• Title/Summary/Keyword: Atmospheric composition

Search Result 411, Processing Time 0.024 seconds

The Influence of the Asian Dust on the Metallic Composition of Fine and Coarse Particle Fractions (황사와 비황사기간의 중금속 농도분포 특성: 2001년 황사기간에 대한 비교연구)

  • 최규훈;김기현;강창희;이진홍
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.19 no.1
    • /
    • pp.45-56
    • /
    • 2003
  • In this study the distribution patterns of the metallic components were analyzed both before and after the Asian Dust (AD) events at 2001 by comparing the chemical composition of metallic components in terms of various statistical methods. According to the AD/NAD concentration ratio of metallic components, the main components of crustal soils were exhibiting the values above 1.0; but opposite results were seen dominantly for hazardous metallic components. Examination of fine-to-coarse (F/C) ratios of metallic components showed higher values for major anthropogenic components including Pb (5.83). Ni (2.61), etc. Comparison of our measurement data with those obtained within and across the Korean peninsula indicated that the metallic distribution patterns of the study area can be distinguished from previous studies. The results of our analysis, when investigated in relation with air mass movement patterns. indicated evidence of the direct influence of AD events and anthropogenic processes.

A Study on the Chemical Composition of Precipitation during the Period of Sandy Dust Phenomena (黃砂現象時 降水의 化學的 成分에 關한 硏究)

  • 李敏熙;韓振錫;韓義正;辛燦基
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.5 no.2
    • /
    • pp.1-11
    • /
    • 1989
  • Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul. During this period it rained and the precipitation was collected to investigate the rain chemistry. This study was carried out to analyzed the chemical composition of precipitation by the measurements of conditivity, cations $(H^+, NH_4^+, K^+, Na^+, Ca^{2+}, MG^{2+})$, and anions $(SO_4^{2-}, NO_3^-, Cl^-, F^-, Br^-)$ which are believed to be the major ions playing an important role in the acidity of rain water. During the period of sandy dust phenomena the range of pH value and conductivity concentration of rainwater were 6.0-6.7, 172-254 $\mu \mho/cm$. The anions and cations concentrations increased and the orders of these concentrations were $SO_4^{2-} > Cl^- > NO_3^- > Na^+ > Ca^{2+} > NH_4^+ > Mg^{2+}$. THe principal chemical compounds of rainwater were estimated at $(NH_4)_2 SO_4, CaSO_4, NaCl, and MgCl_2$.

  • PDF

A Study on the Source Profile of Volatile Organic Compounds from Major Emission Sources (휘발성 유기화합물의 주요 배출원의 배출물질 구성비에 관한 연구-오존 생성 전구물질을 중심으로-)

  • 김소영;한진석;김희강
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.17 no.3
    • /
    • pp.233-240
    • /
    • 2001
  • The composition of volatile organic compounds (VOCs) was anlyzed for major emission sources such as vehicle exhaust, gasoline and diesel vapor, organic solvent vapor, and butane fuel gas. Low carbon-numbered hydrocarbons were found to be the dominant components of gasoline vehicle exhaust. In gasoline evaporative vapor, the predominant constituents were found to be butane and iso-pentane regardless of ambient air temperature. In case of diesel evaporative vapor was similar to those of gasoline evaporative vapor. The composition of organic solvent vapor from painting, ink and petroleum consisted mostly or aromatic compounds such as toluene and m, p, o-xylene. The hydrocarbon fraction of butane fuel gas. which is used by portable bunner, consisted mainly of propane (34%) and butane(70%).

  • PDF

A Seasonal Variation of Elemental Composition of Fine Particles in Chongju Area using PIXE (PIXE를 이용한 청주지역 미세입자 중 원소의 계절 변동 특성)

  • 강병욱;이학성;김희강
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.13 no.4
    • /
    • pp.307-317
    • /
    • 1997
  • Samples of fine particle $(d_P<2.5 \mum)$ were taken in Chongju area using a dichotomous sampler. The data set was collected on fifty-eight different days with 24 hour sampling period from October 27, 1995 through August 25, 1996. The samples were analyzed using a proton induced x-ray emission (PIXE) for Na, Mg, Al, Si, S, Cl, K, Ca, Ti, V, Cr, M, Fe, Ni, Cu, Zn, Br and Pb. Values of Fe, Ca, Si, Cu, K and Cl exhibit marked seasonal variations. Mean concentrations for this study had the following order S > Cl > Si > K > Al > Fe on fine particle. Concentrations of Ca, Si and Fe were higher during the spring season compared with any other season. These phenomena may be attributable to soil dust. Cl and K were higher in the winter, which may be explained by combustion of fossil fuel. Higher values for Cu and Zn in the Winter may be due to the combustion and incineration.

  • PDF

Aerosol Size Distribution and Composition at Kosan, Cheju Island : Measurements in April 1998 (제주도 고산에서의 에어로솔 입경분포별 조성: 1998년 4월 측정 연구)

  • 김용표;배귀남;지준호;진현철;문길주
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.15 no.5
    • /
    • pp.677-685
    • /
    • 1999
  • Aerosol mass size distributions were measured at Kosan, Cheju Island in April 1998 and their compositions were analyzed. Microorifice Uniform Deposit Impactor(MOUDI) was used to collect aerosols. Sulfate and ammonium ions were predominatly present at fine mode of the aerosols while nitrate, chloride, and metal ions were mostly at coarse mode. Based on the size distribution of nitrate, it is suggested that most nitrate were from gas to particle conversion on coarse particles. Non-sea salt(nss) fraction of sulfate accounted for more than 90% of total sulfate mass concentration. In general, ion concentrations in this study are lower than those measured at the same site from the previous studies. Ion balance and chloride ion levels indicates that there had been anthropogenic chloride emission sources near to the site during the measurements.

  • PDF

Chemical Composition of Fine Aerosol Associated with Visibility Degradation in Seoul Metropolitan Area in 1994 (1994년 수도권 지역에서의 시정과 미세 입자상물질 화학조성과의 관계해석)

  • 한진석;김병곤;김신도
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.12 no.4
    • /
    • pp.377-387
    • /
    • 1996
  • This study was carried out to monitor the visibility including measurement and analysis of the various parameters such as particle size distribution, chemical composition, and meteorotical conditions to understand the characteristics and causes of this phenomenon. According to the analysis of intensive sampling, $SO_4^{2-}, NO-3^-, Cl^-, NH_4^+$ ion concentration increased together with the mass concentration around 1 $\mu$m in the case of low visibility. $(NH_4)_2SO_4, NH_4NO_3$, and $NH_4Cl$ were thought to be the major components of fine particles. The statistical analysis showed that the scattering effect of particle was 81.2%, the absorption effect was 14.9%. Therefore, these effects were the major factors to reduce the visibility. In conclusion, the visibility was reduced by the fine particle of sulfate (18.6%), nitrate (14.2%), organic carbon (10.8%), element carbon (25.8%), and residual (24.8%) during this study.

  • PDF