• KIEE International Transactions on Electrophysics and Applications
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• v.4C no.5
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• pp.220-229
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• 2004

We have examined a technique of one-dimensional (1D) fluid modeling for radio-frequency Ar capacitively coupled plasmas (CCP) between unequal-sized powered and grounded electrodes. In order to simulate a practical CCP reactor configuration with a grounded side wall by the 1D model, it has been assumed that the discharge space has a conic frustum shape; the grounded electrode is larger than the powered one and the discharge space expands with the distance from the powered electrode. In this paper, we focus on how much a 1D model can approximate a 2D model and evaluate their comparisons. The plasma density calculated by the 1D model has been compared with that by a two-dimensional (2D) fluid model, and a qualitative agreement between them has been obtained. In addition, 1D and 2D calculation results for another reactor configuration with equal-sized electrodes have also been presented together for comparison. In the discussion, four CCP models, which are 1D and 2D models with symmetric and asymmetric geometries, are compared with each other and the DC self-bias voltage has been focused on as a characteristic property that reflects the unequal electrode surface areas. Reactor configuration and experimental parameters, which the self-bias depends on, have been investigated to develop the ID modeling for reactor geometry with unequal-sized electrodes.

• Journal of Electrochemical Science and Technology
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• v.12 no.3
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• pp.346-357
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• 2021

In recent years, supercapacitors have been developed rapidly as a rechargeable energy storage device. And the performance of supercapacitors is depending on electrode materials, the preparation method and performance of electrode materials have become the primary goal of scientific development. This study synthesizes Co₃O₄@MnO₂@PPy cathode material with porous pattern core-shell structure by hydrothermal method and electrodeposition. The result samples are characterized by X-ray diffraction transmission/scanning electron microscope, and X-ray photoelectron spectroscopy. Electrochemical evaluation reveals that electrochemical performance is significantly enhanced by PPy depositing. The specific capacitance of Co₃O₄@MnO₂@PPy is 977 F g^-1 at 1 A g^-1, the capacitance retention rate of 105%. Furthermore, the electrochemical performance of Co₃O₄@MnO₂@PPy//AC asymmetric supercapacitor assembles with AC as the negative electrode material is significantly better than that of MnO₂//AC and Co₃O₄@MnO₂//AC. The capacity of Co₃O₄@MnO₂@PPy//AC is 102.78 F g^-1. The capacity retention rate is still 120% for 5000 charge-discharge cycles.

• Korean Journal of Optics and Photonics
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• v.19 no.6
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• pp.429-434
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• 2008

We propose a wavelength filter based on long-range surface plasmon-polaritons (LR-SPP) supported by a asymmetric doubleelectrode LR-SPP structure. For the case of the asymmetric double-layered LR-SPP waveguide, LR-SPPs exist with a much broader range of index mismatches between core and clad materials. Thus, the asymmetric double-electrode LR-SPP waveguide is adequate to form a plasmonic band-gap device as we report in this paper by studying Bragg-reflection wavelength filter based on it. The structure for wavelength filter operating telecommunications wavelength is designed by using the method of line (MoL) and the transfer matrix method. The fabricated device shows a relatively high extinction ratio of 50 dB with a bandwidth of 2 nm, and the performance is very consistent with numerical simulations.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.156.1-156.1
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• 2016

Nickel sulfide (NiS) is one of the most promising candidates as an electrode material for supercapacitors due to its good capacitive properties, high electrical conductivity and low cost. In addition to the development of the new electrode materials, nanostructuring the electrode surface is one of the main issues in enhancing the capacitive performance of the supercapacitors because the increased surface area can improve the charge transfer and energy storage processes occurring at the electrode surface. However, most nanofabrication techniques require complicated and delicate nanoprocesses, and hence are not suitable for practical use. In this work, we developed a simple method to fabricate nanostructured NiS electrodes by depositing NiS onto $TiO_2$ nanoparticles. First, $TiO_2$ nanoparticles were spin-coated on a fluorine-doped tin oxide (FTO) substrate, and then NiS layers were deposited onto the $TiO_2$ nanoparticles by consecutive dip-coatings in the solutions containing nickel and sulfur precursors. This nanostructured NiS electrode showed significantly improved capacitive properties compared to the electrode of NiS films deposited without $TiO_2$ nanoparticles. The asymmetric full-cell supercapacitor with this nanostructured NiS electrode and activated carbon electrode was also fabricated and investigated.

