• Journal of Korean Society for Atmospheric Environment
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• v.34 no.3
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• pp.418-429
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• 2018

Measurements of 24-hr size-segregated ambient particles were made at an urban site of Gwangju under high pressure conditions occurred in the Korean Peninsula late in March 2018. The aim of this study was to understand the effect of air stagnation on mass size distributions and formation pathways of water-soluble organic and inorganic components. During the study period, the $NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$, water-soluble organic carbon (WSOC), and humic-like substances(HULIS) exhibited mostly bi-modal size distributions peaking at 1.0 and $6.2{\mu}m$, with predominant droplet modes. In particular, outstanding droplet mode size distributions were observed on March 25 when a severe haze occurred due to stable air conditions and long range transport of aerosol particles from northeastern regions of China. Air stagnation conditions and high relative humidity during the study period resulted in accumulation of primary aerosol particles from local emission sources and enhanced formation of secondary ionic and organic aerosols through aqueous-phase oxidations of $SO_2$, $NO_2$, $NH_3$, and volatile organic compounds, leading to their dominant droplet mode size distributions at particle size of $1.0{\mu}m$. From the size distribution of $K^+$ in accumulation mode, it can be inferred that in addition to the secondary organic aerosol formations, accumulation mode WSOC and HULIS could be partly attributed to biomass burning emissions.

• Journal of Environmental Science International
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• v.19 no.3
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• pp.331-342
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• 2010

Aerosol physical properties have been measured at Pusan National University by using the 16-channel LPC(Laser Particle Counter), and particle characteristics have been examined for the period from Aug. 4 2007 to Dec. 30, 2008. Annual total average, seasonal average, and other averages of the meteorologically classified four categories such as Asian dust, precipitation, foggy, and clear days are respectively described here. Both annually and seasonally averaged number concentration show three peaks at the particle diameter of 0.3, 1.3, and $4{\mu}m$, respectively. However, the first peak for summer season tends to be shifted toward smaller size than other seasons, implying the strong fine particle generation. Meteorological condition shows strong contrast in aerosol concentrations. In Asian dust case, relatively lower number concentrations of fine particles (i.e., smaller than $0.5{\mu}m$) were predominant, while higher concentrations of coarse particles were found particularly for the size bigger than $0.5{\mu}m$. In precipitation day, number concentrations were decreased by approximately 30% due to the removal process of precipitation. Foggy day shows significantly higher concentrations for fine particles, implying the importance of the aerosol condensation process of micro-fine-particle growing to fine-particle. Finally the regressed particle size distribution function was fitted optimally with two log-normal distribution, and discussed the similarities and differences among four categorized cases of the Asian dust, precipitation, foggy, and clear days.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.E
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• pp.27-40
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• 1998

The solubility characteristics of organic compounds were studied in terms of the extraction efficiency as a function of the polarity of the organic solvent, and the acidity of water in urban aerosol samples collected in University of East Anglia (UEA), Norwich, England. The extraction efficiency of organic compounds were evaluated with respect to the organic carbon, -nitrogen and -hydrogen by means of a wide range of solvent which include polar and nonpolar organic solvents as well as acids and alkaline water. In addition, after being dissolved in aqueous solution, the aqueous chemistry of organic compounds were studied in terms of the organic metal complexes in aerosol, which were studied with oxalic acid, copper, and zinc. The results of this study indicate that solubility characteristics of organic compounds depend on the polarity of the solvents and the acidity of the solvents. In particular, some organic compounds are water soluble, even though they are much smaller than acetone soluble fractions. In the comparison between polar organic solvent extraction and non- polar organic solvent extraction, it can be thought that significant fraction of organic compounds analysed in the aerosol samples, are polar organic compounds because of the higher extraction efficiencies of organic compounds in polar organic solvent extraction than in nonpolar organic solvent extraction. Regarding the study of the oxalic -metal complexes, it can be thought that most oxalic acids are present in the form of oxalic -copper complexes in the aerosols collected at UEA.

