• 제목/요약/키워드: Asymmetric division

검색결과 213건 처리시간 0.024초

Entry to Highly Hindered Chiral β-Amino Triazoles Bearing a gem-Diaryl Group by Azide-alkyne Click Chemistry

  • Sadu, Venkata Subbaiah;Roy, Harendra Nath;Arigala, Pitchaiah;Hwang, In-Taek;Lee, Kee-In
    • Bulletin of the Korean Chemical Society
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    • 제35권6호
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    • pp.1605-1612
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    • 2014
  • Copper(I)-catalyzed Huisgen cycloaddition of terminal alkynes with unmasked azidoamines derived from amino acids is described. The reported strategy provides a new entry to highly hindered ${\beta}$-amino 1,2,3-triazole derivatives bearing a gem-diaryl group, which are potentially valuable entities as molecular catalysts for asymmetric transformations.

Localized Eigenmodes in a Triangular Multicore Hollow Optical Fiber for Space-division Multiplexing in C+L Band

  • Hong, Seongjin;Oh, Kyunghwan
    • Current Optics and Photonics
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    • 제2권3호
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    • pp.226-232
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    • 2018
  • We propose a triangular-multicore hollow optical fiber (TMC-HOF) design for uncoupled mode-division and space-division multiplexing. The TMC-HOF has three triangular cores, and each core has three modes: $LP_{01}$ and two split $LP_{11}$ modes. The asymmetric structure of the triangular core can split the $LP_{11}$ modes. Using the proposed structures, nine independent modes can propagate in a fiber. We use a fully vectorial finite-element method to estimate effective index, chromatic dispersion, differential group delay (DGD), and confinement loss by controlling the parameters of the TMC-HOF structure. We confirm that the proposed TMC-HOF shows flattened chromatic dispersion, low DGD, low confinement loss, low core-to-core crosstalk, and low crosstalk between adjacent modes. The proposed TMC-HOF can provide a common platform for MDM and SDM applications.

Interpretation of the Asymmetric Color and Shape of Brownish Ring in Quartz Crucible

  • Jung, YoonSung;Choi, Jae Ho;Min, Kyung Won;Byun, Young Min;Im, Won Bin;Kim, Hyeong-Jun
    • 반도체디스플레이기술학회지
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    • 제21권4호
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    • pp.50-52
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    • 2022
  • Brownish rings (BRs) with white interiors are formed during the manufacture of silicon ingots in quartz glass crucibles. These BRs inhibit the yield of silicon ingots. However, the composition and mechanism of the formation of these BRs remain unclear thus far. Therefore, in this study, we analyzed the color and shape of these BRs. Raman analysis revealed that the brown and white colors appear owing to oxygen deficiency rather than crystallization from excess oxygen supply as previously assumed. Moreover, the dark shade of the brown areas depends on the degree of oxygen deficiency and the asymmetrical width of the brown areas is attributed to the direction of the molten silicon flow, which is influenced by the rotation and heat of the ingot crucible.

비고리 알릴아민 화합물의 입체선택적 이중알코올화 반응 (Stereocontrolled Dihydroxylation Reactions of Acyclic Allylic Amines)

  • 전종호;신나라;김영규
    • 공업화학
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    • 제25권5호
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    • pp.437-446
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    • 2014
  • 비고리 알릴아민 화합물의 이중알코올화 반응은 아미노 다이올 구조를 도입할 수 있는 효율적인 합성법으로 아미노 다이올 구조를 포함하는 다양한 생리활성 천연물의 효율적인 합성에 적용될 수 있다. 본 리뷰에서는 기질 그 자체, 혹은 카이랄 리간드를 이용한 다양한 입체선택적 이중알코올화 반응들을 소개하고 이를 실제 천연물의 합성에 적용한 최근의 반응 결과들을 살펴보고자 한다.