• Journal of Electrochemical Science and Technology
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• v.2 no.3
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• pp.152-156
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• 2011

A hybrid supercapacitor is fabricated using a composite material from $LiMn_2O_4$ (LMO) and activated carbon (AC) as the positive electrode and AC as the negative electrode to form the (LMO + AC)/AC system. Volume ratio (positive : negative) of electrodes is controlled to investigate of the power and energy balance. The (LMO + AC)/AC system shows better performances than the LMO/AC system. Especially, electrochemical impedance spectra, rate charge.discharge and cycle performance testing show that the (LMO + AC)/AC system have an outstanding electrochemical performance at volume ratios of (LMO + AC)/AC = 1 : 1.7 and 1 : 2. Electric double layer capacitor (EDLC) capacitance between AC of the positive electrode and AC of the negative electrode improves power density without loss of capacitance. Stable capacitance is achieved by lowering the positive electrode resistance and balancing the energy and power densities between the positive and negative electrodes by the addition of AC to the positive electrode at high current density.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.29A no.8
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• pp.41-48
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• 1992

The characteristics of traveling-wave electrodes for high-frequency electroptic integrated devices are described from the view point of improvement of phase-matching based on the conformal mapping method. Specific calculations of the characteristic impedance, effective microwave index, and eletrode loss for asymmetric coplanar strip(ACPS) and coplanar waveguide(CPW) electrode structures are presented as a function of the geometric electrode parameters including the electrode thickness and buffer layer thickness. 5-10(x10S0-6Tm) thick Au-ACPS electrodes were successfully fabricated by electroplating and ECR etcher. The improvement of modulation bandwidth can be theoretically observed from the combination of electrode and buffer layer thickness.

• Journal of the Korean Applied Science and Technology
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• v.28 no.3
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• pp.329-334
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• 2011

The electrochemical performances of an asymmetric hybrid capacitor were investigated using $LiFePO_4$ as the positive electrode and active carbon fibers(ACF) as the negative electrode. The electrochemical behaviors of a nonaqueous hybrid capacitor were characterized by constant current charge/discharge test. The specific capacitance using $LiFePO_4$/ACF electrode turned out to be $0.87F/cm^2$ and the unit cell showed excellent cycling performance. This hybrid capacitor was able to deliver a specific energy as high as 178 Wh/kg at a specific power of 1,068 W/kg.

• Transactions on Electrical and Electronic Materials
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• v.6 no.4
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• pp.177-185
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• 2005

Fatigue characteristics of lead zirconate titanate (PZT) films deposited by electron cyclotron resonance plasma enhanced chemical vapor deposition (ECR-PECVD) were investigated. The fatigue characteristics were investigated with respect to PZT film thickness, domain structure, fatigue pulse height, temperature, electrode materials and electrode configurations. The used top and bottom electrode materials were Pt and $RuO_2$. In the fatigue characteristics with fatigue pulse height and PZT film thickness, the fatigue rates are independent of the applied fatigue pulse height at the electric field regions to saturate the P-E hysteresis and polarization $(P^*,\;P^A)$ characteristics. The unipolar and bipolar fatigue characteristics of PZT capacitors with four different electrode configurations $(Pt//Pt,\;Pt//RuO_2,\;RuO_2//Pt,\;and\;RuO_2//RuO_2)$ were also investigated. The polarization-shifts during the unipolar fatigue and the temperature dependence of fatigue rate suggest that the migration of charged defects should not be expected in our CVD-PZT films. It seems that the polarization degradations are attributed to the formation of charged defects only at the Pt/PZT interface during the domain switching. The charged defects pin the domain wall at the vicinity of Pt/PZT interface. When the top and bottom electrode configurations are of asymmetric $(Pt//RuO_2,\;RuO_2//Pt)$, the internal fields can be generated by the difference of charged defect densities between top and bottom interfaces.

• Proceedings of the Korean Ceranic Society Conference
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• 2000.10a
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• pp.141.1-141
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• 2000

• Journal of the Korean Ceramic Society
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• v.35 no.9
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• pp.945-952
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• 1998

Ferroelectric Sr0.8Bi2.4Ta2O9 stock solutions were prepared by MOD(Metaloganic Decompostion) process. The phase transformation for the layered perovskite of the SBT thin films by changing RTA(Rapid her-mal Annealing) temperatuer from 700$^{\circ}C$to 780$^{\circ}C$ were observed using XRD and SEM. Layered perovskite phase began to appear above 740$^{\circ}C$ and then SBT thin films were annealed at 800$^{\circ}C$ for 1hr for its com-plete crystallization. The specimens showed well shaped hysteresis curves without post annealing that car-ried out after deposition of Pt top electrode. The SBT thin films showed the asymmetric ferroelectric pro-perties. It was confirmed that the properties were caused by interface effect to SBT and electrode by leak-age current density measurement and asymmetric properties reduced by post annealing. At post annealing temperature of 800$^{\circ}C$ remanant polarization values (2Pr) were 6.7 9 ${\mu}$C/cm2 and those of leakage current densities were 3.73${\times}$10-7 1.32${\times}$10-6 A/cm2 at 3, 5V respectively. Also bismuth bonding types of SBT thin film surface were observed by XPS.