• Journal of Environmental Science International
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• v.16 no.10
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• pp.1157-1167
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• 2007

In an effort to interpret the characteristics of fine particle concentrations in Busan, time variations of hourly monitored concentrations $PM_{10}$ (Particulate Matter with aerodynamic Diameter ${\le}10\;{\mu}m$) in Busan are analyzed for the period from 2000 to 2005. The characteristics of aerosol second generation formation process is also interpreted qualitatively, by using the statistical analysis of the meteorological variables including temperature, wind speed, and relative humidity. The result shows some significant annual, seasonal, weekly and diurnal variations of $PM_{10}$ concentrations. In particular, seasonal(i.e., spring) variations are governed by frequency of yellow sand events even for the non-yellow sand cases where yellow-sand days are eliminated in our analysis. However, in seasonal variation, summer season predominate lower $PM_{10}$ concentrations due to the frequent precipitation, and weekly and diurnal variations are both found to be reflecting the emission rate from traffic amount. Correlation coefficients between $PM_{10}$ concentration and meterological variables for non-yellow sand days show overall negative correlation with visibility, wind speed, cloud amounts, and relative humidity. However for non-precipitation days, during non-yellow sand period positive correlation are found clearly with relative humidity, suggesting the importance of secondary aerosol formation in Busan that can be achieved by both homogeneous aerosol formation and heterogeneous transformations resulting from hygroscopic aerosol characteristics.

• Korean Journal of Optics and Photonics
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• v.26 no.1
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• pp.9-16
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• 2015

We have developed ellipsometry lidar and measured aerosol and ice-cloud characteristics. To measure a full normalized backscattering phase matrix (NBSPM) composed of nine elements, we have designed an optical system with three kinds of transmission and three kinds of reception, composed of ${\lambda}/2$ waveplate, ${\lambda}/4$ waveplate and empty optic. To find systematic optical errors, we used clean day middle-altitude (4-6km) lidar signals for which the aerosol's concentration was small and its orientation chaotic. After calibrating our lidar system, we have calculated NBSPM elements scattered from an aerosol and from an ice cloud. In the case of an aerosol, we found that the off-diagonal values $m_{12},{\ldots},m_{34}$ of the NBSPM are smaller than those for a cirrus cloud. Also, the off-diagonal values of the NBSPM from a cirrus cloud depend on atmospheric conditions.

• Atmosphere
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• v.28 no.4
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• pp.469-477
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• 2018

We performed the comparison of observed $PM_{10}$ and $PM_{2.5}$ at both the Yonsei University and the AIRKOREA site in the same Seodaemun-gu district, Seoul from March to December 2016. Generally, the moderate correlations between two sites were found for both $PM_{10}$ and $PM_{2.5}$, but monthly difference was somewhat occurred, implying that the measurement situation is not equally maintained even in a closely located area. Particularly correlations became weaker in June and July, which seems the impact of rainy conditions. Correlations between two stations were higher for $PM_{10}$ compared to $PM_{2.5}$, probably indicating the spatially larger difference of fine mode particle. Monthly mean variation was similar between two sites showing a maximum in March and minimum in August. Diurnal variation was somewhat different: morning peak at Yonsei University but evening peak at the Seodaemun-gu AIRKOREA site, reflecting the difference of local air condition. We also compared the extent of $PM_{10}$ and $PM_{2.5}$ according to the local wind speed and direction. In general, the level of particulate matter was high when the wind is blowing from the northwestern area with low wind speed, meaning the high accumulation effect of transported air particles. Findings of this study can be usefully considered for the investigation about the discrepancy of aerosol measurement in a local scale.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.10a
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• pp.121-123
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• 1999

Bio-Aerosol Concentrator Inlets were made to collect particles of which size was $2\mu\textrm{m}$ as aerodynamic diameter or larger. The Concentrator Inlets were designed by using virtual impactors, because the virtual impactors are known for high efficiency. In a virtual impactor, the intake air is typically divided into two streams with the major and the minor flow. In this work, several types of the acceleration nozzles and collection probes were designed. Subsequently, the results were evaluated experimentally. It was found that if controled properly, the velocity can improve substantially the aerosol concentration performance. The diameter of acceleration nozzle and type of collection probe were varied to obtain the optimum design. Subsequently, the different designs were compared respectively and the best design among them was identified. It is expected that this new finding can help improve design of future Aerosol Concentrator for high concentration rate.