A New Approch for Catalyst Optimization: Host/Guest Complexes of Chiral Bisphosphine Bearing Imidazolidinone and Their Application in Rh-Catalyzed Asymmetric Hydrogenation

  • Park, Jung-Hwan;Shin, Hyun-Ik;Park, Doo-Han;Lee, Sang-Gi
    • Bulletin of the Korean Chemical Society
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    • 제31권3호
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    • pp.635-638
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    • 2010
  • As a new strategy for the optimization of a chiral catalyst, the catalytic activity of the host-guest complexes of chiral bisphosphine bearing imidazolidinone was investigated in Rh-catalyzed asymmetric hydrogenation of enamide. Marginal enhancement in enantioselectivity was observed and the nature of interaction between host-guest was experimentally elucidated.

Design of a Cost-Effective Hybrid-Type PBEx Providing a High Power Budget in an Asymmetric 10G-EPON

  • Kim, Kwangok;Lee, Sangsoo;Lee, Jonghyun;Jang, Younseon
    • ETRI Journal
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    • 제34권6호
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    • pp.838-846
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    • 2012
  • This paper proposes a cost-effective hybrid-type power budget extender (PBEx) that can provide a high power budget of over 45 dB in an asymmetric 10-Gb/s Ethernet passive optical network (10/1G-EPON). The hybrid-type 10/1G-EPON PBEx comprises a central office terminal (COT) and remote terminal (RT) module supporting four channels and uses a coarse wavelength division multiplexing (CWDM) technology between the COT and RT for a reduction of fiber cost and efficient access network design. The proposed 10/1G-EPON PBEx can provide over a 40-km reach and 128-way split per CWDM wavelength with no modification of a legacy 10/1G-EPON system and can satisfy the error-free service in $10^{10}$ packet transmission.

Symmetric and Asymmetric Properties in Korean Verbal Coordination: A Computational Implementation

  • Kim, Jong-Bok;Yang, Jae-Hyung
    • 한국언어정보학회지:언어와정보
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    • 제15권2호
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    • pp.1-21
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    • 2011
  • Of the coordination structures in Korean, the symmetric and asymmetric properties of verbal coordination have challenged both theoretical and computational approaches. This paper shows how a typed feature structure grammar, HPSG, together with the notions of 'type hierarchy' and 'constructions', can provide a robust basis for parsing (un)tensed verbal coordination as well as pseudo-coordination found in the language. We show that the analysis sketched here and computationally implemented in the existing resource grammar for Korean, Korean Resource Grammar (KRG), can yield proper syntactic structures as well as enriched semantic representations for real-time applications such as machine translation.

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Performance Analysis of A Modified Asymmetric Rectangular Fin

  • Kang, Hyung Suk
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제6권2호
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    • pp.109-120
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    • 2002
  • The dimensionless heat loss from a modified asymmetric rectangular fin is investigated as a function of the fin top and tip Biot numbers using the two-dimensional separation of variables method. A rectangular fin is modified by attaching the wing on the top side of the fin. Fin effectiveness and efficiency with the variation of the location of the wing and the width of the wing are presented. The relationship between top surface Biot number and bottom surface Biot number as well as the relationship between the dimensionless wing height and the location of the wing for equal amount of heat loss is also discussed.

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다중모드 간섭효과를 이용한 1.3/1.55$\mu\textrm{M}$ InGaAlAs/InP 파장분배기의 제작 (Fabrication of a 1.3/l.55$\mu\textrm{M}$InGaAlAs/InP Dual Wavelength Demultiplexer Based on Multimode Interference(MMI))

  • Moon, Jeong-Yi;Yu, Jae-Su;Dong, Song-Jin;Kim, Jong-Min;Lee, Yong-Tik
    • 한국광학회:학술대회논문집
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    • 한국광학회 2001년도 제12회 정기총회 및 01년도 동계학술발표회
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    • pp.34-35
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    • 2001
  • The wavelength demultiplexer is an essential component in optical transmission systems using wavelength-division multiplexing(WDM), which can increase the number of channels and information capacity of optical fibers. For optical telecommunication, much attention has been given to demultiplexing two wavelengths in the 1.3${\mu}{\textrm}{m}$ of low dispersion band and 1.55${\mu}{\textrm}{m}$ of low loss window. Various integrated-optical devices have been proposed to perform this function, including conventional directional couplers, asymmetric Y-branching devices, asymmetric Mach-Zehnder interferometers and two-mode interference devices. (omitted)

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