the Nafion dryer, which is often installed to remove water vapor in air samples before being adsorbed onto the cold trap. Therefore, if a Nafion dryer is used in any studies of monitoring VOCs, the benzene contamination should be carefully examined before carrying out obtaining the data.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.1
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• pp.125-131
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• 2007

• Journal of Sensor Science and Technology
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• v.29 no.5
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• pp.342-347
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• 2020

In this study, a portable total-phosphorus (TP) monitoring system utilizing a photocatalytic-reaction-based pretreatment method is proposed, fabricated, and characterized. Commercial TP monitoring systems are only used in laboratories because of their complex monitoring procedure, bulk-size, and high-cost. In particular, pretreatment in commercial TP monitoring systems is performed at high temperatures (> 120 ℃) and pressure (> 1.1 kg cm^-2) making it difficult to minimize the scale of the systems. The proposed TP monitoring system employs a pretreatment method with a photocatalytic reaction; thus, its size can be reduced, as photocatalytic reactions occur at room temperature and atmospheric pressure. Analytes with various TP concentrations are pretreated using the proposed portable TP monitoring system and are quantitatively measured with an LED and a photodiode.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 1996.04a
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• pp.22-22
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• 1996

;The Kwinana Shoreline Fumigation Experiment(KSFE) took place in Fremantle, WA, Australia between 23 January and 8 February, 1995. All measurement systems performed to expectation. The CSIRO DAR(Division of Atmospheric Research) LIDAR measured plume sections from near the Kwinana Power Station(KPS) stacks to up to about 5 km downstream. It also measured boundary layer aerosols and the structure of the boundary layer on some occasions. Both stages A and C of KPS were used as tracers at different times. Radiosonde and double theodolite sounding systems measured temperature, humidity, air pressure and wind structure at the coast(Woodman Point) and at the inland(ALCOA residue dump) site at intervals of roughly two hours. These were supplemented by mid afternoon soundings(radiosonde and single theodolite) by Department of Environmental Protection(DEP) at Swanbourne. The Flinders aircraft measured wind, turbulence and temperature structure of the atmospheric boundary layer, concentrations of $C0_2,\;0_3,\;S0_2\;and\;NO_x$ in the smoke plumes and surface radiation over both land and sea. CSIRO DCET(Division of Coal and Energy Technology) vehicle successfully interceptde many smoke plumes and using a range of tracers will be able to identify the various sources much of the time. Routine data from the DEP and Kwinana Industrial Council(KIC) air quality monitoring networks were also automatically logged. Murdoch University measured surface heat flux at Hope Valldy monitoring station and also at Wattleup monitoring station for the last five days. The heart of the LIDAR system is a Neodymium-doped Yttrium-aluminumgarnet(Nd:Y AG) laser operating at a fundamental wavelength of 1064 nm, with harmonics fo 532 nm and 355 nm. A small fraction of the laser beam is scattered back to the LIDAR, collected by a telescope and detedted by a photomultiplier tube. The intensity of the signal as a function of time is a measure of the particle concentration as a function of distance along the line of the laser shot. The results of nine days special field observations are summarized in detail.etail.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.1-14
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• 2006

Tropospheric aerosols are highly variant in time and space due to non-uniform source distribution and strong influence of meteorological conditions. Backscatter lidar measurement is useful to understand vertical distribution of aerosol. However, the backscatter lidar equation is undetermined due to its dependence on the two unknowns, extinction and backscattering coefficient. This dependence necessitates the exact value of the ratio between two parameters, that is, the lidar ratio. Also, Iidar ratio itself is useful optical parameter to understand properties of aerosols. Tropospheric aerosols were observed to understand variance of lidar ratio at Anmyeon island ($36.32^{/circ}N$, $126.19^{/circ}E$), Korea using a multi-wavelength raman lidar system developed by the Advanced Environmental Monitoring Research Center (ADEMRC), Gwangju Institute Science and Technology (GIST), Korea during measurement periods; March 15$\sim$April $16^{th}$, 2004 and May 24$\sim$ $8^{th}$ 2005. Extinction coefficient, backscattering coefficient, and lidar ratio were measured at 355 and 532 nm by the Raman method. Different types of aerosol layers were distinguished by the differences in the optical properties such as Angstrom exponent, and lidar ratio. The average value of lidar ratio during two observation periods was found to be $50.85\pm4.88$ sr at 355 nm and $52.43\pm15.15$ sr at 532 nm at 2004 and $57.94\pm10.29$ sr at 355 nm and $82.24\pm15.90$ sr at 532 nm at 2005. We conduct hysplit back-trajectory to know the pathway of airmass during the observation periods. We also calculate lidar ratio of different type of aerosol, urban, maritime, dust, continental aerosols using OPAC (Optical Properties of Aerosols and Clouds), Remote sensing of atmospheric aerosol using a multi-wavelengh lidar system with Raman channels is quite and powerful tool to characterize the optical propertises of troposheric aerosols.