• Korean Journal of Remote Sensing
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• v.24 no.4
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• pp.289-298
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• 2008

An algorithm was developed to retrieve both cloud optical thickness and effective particle radius considered the aerosol effect on clouds. This study apply the algorithm of Nakajima and Nakajima (1995) that is used to retrieve cloud optical thickness and effective particle radius from visible, near infrared satellite spectral measurements. To retrieve cloud properties, Look-up table (LUT) was made under different atmospheric conditions by using a radiative transfer model. Especially the vertical distribution of aerosol is based on a tropospheric aerosol profile in radiative transfer model. In the case study, we selected the extensive forest fire occurred in Russia in May 2003. The aerosol released from this fire may be transported to Korea. Cloud properties obtained from these distinct atmospheric situations are analysed in terms of their possible changes due to the interactions of the clouds with the aerosol particle plumes. Cloud properties over the East sea at this time was retrieved using new algorithm. The algorithm is applied to measurements from the MODerate Resolution Imaging Spectrometer (MODIS) onboard the Terra spacecrafts. As a result, cloud effective particle radius was decreased and cloud optical thickness was increased during aerosol event. Specially, cloud effective particle radius is hardly greater than $20{\mu}m$ when aerosol particles were present over the East Sea. Clouds developing in the aerosol event tend to have more numerous but smaller droplets.

• Atmosphere
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• v.22 no.4
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• pp.437-447
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• 2012

There is still large uncertainty in estimating aerosol indirect effect despite ever-escalating efforts and virtually exponential increase in published studies concerning aerosol-cloud-precipitation interactions (CAPI). Probably most uncertainty comes from a wide range of observational scales and different platforms inappropriately used, and inherent complex chains of CAPI. Therefore, well-designed field campaigns and data analysis are required to address how to attribute aerosol signals along with clouds and precipitation to the microphysical effects of aerosols. Basically, aerosol influences cloud properties at the microphysical scales, "process scale", but observations are generally made of bulk properties over a various range of temporal and spatial resolutions, "analysis scale" (McComiskey & Feingold, 2012). In the most studies, measures made within the wide range of scales are erroneously treated as equivalent, probably resulting in a large uncertainty in associated with CAPI. Therefore, issues associated with the disparities of the observational resolution particular to CAPI are briefly discussed. In addition, the dependence of CAPI on the cloud environment such as stability and adiabaticity, and observation characteristics with varying situations of CAPI are also addressed together with observation framework optimally designed for the Korean situation. Properly designed and observation-based CAPI studies will likely continue to accumulate new evidences of CAPI, to further help understand its fundamental mechanism, and finally to develop improved parameterization for cloud-resolving models and large scale models.

• Atmosphere
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• v.27 no.4
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• pp.499-509
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• 2017

Possible links among cosmic ray, cloud, and climate have scientific uncertainties. The reputed topics have been highly controversial during several decades. A link between the atmospheric ionization by galactic cosmic rays (GCR), which is modulated by solar activities, and global cloud cover was firstly proposed in 1997. Some researchers suggested that the GCR can stimulate the formation of cloud condensation nuclei (CCN) in the atmosphere, and then the higher CCN concentrations may lead to an increase of cloud cover, resulting in a cooling of the Earth's climate, and vise versa. The CLOUD (Cosmic leaving outdoor droplets) experiment was designed to study the effect of GCR on the formation of atmospheric aerosols and clouds under precisely controlled laboratory conditions. A state-of-the-art chamber experiment has greatly advanced our scientific understanding of the aerosol formation in early stage and its nucleation processes if the GCR effect is considered or not. Many studies on the climate-GCR (or space weather) connection including the CLOUD experiment have been carried out during the several decades. Although it may not be easy to clarify the physical connection, the recent scientific approaches such as the laboratory experiments or modeling studies give some implications that the research definitively contributed to reduce the scientific uncertainties of natural and anthropogenic aerosol radiative forcing as well as to better understand the formation processes of fine particulate matters as an important parameter of air quality forecast.