• International Journal of Advanced Culture Technology
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• v.8 no.3
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• pp.269-274
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• 2020

It has used buoy for efficient domestic farm operations and fishermen fish. Buoy uses IoT-based communication to transmit water temperature, salinity, humidity, wind speed, etc. to fishers in real time. In this paper, we utilize LoRa, which enables communication in the marine environment, to construct a network and apply it to an actual buoy for monitoring. The implemented LoRa uses the 900MHz band to configure the network. The sensor consisted of a sensor that can monitor the atmospheric environment and a sensor that can monitor the marine environment. In addition, the information received in real time will be provided to the fishing village host. The fishermen were fully aware of this and took appropriate measures to conduct sea trials.

• Journal of Korean Society for Atmospheric Environment
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• v.10 no.4
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• pp.245-251
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• 1994

We considered that characteristics of SO$_2$, concentration level and relations of the meteorological parameters and high pollution concentration from the data measured 7 air quality continuous monitoring stations during 4 years, from 1990 to 1993 in Pusan. The SO$_2$ concentration level showed decreasing trend yearly, it was maximum in Winter, minimum in Summer. The time of SO$_2$ peak concentration lagged from seashore to land because of break-down of the nocturnal inversion layer and seabreeze. Ihe correlations of daily SO$_2$, value between various air quality continuous monitoring stations were highest between Beomcheondong and Meongryundong, lowest between Daeyeondong and Sinpyeongdong because of difference of air Pollution emission sources characteristic. The meteorological parameters affecting SO$_2$ concentration level were minimum temperature, relative humidity, wind speed and air pressure. The SO$_2$ high pollution($\geq$95ppb) occurred almost in Winter, particulaly in such day showing lower wind speed and higher air pressure. Elementary SO$_2$ high Pollution Predictor were high pressure system and stability of lower atmosphere.

• Journal of Korean Society for Atmospheric Environment
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• v.10 no.E
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• pp.299-302
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• 1994

At a nuclear power plant, environmental radioactivity monitoring is routine work for the radiation safety management For the environmental monitoring of tritium($^3$H) activity in water sampled liquid scintillation counting( LSC) method is applied to measure low- energy beta activity from tritium in the samples. The $^3$H activity is measured using the BECKMAN 5801 system at the KRISS( Korea Research Institute of Standards and Science) for evaluating the lower limits of detection( LLD) of $^3$H measurement and the measuring capability of low-level $^3$H activity at four nuclear Power Plant sites. The LSC systems used for low-level $^3$H activity measurements at the nuclear Power Plants are confirmed to satisfy throughout an intercomparison study under the experimental arrangements by the KRISS.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.6
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• pp.734-745
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• 2011

In this article, we reviewed the monitoring status of hazardous VOC in ambinet air in Korea and some developed countries such as USA, Japan, and UK. In many countries, two types of VOC monitoring stations are being operated, i.e., for hazardous VOC and photochemical VOC. Each country has different target VOC but all includes benzene. Korea, Japan, and UK have a national ambient air quality standard for benzene, but no national standard has been established in the USA. For sampling of the hazardous VOC, the adsorbent method is adopted in Korea and UK, while the canister method is used in the USA. Both of adsorbent and canister methods are used in Japan. USA and UK have only non-automatic method to measure the hazardous VOC, and the individual samples are being sent to their national laboratories for integrated analysis. On the other hand, Korea and Japan have automatic and nonautomatic methods to measure the hazardous VOC. Local governments or regional environmental agencies in Korea and Japan have the authorization for the sampling and analysis of VOC. According to a field study to evaluate the performance of automatic VOC monitoring system, controlling the moisture in the air sample was identified as the most important problem. However, careful attention must be given to using a moisture removing device such as Nafyon dryer, because of unexpected artifacts formation. In order to have reliable data, it is highly recommended not only to use internal standards, but to use appropriate hydrophobic adsorbents as a cold trap in any automatic on-line VOC monitoring system.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2007.10a
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• pp.303-304
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• 2007